Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

On the Nature of the Object HD 209458b: Conclusions Drawn from Comparison of Experimental and Theoretical Data

The experimental data obtained in transit observations of the extrasolar planet HD 209458b and their comparison with theoretical inferences have led to the conclusions that HD 209458b (and other similar hot jupiters) is of a (mainly) hydrogen nature and that these objects probably possess strong magnetic fields. The results of the studies of HD 209458b and prospects for searches for the transits of other extrasolar planets are considered in detail.     

Jets in AGN as seen with an ultimate angular resolution

Jets and cores in Active Galactic Nuclei (AGN) constitute the dominant radio structural pattern in a broad range of angular scales from hundreds of arc seconds down to sub-milliarcseconds. This brief review desribes some recent results in studying the most compact `core-jet' morphologies in AGN using Very Long Baseline Interferometry (VLBI) technique. They include measurements of the cross-section brightness distribution in pc-scale radio jets and attempts to investigate the most compact cores with brightness temperatures in excess of 10¹³ K.     

Ion Irradiation of Asphaltite: Optical Effects and Implications for Trans-Neptunian Objects and Centaurs

Trans-Neptunian Objects (TNOs) and Centaurs show remarkable colour variationsin the visual and near-infrared spectral regions. Surface alteration processes such asspace weathering (e.g., bombardment with ions) and impact resurfacingmay play an important role in the colour diversity of such bodies. Ion irradiation ofhydrocarbon ices and their mixtures with water ice transforms neutral (grey) surfacecolours of ices to red and further to grey. Along with the ices, TNOs and Centaursprobably contain complex carbonaceous compounds, in particular, complexhydrocarbons. Unlike ices, such refractory organic materials have originally lowvisual albedos and red colours in the visible and near-infrared ranges. Here wepresent the first results of ion irradiation experiments on asphaltite. Asphaltite isa natural complex hydrocarbon material. The reflectance spectra of asphaltite inthe 0.4–0.8 μm range have been recorded before irradiation and after eachirradiation step. We demonstrate that irradiation of this red dark material with30 keV H⁺ and 15 keV N⁺ ions gradually transforms its colour from redto grey as a result of carbonization. A moderate increase in the visual albedo hasbeen observed. These results may imply that the surfaces of primitive red objectsoptically dominated by complex refractory organics may show a similar spaceweathering trend. Our laboratory results were compared with published coloursof TNOs and Centaurs. A broad variety of spectral colours observed for TNOs andCentaurs may be reproduced by various spectra of irradiated organics correspondingto different ion fluences. However, such objects probably also contain ices and silicatecomponents which show different space weathering trends. This fact, together with alack of information about albedos, may explain difficulties to reveal correlations between surface colours within TNO and Centaur populations and their other properties, such as absolute magnitudes and orbital parameters.     

Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002