Seasonal variations of phosphorus species in sediment from the middle Adriatic Sea

Phosphorus (P) species concentrations in 0–2 cm surface sediment layer were investigated monthly from November 2001 to December 2002 at the bay, channel and open sea stations in the middle Adriatic. Modified SEDEX method was used for inorganic phosphorus species determination [P in biogenic (P-FD), authigenic (P-AUT), detrital apatite (P-DET) and P adsorbed on to iron oxides and hydroxides (P–Fe)], and organic phosphorus (P-ORG). P-FD, P-AUT and P-DET concentration ranges (1.5–5.4, 0–2.7 and 0.4–3.4 μmol g⁻¹, respectively) were similar at all stations, and showed no obvious common trend of seasonal changes. P–Fe ranged from 1.9 to 11.9 μmol g⁻¹ with the highest values at bay station and higher seasonal oscillations than other inorganic P forms. P-ORG ranged from 0.3 to 18.7 μmol g⁻¹ with higher concentrations at stations of fine-sized sediments and showed increased concentrations in warm part of the year at all stations. Correlation between concentrations of P–Fe in the surface sediment layer and orthophosphate sediment-water interface concentration gradients at bay and channel stations indicated to P–Fe importance in the orthophosphate benthic flux. For the bay station, linkage between sediment P-ORG and chlorophyll a concentrations, primary production and microzooplankton abundance was established, indicating a 1 month delay of sediment response to production fluctuations in the water column.     

Rock displacement and thermal expansion study at historic heritage sites in Slovakia

The paper discusses the results of the research devoted to the preservation of cultural heritage carried out within last two decades in Slovakia. The aim of the study depended on monitoring of selected castle rocks showing instability problems due to extremely slow displacements of creep character. Apart from traditional methods of investigation at one test site (Spis Castle), authors implemented in their work the study of thermal expansion of the rocks as a result of seasonal periodic temperature changes having potential influence on displacements and numerical modeling in order to understand better the landslide failure mechanism. The results obtained from all study sites confirmed that even slow movements have to be implemented into preservation and stabilization works in order to safeguard the sites of great historic value.     

The Ereendavaa Range (north-eastern Mongolia): an additional argument for Mesozoic extension throughout eastern Asia

Mesozoic rift basins locally bounding metamorphic core complexes have been recognized in Transbaikalia and northern China. Numerous basement outcrops located between these two regions, in eastern Mongolia, are considered as pre-Palaeozoic in age. One of these, the Ereendavaa Range, appears as a gneissic core marked by amphibolite-facies metamorphic conditions. The range is overlain to the NW by the unmetamorphosed Mesozoic Onon Basin. Below the basin, the upper part of the range consists of a gently NW-dipping shear zone associated with top-to-the-NW motion. The structural pattern is consistent with syn-extensional exhumation of the range. Preliminary geochronological data indicate that the shear zone is late Jurassic to early Cretaceous in age, coeval with the Onon Basin. These new data from eastern Mongolia constitute a link between Transbaikalia and northern China, indicating that NW–SE extensional Mesozoic tectonics occurred throughout the entire region.     

Electrical Resistivity Imaging technique to delineate coal seam barrier thickness and demarcate water filled voids

Exploration and exploitation of coal seams is one of the major resources for the energy sector in any country but at the same time water filled voids/water logged areas in the old workings of these seams are very critical problems for the coal mining industry. In such situations, disasters like inundation, landslides, collapsing of the old seams may occur. In this regard, it is necessary to find out the water saturated/water filled voids and zones in the mining areas. Since no established technique is available to find such zones, an experimental study using Electrical Resistivity Imaging (ERI) has been carried out in one of the coal mining areas near Dhanbad, to find out the feasibility of finding the barrier thickness and the water logged area in underground coal mines. The area under study forms part of Jharia coalfield in Dhanbad district, Jharkhand state. The coal bearing rocks of Barakar Formation of Lower Permian age (Gondwana period) occur in the area under a thin cover (10 m to15 m) of soil and or alluvium. Coal bearing Barakar Formations consist mainly of sandstone of varying grain size, intercalation of shale and sandstone, grey and carbonaceous-shale and coal seams. Since the water saturation reduces the resistivity of a formation to a large extent, water filled voids and old coal workings are expected to have significant resistivity contrast with the surrounding host rock. Hence, ERI technique was applied in such an environment as this technique uses high-density data acquisition both laterally and vertically by using multiple number of electrodes. Along with ERI, mise-à-la-masse (also called charged body) technique was also employed at one of the promising sites to find out the connectivity of water logged areas and also detection of these old workings from the surface measurements was analyzed. The interpreted 2D resistivity sections have clearly indicated the water bearing zone(s) along the profile which was well confirmed with the existing water level in the nearby borewells. On the other hand, this technique did not identify the size of the coal pillar and gallery (air filled voids), which might be due to the small size of the voids (i.e. about 2 m × 2 m) below a depth of 15m and more but have indicated altogether as a high resistive zone ranging from 600–1000 Ohm-m.     

Mn-oxides and sequestration of heavy metals in a suburban catchment basin of the Chesapeake Bay watershed

The Chesapeake Bay is greatly impacted by numerous pollutants including heavy metals and understanding the controls on the distribution of heavy metals in the watershed is critical to mitigation and remediation efforts in controlling this type of pollution. Clasts from a stormwater catchment basin draining a subdivision near George Mason University, Fairfax VA (38°50.090°N 78°19.204°W) were investigated using X-ray diffraction (XRD), Scanning electron microcopy (SEM) and energy dispersive spectroscopy (EDS) to determine the nature of Mn-oxide coatings and relationship to bound heavy metals. Mn-oxides are poorly crystalline and occur as subhedral to anhedral platy particles and more rarely as euhedral plates. Micronodules are a commonly observed texture. Chemical compositions of coatings are variable with average major constituent concentrations being Mn (33.38 wt%), Fe (11.88 wt%), Si (7.33 wt%), Al (5.03 wt%), and Ba (0.90 wt%). Heavy metals are found in the coatings with Zn being most prevalent, occurring in approximately 58% of analyses with an average concentration of (0.66 wt%). Minor amounts of Co, Ni, Pb, and Cl are observed. Heavy metals and Cl are interpreted as being derived from road pollution. Mn-oxides can serve as a sequestration mechanism for pollution but may also release heavy metals. Field and laboratory observations indicate Mn-oxides occurring on the surface of the clasts can be mechanically mobilized. This is a mechanism for transporting heavy metals into the Chesapeake Bay watershed. Deicing agents may serve as a mechanism to release heavy metals through cation exchange and increased ionic strength. This is the first detailed mineralogical investigation of Mn-oxides and the roles they may play in pollution in the Chesapeake Bay.     

Tectono-geomorphic development of intra-continental Cenozoic depressions within Cretaceous rocks of the Interior Homocline,Central Arabia

Intra-continental depressions occurred in Central Arabia, within the evaporite-bearing Sulaiy Formation, and extends for over 550 km along N-S arcuate belt, passing through eastern Ar Riyadh, Saudi Arabia. They mark Jurassic/Cretaceous contact within the Interior Homocline of Central Arabia, accommodating Neogene and Quaternary deposits. Two en echelon major depressional areas were discovered, the northern major depressional area and the southern major depressional area. The first depressional area occurs between Al Artawiyah and Ad Dilam towns, following the arcuate Jurassic/Cretaceous contact. It contains five depressions: N-S Al Artwaiyah depression; NW-SE Ath Thumamah depression, northeast of Riyadh; NW-SE Jinadriyah depression, east of Riyadh; E-W Al Kharj depression; and N-S Ad Dilam depression. All five depressions seems to be formed by tectonic and subsequent geomorphic events, except for Al Artawiyah and Jinadriyah depression, which developed mainly by tectonic events. Southern major depressional area steps over to southwest of Ad Dilam, and occurs from Hawtat bani tamim to Layla towns. This Hawtah-Layla major depression trends N-S, and Cretaceous units strike NNE, which is a slightly oblique relationship, suggesting expression of deep-seated structures. Tectonic features were part of the Alpine-Himalayan orogeny, developing during Eocene. They followed by a geomorphic event (karsts and subsequent collapse) that took place during Mid Pleistocene. Ad Dilam depression is a surface expression of three oil and gas fields, while the southern major depression between Hawtat Bani Tamim and Layla towns is a surface expression of four oil and gas fields. Yet, other several depressional areas are also accommodating Quaternary desert sediments, and they contain economic resources, which therefore, worth further detailed studies.     

Experimental and numerical investigation on coal drawing from thick steep seam with longwall top coal caving mining

Steep coal seam mining activities will frequently occur during the next few decades in China. In this study, both experimental and numerical methods are employed to investigate the coal drawing from thick steep seam with longwall top coal caving mining. A series of analyses is performed to investigate the features of the drawing body, the distribution of top coal recovery ratio and the shape of the rock flow under steep conditions. The results indicate that the drawing body of top coal develops prior to upper side of the panel face obviously, and the top coal in the central part of the panel has a higher recovery ratio than that in the lower and upper parts in steep coal seam with caving mining method. The flow paths of the fragmented top coal are nearly straight lines moving towards the drawing window, and the fastest path maintains a constant angle with the plumb line. The spatial shape of the rock flow indicates “bidirectional asymmetry,” which results from the presence of the shield beam and dip angle of the coal seam; thus, this is the root cause of the appearance of the drawing body’s prior development towards the upper side of the panel. The field observation data indicates the same distribution of top coal recovery as that in the physical experiment and numerical simulation. Furthermore, suggested measurements are proposed to improve top coal recovery in steep seam mining based on the engineering practice of Dayuan coal mine.     

Hydrogeochemical Characterization and Groundwater Quality of Jamshedpur Urban Agglomeration in Precambrian Terrain,Eastern India

This paper reports petrography, geochemistry and Rb-Sr age data on the rare metal bearing Neoarchean fertile (Nb-Ta) granite at Allapatna and elucidates its petrogenesis and role in Nb-Ta-Li-Be mineralization. The Allapatna granite (AG) intrudes the Tonalitic-Trondhjemitic - Granodioritic (TTG) Peninsular Gneiss and analysed SiO₂ (72.3-75.6 wt%), K₂O (4.0-5.7wt%), Na2O (3.0-4.4wt%), CaO (0.7-1wt%), MgO (0.13-0.25wt%) and K₂O/Na₂O (>1) indicating evolved nature. The presence of muscovite, biotite and garnet in the mode, peraluminous nature and high initial ⁸⁷Sr/⁸⁶Sr ratio (0.7284±0.0083) attest to their S-type characteristics. Varying Nb/Ta ratio and high Li with moderate abundance of Cs further indicate affinity to Li-Cs-Ta (LCT) type granite-pegmatite system. TheAG showing whole rock Rb-Sr isochron age of 2803± 68 Ma, is the oldest reported fertile granite in India parental to rare metal pegmatites hosting Nb-Ta, Be, and Li resources. Partial melting of a mixed source consisting of both basement TTG rocks and metapelites has generated such type of granitic magma. Fractionation of such granitic magma possibly has given rise to the rare metal (Ta-Nb-Li-Be) bearing pegmatites intruding the nearby schist belt.