The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain

Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss.     

Energetic protons from the solar flare of March 24, 1966

Ten to 100 meV protons from the solar flare of March 24, 1966 were observed on the University of California scintillation counter on OGO-I. The short rise and decay times observed in the count rates of the 32 channels of pulse-height analysis show that scattering of the protons by the interplanetary field was much less important in this event than in previously observed proton flares. A diffusion theory in which D = M _r is found to be inadequate to account for the time behavior of the count rates of this event. Small fluctuations of the otherwise smooth decay phase may be due to flare protons reflected from the back of a shock front, which passed the earth on March 23.     

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.     

Ionospheric Joule dissipation as a damping mechanism for high latitude ULF pulsations: Observational evidence

On 9 January 1979 an SI-excited pulsation event was observed by the Scandinavian Magnetometer Array. The pulsation period shows a clear variation with latitude which suggests decoupled oscillations of individual magnetic field shells. The pulsation amplitudes exhibit an e-fold decay with the damping rate γ varying both in longitudinal and latitudinal directions. Assuming Joule heating in the ionosphere as the dominant damping mechanism (and thus γ ～ Σ^?1_p) approximate height-integrated Pedersen conductivity profiles were calculated which fit well with previously observed Σ_p distributions. This is interpreted as observational evidence for ionosopheric Joule dissipation as the major damping mechanism for high-latitude ULF-pulsations.     

On the convective instability of finitely conducting viscous model chromosphere

The convective stability of a simple model chromosphere, consisting of protons, electrons and hydrogen atoms in the ground state, has been studied in the presence of a vertically upward uniform magnetic field to include the effects of FLR, Hall-currents, finite conductivity and ionization. The ionization in the chromosphere is collisional and the recombination is radiative. It is found that the Schwarzchild criterion should necessarily be satisfied for the stability together with the condition thatv > 2v ₀, where is kinematic viscosity andv ₀ is gyroviscosity. Some special cases have also been investigated.     

Magnesium-iron compositional variance in hornblende pyroxene granulites

Hornblende-orthopyroxene-calcic pyroxene-plagioclase (andesine-labradorite) — magnetite-ilmenite±quartz assemblages are evidently the most common granulite facies representatives of basic rocks throughout the world, and they must represent a variance of more than one. Ramberg (1948) invoked an additional degree of freedom arising out of unequal fractionation of Mg and Fe in the ferromagnesian silicates in such rocks. This is examined in detail on the basis of chemical data on twentytwo hornblende-orthopyroxenecalcic pyroxene triads, half of them from the type charnockite area near Madras.Theoretical consideration of a magnesium-iron distribution model shows that in quartz-bearing hornblende pyroxene granulites, the Mg/Mg+Fe ratios of hornblende, orthopyroxene and calcic pyroxene are uniquely determined by temperature at constant pressure. But these assemblages contain quartz rarely and Mg-Fe distribution among the three can be best described by three exchange equilibria where, at constant temperature, there is a fixed relation between the Mg/Mg+Fe ratios of the minerals. Among these, the exchange equilibria between hornblende-orthopyroxene and hornblende-calcic pyroxene appear to be interdependent; however, they are known to be significantly modified by varying tetrahedral aluminium contents of hornblendes. Comparison of molecular Mg/(Mg+Fe) ratios of hornblendes and parent rocks strongly points to an absence of Mg-Fe compositional variance in the total system, a petrologically important corollary being that the hornblendes in these rocks are highly unlikely to be secondary after pyroxenes. The general variance of the assemblages is also discussed.     

Allochthonous and autochthonous organic matter in surface waters in Karelia

A relationship between indirect chemical indices of organic matter content of surface waters and light absorption in the visible and ultraviolet ranges is discussed. The allochthonous and autochthonous types of organic matter are found to essentially differ in the rate of light absorption. Techniques are proposed for the calculation of the concentrations of allochthonous and autochthonous organic matter by the integral rate of light consumption in the visible region and the bichromate oxidability of water, as well as by three indirect indices: chemical oxygen demand, permanganate oxidability, and water color index. The mean concentrations of allochthonous and autochthonous organic matter in large lakes (Ladoga, Onega, and Baikal) and in rivers and smaller water bodies in Karelia (>300 water objects) are analyzed. Allochthonous organic matter was found to predominate in most surface waters of Karelia (>80%), while allochthonous organic matter predominates only in lakes with a small specific catchment area (supposedly, <5) and in highly eutrophic lakes.     

Biofacies analysis of Upper Cretaceous deposits in the Ust-Yenisei region: Implications of palynomorphs

The results of palynomorph biofacies analysis in the Upper Cretaceous deposits of the Ust-Yenisei region are presented. The established facies confinement and indicative features of separate palynomorph groups are used, along with identified dinocyst morphotypes and taxa, in paleogeographic reconstructions. Seven palynomorph associations characterizing continental, coastal-marine, shallow-and deep-water facies are distinguished based on quantitative proportions between morphological groupings and individual taxa. As boundaries between distinguishable biostratigraphic and facies subdivisions do not coincide, dinocysts were likely insignificantly dependent in distribution on facies in the West Siberian epicontinental basin at least. On the other hand, distribution trends of particular dinocyst morphotypes and other microphytofossils are correlative with transgressive-regressive cycles and can be used for reconstruction of paleoenvironments.