Energetics of radiation damage in natural zircon (ZrSiO4)

Transposed temperature drop calorimetry at 1000 °C was performed on natural zircons (ZrSiO₄) from Sri Lanka that were partially to completely metamict due to α-decay event damage (0.06 to 11.7×10¹⁵ α-decay events/mg). The enthalpy of annealing at room temperature (ΔH_anneal) varies sigmoidally as a function of radiation dose. ΔH_anneal reaches a saturation plateau at radiation doses greater than 5×10¹⁵ α-decay events/mg. The annealing of several samples to a crystalline structure with broadened diffraction peaks does not significantly affect the enthalpy of annealing. The large magnitude of the enthalpy of annealing plateau, ?59±3 kJ/mol, suggests that the damage to the structure is pervasive on the scale of Angstroms, consistent with the loss of mid-range order characteristic of a glass. The energetics are consistent with, but do not require, chemical heterogeneity caused by micro-domains of amorphous SiO₂-rich and ZrO₂-rich regions in the metamict state.     

Land-derived pollutant hydrocarbons

Evidence is given for the derivation of oil pollution from on-shore sources and for a possible relation between its concentration in estuarine sediment and in the lipids of the sediment biomass.     

Groundwater quality assessment from a hard rock terrain, Salem district of Tamilnadu, India

A total of 162 groundwater samples for three representative seasons were collected from Salem district of Tamilnadu, India to decipher hydrogeochemistry and groundwater quality for determining its suitability for drinking and agricultural proposes. The water is neutral to alkaline in nature with pH ranging from 6.6 to 8.6 with an average of 8.0. Higher electrical conductivity was observed during post-monsoon season. The abundance of major ions in the groundwater was in the order of $ {\text{Na} > \text{Ca} > \text{Mg} > \text{K} = \text{Cl} > \text{HC}}{{\text{O}}_3}\; > \;{\text{S}}{{\text{O}}_4}\; > \;{\text{N}}{{\text{O}}_3} $ . Piper plot reveals the dominance of geochemical facies as mixed Ca–Mg–Cl, Na–Cl, Ca–HCO₃, Ca–Na–HCO₃, and Ca–Cl type. NO₃, Cl, SO₄, and F exceed the permissible limit during summer and post-monsoon seasons. Sodium adsorption ratio was higher during post-monsoon and southwest monsoon season indicating high and low salinity, satisfactory for plants having moderate salt tolerance on soils. Permeability index of water irrespective of season falls in class I and class II indicating water is moderate to good for irrigation purposes. As per the classification of water for irrigation purpose, water is fit for domestic and agricultural purposes with minor exceptions irrespective of seasons.     

Palaeointensity In the Pelagic Realm: Marine Sediment Data Compared With Archaeomagnetic and Lake Sediment Records

Summary. Four box cores collected from the Ontong—Java plateau during the Eurydice expedition have been used to make relative geomagnetic palaeo-intensity measurements. Rock magnetic measurements on the sediments show that they are characterized by a uniform magnetic mineralogy, and that they are suitable for relative intensity estimates. These are obtained by normalizing the NRM by an ARM imparted in a low DC bias field. the palaeoceanographic event known as the preservation spike is used to establish a crude time-scale for the record so that it may be compared with other data from the same region, and also with global palaeointensity estimates. the marine sediment data are quite similar to Australian intensity data from lake sediments and archaeomagnetic sources, but as might be expected exhibit some obvious differences from the global record.     

The Middle Miocene to Recent Davis Strait Drift Complex: implications for Arctic�CAtlantic water exchange

A large-scale contourite drift complex has been recognised on multi-channel 2D reflection seismic data acquired in the south-eastern Davis Strait and adjacent Labrador Sea slope offshore West Greenland between 63°?C66°N. Based on well-tie data, the drift complex developed from the Middle Miocene to the Recent. It has been mapped in a wide variety of water depths ranging from about 700?m, at a NNW-ESE-elongated crest located above structural highs in the Davis Strait, to more than 2,000?m beyond the slope to the Labrador Sea. The overall drift geometry has been described by subdivision into two first-order seismic units, enabling the generation of time-isochore maps. The reflection patterns demonstrating current-related deposition are illustrated by seismic examples. The time-isochores of the two first-order seismic units show lateral changes in their depocentres: the lower unit is absent in a zone slightly displaced south-westwards of the present-day crest, indicating changes in the prevailing deepwater current system during the Early Pliocene. The observations can be explained by two alternative palaeoceanographic scenarios: (1) either the present-day oceanographic setting with Arctic?CAtlantic water exchange across the Davis Strait was largely established by the mid-Miocene, with only minor adjustments during the Early Pliocene caused by tectonic movements, or (2) it became established during the Early Pliocene as a consequence of enhanced northward flow across the Davis Strait due to lowering of the sill depth.     

Insolation estimates for the LITFASS area derived from high resolution satellite data

Summary ?For the LITFASS-98 experiment, from June 1 until June 30, 1998, the spatially resolved insolation at surface could be computed from NOAA-14 AVHRR data applying the modular analysis scheme SESAT (Strahlungs- und Energiebilanzen aus Satellitendaten). The satellite inferred insolation for this period shows for clear-sky regions a good agreement with surface based observations with a rms error of 76 Wm⁻². For cloudy conditions the insolation is overestimated with respect to ground based observations, with a rms error between 83 and 118 Wm⁻², depending on the cloud optical thickness. This overestimation can be explained by the surface heterogeneity, leading to underestimated cloud optical thickness, and also by a fixed relative humidity below clouds (55%, dry atmosphere) and a fixed horizontal visibility (50 km, clear atmosphere). A detailed study of comparable scales in space and time, considering the different observation geometries and sampling intervals, shows that a 30 min ground based observation can be compared with a 8 × 8 km² mean by the satellite data. Received July 12, 2001; revised April 29, 2002; accepted June 7, 2002     

Rainfall induced debris flows in pyroclastic deposits, Campania (southern Italy)

A combination of empirical and physically based hydrological models has been used to analyze historical data on rainfall and debris-flow occurrence in western Campania, to examine the correlation between rainfall and debris-flow events.

Rainfall data from major storms recorded in recent decades in western Campania were compiled, including daily series from several rain gauges located inside landslide areas, supplemented by hourly rainfall data from some of the principal storms.

A two-phase approach is proposed. During phase 1, soil moisture levels have been modelled as the hydrological balance between precipitation and evapotranspiration, on a daily scale, using the method of Thornthwaite [Geograph. Rev. 38 (1948) 55].

Phase 2 is related to the accumulation of surplus moisture from intense rainfall, leading to the development of positive pore pressures. These interactions take place on an hourly time scale by the “leaky barrel” (LB) model described by Wilson and Wiezoreck [Env. Eng. Geoscience, 1 (1995) 11]. In combination with hourly rainfall records, the LB model has been used to compare hydrological effects of different storms. The critical level of retained rain water has been fixed by the timing of debris-flow activity, related to recorded storm events.

New rainfall intensity–duration thresholds for debris-flow initiation in western Campania are proposed. These thresholds are related to individual rain gauge and assume a previously satisfied field capacity condition. The new thresholds are somewhat higher than those plotted by previous authors, but are thought to be more accurate and thus need less conservatism.     

On the mechanical interaction between a growing porphyroblast and its surrounding matrix

Whether or not a growing porphyroblast can displace its surrounding matrix is an important but contentious issue affecting the interpretation of metamorphic textures. As an alternative to treating the problem in terms of force of crystallization, this paper examines the mechanics of porphyroblast-matrix interaction using a different and much simpler conceptual framework. New microstructural evidence for matrix displacement is then presented and analysed in detail. This evidence, from a hornfelsed metagreywacke, consists of dome-shaped accumulations of muscovite and graphite, each dome being attached to (and concave towards) a rhombdodecahedral face of a garnet porphyroblast. Muscovite within the domes shows a dimensional preferred orientation subparallel to the dome outlines while, in the matrix away from the domes, there is no preferred orientation.Our model for the origin of the mica domes envisages muscovite and graphite being swept ahead of, and mechanically accumulated onto, the growing garnet faces as they advance through the matrix. Rigorous testing of this model provides strong evidential support for matrix displacement by growing porphyroblasts. A new analysis is provided of the conditions under which matrix grains are included or displaced by porphyroblasts. It is concluded that matrix grain displacement may be very common, although the special combination of circumstances necessary to produce a diagnostic microstructural pattern probably occurs very rarely.