Sulfur and iron speciation in surface sediments along the northwestern margin of the Black Sea

The speciation of sedimentary sulfur (pyrite, acid volatile sulfides (AVS), S⁰, H₂S, and sulfate) was analyzed in surface sediments recovered at different water depths from the northwestern margin of the Black Sea. Additionally, dissolved and dithionite-extractable iron were quantified, and the sulfur isotope ratios in pyrite were measured. Sulfur and iron cycling in surface sediments of the northwestern part of the Black Sea is largely influenced by (1) organic matter supply to the sediment, (2) availability of reactive iron compounds and (3) oxygen concentrations in the bottom waters. Biologically active, accumulating sediments just in front of the river deltas were characterized by high AVS contents and a fast depletion of sulfate concentration with depth, most likely due to high sulfate reduction rates (SRR). The δ³⁴S values of pyrite in these sediments were relatively heavy (−8‰ to −21‰ vs. V-CDT). On the central shelf, where benthic mineralization rates are lower, re-oxidation processes may become more important and result in pyrite extremely depleted in δ³⁴S (−39‰ to −46‰ vs. V-CDT). A high variability in δ³⁴S values of pyrite in sediments from the shelf-edge (−6‰ to −46‰ vs. V-CDT) reflects characteristic fluctuations in the oxygen concentrations of bottom waters or varying sediment accumulation rates. During periods of oxic conditions or low sediment accumulation rates, re-oxidation processes became important resulting in low AVS concentrations and light δ³⁴S values. Anoxic conditions in the bottom waters overlying shelf-edge sediments or periods of high accumulation rates are reflected in enhanced AVS contents and heavier sulfur isotope values. The sulfur and iron contents and the light and uniform pyrite isotopic composition (−37‰ to −39‰ vs. V-CDT) of sediments in the permanently anoxic deep sea (1494 m water depth) reflect the formation of pyrite in the upper part of the sulfidic water column and the anoxic surface sediment. The present study demonstrates that pyrite, which is extremely depleted in ³⁴S, can be found in the Black Sea surface sediments that are positioned both above and below the chemocline, despite differences in biogeochemical and microbial controlling factors.     

WAS THE FORMATION OF A 20-KM-DIAMETER IMPACT CRATER ON THE MOON OBSERVED ON JUNE 18, 1178?

As reported in medieval chronicles, on the evening of June 18, 1178, the upper horn of a new moon split, and from the division a flaming torch sprang up. We interpret this observation in terms of a large impact event which formed the 20-km-diameter crater, Giordano Bruno.     

The enigma of the Uranian satellites' orbital eccentricities

Using recently published determinations of the diameters and orbital elements of the uranian satellites and assuming reasonable dissipation functions and rigidities for icy satellites, the eccentricity decay times for the satellites were calculated. For the inner three, decay times are on the order of 10⁷–10⁸ years, making it difficult to understand why these satellites still have their observed eccentricities. The three inner satellites have a near-commensurability in their mean motions that may be able to force their eccentricities at some time in the future, but cannot force them now. Several possible explanations exist: (1) The reported eccentricities are incorrect, and are in fact near-zero. (2) The reported mean motions are incorrect, and an exact commensurability exists. (3) The physical properties that we have assumed for the satellites are grossly in error (e.g., dissipation function Q is in reality very large). (4) The system is evolving very rapidly, perhaps from a previous state of higher eccentricity. Cases 1 and 2 are unlikely when one considers the quality of existing data. Case 3 would be more consistent with non-icy compositions. Cases 2 and 4 would imply some tidal heating of the satellites, particularly Ariel. A new lower bound of ～ 1.7 × 10⁴ on the Q of Uranus is calculated from the mass of Ariel and its proximity to Uranus.     

Phosphine photochemistry in the atmosphere of Saturn

A model is presented for the photochemistry of PH₃ in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH₃ and hydrocarbon photochemistry, specifically the C₂H₂ catalyzed photodissociation of CH₄. PH₃ is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～10⁴cm²sec^?1; an upper limit for K at the tropopause is estimated at ～10⁵cm²sec^?1. If there is no gas phase P₂H₄ because of sublimation, P₂ and P₄ formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H₂ + M → PH₃ + M is exceedingly slow. An upper limit P₄ column density of ～2×10¹⁵cm^?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P₂H₄, P₂ and P₄ may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH₃P₂H₂ and HCP are predicted, with column densities of >10¹⁷ cm^?2 and production rates of ～2×10⁸cm^?2sec^?1. The possible importance of electronically excited states of PH_x and additional PH₃/hydrocarbon photochemical coupling paths are also considered.     

Streamflow generation in a headwater basin on the precambrian shield

Current conceptual runoff models hypothesize that stormflow generation on the Canadian Shield is a combination of subsurface stormflow and saturation overland flow. This concept was tested during spring runoff in a small (3.3 ha) headwater basin using: (1) isotopic and chemical hydrograph separation and (2) field mapping and direct tracing of saturated areas. Isotopic and chemical hydrograph separation indicated three runoff components: (1) pre-melt subsurface flow; (2) subsurface flow of new (event) water; and (3) direct precipitation on to saturated areas (DPS). During early thaw-freeze cycles, their relative contributions to total flow remained constant (65 per cent, 30 per cent, and 5 per cent respectively). It is hypothesized that lateral flow along the bedrock/mineral soil interface, possibly through macropores, supplied large volumes of subsurface flow (of both old and new water) rapidly to the stream channel. Much higher contributions of DPS were observed during an intensive rain-on-snow event (15 per cent of total flow). Mapping and direct tracing of saturated areas using lithium bromide, suggested that saturated area size was positively correlated to stream discharge but its response lagged behind that of discharge. These observations suggest that the runoff mechanisms, and hence the sources of stream flow, will vary depending on storm characteristics.     

Ballistic transport in Saturn's rings: An analytic theory

Ejecta from impacts of micrometeoroids on Saturn's ring particles will, in most cases, remain in orbit about Saturn and eventually be reaccreted by the rings, possibly at a different radial location. The resulting mass transport has been suggested as the cause of some of the features observed in Saturn's rings. Previous attempts to model this transport have used numerical simulations which have not included the effects of the angular momentum transport coincident with mass transport. An analytical model for ballistic mass transport in Saturn's rings is developed. The model includes the effects of angular momentum advection and shows that the net material movement due to angular momentum advection is comparable to that caused by direct ballistic mass transport.     

Monitoring of movement of potential earthquake areas with precise distance measuring and leveling systems

Whether monitoring crustal movements in localized volcanic areas along known fault lines, or over large crustal-movement areas, the geodesist has been restricted by the measurement accuracy of the instruments used, the accumulation of errors, the lack of reliable air refraction information and the problem of finding proper measurement procedures and mathematical solutions to assure that the inherent errors of the measurement-mathematical procedures do not exceed any conceivable ground movement.

Recent technological advances have placed new instruments and systems at the disposal of the geodesist, so that is now feasible to measure and analyze these micro and macro crustal movements within the accuracies required.

The paper describes three such systems:

1. (1) The Wild Electronic Theodolite T-2000 with a highly precise distance-measurement instrument, the DI-4S, together with a data collector, the GRE-3, which are connected to a computer and a plotter to measure and analyze both micro and macro crustal movements.

2. (2) The Wild NAK-2 level with an antimagnetic compensator which increases the accuracy in the height/velocity monitoring of vertical crustal movements by virtual elimination of the influence of natural or man-made magnetic fields on the automatic level.

3. (3) The use of analytical photogrammetry employing both terrestrial and aerial photography to monitor crustal movements.

By taking advantage of these new instruments and systems, the scientists capability to provide crustal movement data for use in the analysis and prediction of micro or macro crustal movement is greatly enhanced.