Numerical simulations of rotating cooling flows in galaxy cluster environments

We have used 2D numerical simulations to study the evolution of galaxy cluster cooling flows undergoing a rotational perturbation. We show that such rotations in the intracluster medium may arise from cluster/subcluster mergers. Our galaxy cluster initial conditions involve spherically symmetric, steady-state cooling flows with varying mass-dropout strengths. The rotational perturbation serves to break the symmetry for each of the initial cooling flows, resulting in the formation of thin, gaseous disc-like structure extending radially out to ∼10 kpc. Disc-like structure formed for low mass-dropout strength simulations appears to contain cooling condensations whereas disc-like structure in higher mass-dropout strength simulations appears smooth. This is due to the influence of mass-dropout on the degree of cooling, which serves to reduce the strength of thermal instabilities by the removal of 'cold' gas from the flow. Morphological comparisons of the disc-like structure formed in our simulations are made to structure observed in the X-ray emitting gas of A4059. Comparisons of the gas dynamics within the disc-like structure are also made to the solid-body rotation profile observed from emission-line gas within the central galaxy of Hydra A. The influence of grid effects on the simulations is also discussed.     

Significance of cytochrome P450 system responses and levels of bile fluorescent aromatic compounds in marine wildlife following oil spills

The relationships among cytochrome P450 induction in marine wildlife species, levels of fluorescent aromatic compounds (FAC) in their bile, the chemical composition of the inducing compounds, the significance of the exposure pathway, and any resulting injury, as a consequence of exposure to crude oil following a spill, are reviewed. Fish collected after oil spills often show increases in cytochrome P450 system activity, cytochrome P4501A (CYP1A) and bile fluorescent aromatic compounds (FAC), that are correlated with exposure to polycyclic aromatic hydrocarbons (PAH) in the oil. There is also some evidence for increases in bile FAC and induction of cytochrome P450 in marine birds and mammals after oil spills. However, when observed, increases in these exposure indicators are transitory and generally decrease to background levels within one year after the exposure. Laboratory studies have shown induction of cytochrome P450 systems occurs after exposure of fish to crude oil in water, sediment or food. Most of the PAH found in crude oil (dominantly 2- and 3-ring PAH) are not strong inducers of cytochrome P450. Exposure to the 4-ring chrysenes or the photooxidized products of the PAH may account for the cytochrome P450 responses in fish collected from oil-spill sites. The contribution of non-spill background PAH, particularly combustion-derived (pyrogenic) PAH, to bile FAC and cytochrome P450 system responses can be confounding and needs to be considered when evaluating oil spill effects. The ubiquity of pyrogenic PAH makes it important to fully characterize all sources of PAH, including PAH from natural resources, e.g. retene, in oil spill studies. In addition, such parameters as species, sex, age, ambient temperature and season need to be taken into account. While increases in fish bile FAC and cytochrome P450 system responses, can together, be sensitive general indicators of PAH exposure after an oil spill, there is little unequivocal evidence to suggest a linkage to higher order biological effects, e.g. toxicity, lesions, reproductive failure.     

Early Diagenesis of Plant Pigments in Hudson River Sediments

Plant pigment concentrations were measured using high performance liquid chromatography in Hudson River sediments. Sedimentation rates and mixing characteristics were determined from depth profiles of the naturally occurring radionuclides ⁷Be, ²¹⁰Pb. Previous estimates of the mean-lives (1/λ) of plant pigments (chlorophylls a and b, fucoxanthin) from laboratory experiments, indicate a range of c. 20-40 days. However, in the field, we observed that these pigments decreased less rapidly with depth and penetrated deeper than ⁷Be (mean-life 77 days) in Hudson sediments 95% of the time. Assuming similar mixing processes for particles carrying ⁷Be and pigments, this indicates that pigment decay rates in the field are slower than the 0·013 day^-1 decay rate of ⁷Be, hence, more than 2-fold slower than the derived laboratory rates. We believe that high inputs of vascular plant detritus in the Hudson may increase the complexation of humic substances with pigments resulting in slower decay rates.While most pigments showed an exponential decrease with sediment depth, lutein concentrations generally increased with depth. This pattern of decay resistance is in agreement with laboratory experiments which show that lutein is the most decay resistant among dominant pigments. These data along with other studies demonstrate that the carotenoids lacking the 5,6-epoxide group (i.e., lutein) are more decay resistant than pigments that contain it (i.e., fucoxanthin).     

Burial dolomitization driven by modified seawater and basal aquifer‐sourced brines: Insights from the Middle and Upper Devonian of the Western Canadian Sedimentary Basin

Dolomitization in the Western Canadian Sedimentary Basin has been extensively researched, producing vast geochemical datasets. This provides a unique opportunity to assess the regional sources and flux of dolomitizing fluids on a larger scale than previous studies. A meta‐analysis was conducted on stable isotope, strontium isotope (⁸⁷Sr/⁸⁶Sr), fluid inclusion and lithium‐rich formation water data published over 30 years, with new petrographic, X‐ray diffraction, stable isotope and rare‐earth element (REE+Y) data. The Middle to Upper Devonian Swan Hills Formation, Leduc Formation and Wabamun Group contain replacement dolomite (RD) cross‐cut by stylolites, suggesting replacement dolomitization occurred during shallow burial. Stable isotope, REE+Y and ⁸⁷Sr/⁸⁶Sr data indicate RD formed from Devonian seawater, then recrystallized during burial. Apart from the Wabamun Group of the Peace River Arch (PRA), saddle dolomite cement (SDC) is more δ¹⁸O_(PDB) depleted than RD, and cross‐cuts stylolites, suggesting precipitation during deep burial. SDC ⁸⁷Sr/⁸⁶Sr data indicate contributions from ⁸⁷Sr‐rich basinal brines in the West Shale Basin (WSB) and PRA, and authigenic quartz/albite suggests basinal brines interacted with underlying clastic aquifers before ascending faults into carbonate strata. The absence of quartz/albite within dolomites of the East Shale Basin (ESB) suggests dolomitizing fluids only interacted with carbonate strata. We conclude that replacement dolomitization resulted from connate Devonian seawater circulating through aquifers and faults during shallow burial. SDC precipitated during deep burial from basinal brines sourced from basal carbonates (ESB) and clastic aquifers (WSB, PRA). Lithium‐rich formation waters suggest basinal brines originated as residual evapo‐concentrated Middle Devonian seawater that interacted with basal aquifers and ascended faults during the Antler and Laramide Orogenies. These results corroborate those of previous studies but are verified by new integrated analysis of multiple datasets. New insights emphasize the importance of basal aquifers and residual evapo‐concentrated seawater in dolomitization, which is potentially applicable to other regionally dolomitized basins.     

Size Matters to Lesbians,Too: Queer Feminist Interventions into the Scale of Big Data

How can we recognize those whose lives and data become attached to the far-from-groundbreaking framework of “small data”? Specifically, how can marginalized people who do not have the resources to produce, self-categorize, analyze, or store “big data” claim their place in the big data debates? I examine the place of lesbians and queer women in the big data debates through the Lesbian Herstory Archive's not “big” enough lesbian, gay, bisexual, trans, and queer (LGBTQ) organizing history data set—perhaps the largest data set known to exist on LGBTQ activist history—as one such alternative. In a contribution to critical data studies, I take a queer feminist approach to the scale of big data by reading for the imbricated scales and situated knowledge of data.     

An embedded fracture modeling framework for simulation of hydraulic fracturing and shear stimulation

A numerical modeling framework is described that is able to calculate the coupled processes of fluid flow, geomechanics, and rock failure for application to general engineering problems related to reservoir stimulation, including hydraulic fracturing and shear stimulation. The numerical formulation employs the use of an embedded fracture modeling approach, which provides several advantages over more traditional methods in terms of computational complexity and efficiency. Specifically, the embedded fracture modeling strategy avoids the usual requirement that the discretization of the fracture domain conforms to the discretization of the rock volume surrounding the fractures. As fluid is exchanged between the two domains, conservation of mass is guaranteed through a coupling term that appears as a simple source term in the governing mass balance equations. In this manner, as new tensile fractures nucleate and propagate subject to mechanical effects, numerical complexities associated with the introduction of new fracture control volumes are largely negated. In addition, the ability to discretize the fractures and surrounding rock volume independently provides the freedom to choose an acceptable level of discretization for each domain separately. Three numerical examples were performed to demonstrate the utility of the embedded fracture model for application to problems involving fluid flow, mechanical deformation, and rock failure. The results of the numerical examples confirm that the embedded fracture model was able to capture accurately the complex and nonlinear evolution of reservoir permeability as new fractures propagate through the reservoir and as fractures fail in shear.     

Orbital stability of systems of closely-spaced planets,II: configurations with coorbital planets

We numerically investigate the stability of systems of 1 \({{\rm M}_{\oplus}}\) planets orbiting a solar-mass star. The systems studied have either 2 or 42 planets per occupied semimajor axis, for a total of 6, 10, 126, or 210 planets, and the planets were started on coplanar, circular orbits with the semimajor axes of the innermost planets at 1 AU. For systems with two planets per occupied orbit, the longitudinal initial locations of planets on a given orbit were separated by either 60° (Trojan planets) or 180°. With 42 planets per semimajor axis, initial longitudes were uniformly spaced. The ratio of the semimajor axes of consecutive coorbital groups in each system was approximately uniform. The instability time for a system was taken to be the first time at which the orbits of two planets with different initial orbital distances crossed. Simulations spanned virtual times of up to 1 × 10⁸, 5 × 10⁵, and 2 × 10⁵ years for the 6- and 10-planet, 126-planet, and 210-planet systems, respectively. Our results show that, for a given class of system (e.g., five pairs of Trojan planets orbiting in the same direction), the relationship between orbit crossing times and planetary spacing is well fit by the functional form log(t _c /t ₀) = b β + c, where t _c is the crossing time, t ₀ = 1 year, β is the separation in initial orbital semimajor axis (in terms of the mutual Hill radii of the planets), and b and c are fitting constants. The same functional form was observed in the previous studies of single planets on nested orbits (Smith and Lissauer 2009). Pairs of Trojan planets are more stable than pairs initially separated by 180°. Systems with retrograde planets (i.e., some planets orbiting in the opposite sense from others) can be packed substantially more closely than can systems with all planets orbiting in the same sense. To have the same characteristic lifetime, systems with 2 or 42 planets per orbit typically need to have about 1.5 or 2 times the orbital separation as orbits occupied by single planets, respectively.     

AquaEnv: An Aquatic Acid–Base Modelling Environment in R

AquaEnv is an integrated software package for aquatic chemical model generation focused on ocean acidification and antropogenic CO₂ uptake. However, the package is not restricted to the carbon cycle or the oceans: it calculates, converts, and visualizes information necessary to describe pH, related CO₂ air–water exchange, as well as aquatic acid–base chemistry in general for marine, estuarine or freshwater systems. Due to the fact that it includes the relevant acid–base systems, it can also be applied to pore water systems and anoxic waters. AquaEnv is implemented in the open source programming language R , which allows for a flexible and versatile application: AquaEnv ’s functionality can be used stand-alone as well as seamlessly integrated into reactive-transport models in the R modelling environment. Additionally, AquaEnv provides a routine to simulate and investigate titrations of water samples with a strong acid or base, as well as a routine that allows for a determination of total alkalinity and total carbonate values from recorded titration curves using non-linear curve-fitting.