Book reviews

Under thhe drought conditions that have occurred in Bulgaria during the last decade, agricultural use of non-conventional water may be an important resource. This is a specific case of simultaneous purification and utilisation by soil ecological systems. However, using non-conventional quality water presents a number of ecological and health risks and poses problems connected with soil and surface and ground water contaminated and with producing crops of acceptable quality. Bulgaria's municipal, industrial, and rural wastewater reclamation and reuse, in addition to other non conventional water resources as sea water, drainage water and mineralised groundwater, may be a reliable source even in drought years and thus is capable of replacing potable used in agriculture. This paper reviews the work of the authors and their colleagues in assessing the irrigation potentials of waste water in Bulgaria.     

Modeling Volatile Chemical Transport, Biodecay, and Emission to Indoor Air

A model is presented for estimating vapor concentrations in buildings because of volatilization from soil contaminated by non- aqueous phase liquids (NAPL) or from dissolved contaminants in ground water. The model considers source depletion, diffusive- dispersive transport of the contaminant of concern (COC) and of oxygen and oxygen-limited COC biodecay. Diffusive-advective transport through foundations and vapor losses caused by foundation cross-flow are considered. Competitive oxygen use by various species is assumed to be proportional to the product of the average dissolved-phase species concentration and a biopreference factor. Laboratory and field data indicate the biopreference factor to be proportional to the organic carbon partition coefficient for the fuel hydrocarbons studied. Predicted indoor air concentrations were sensitive to soil type and subbase permeability. Lower concentrations were predicted for buildings with shallow foundations caused by flushing of contaminants by cross-flow. NAPL source depletion had a large impact on average exposure concentration. Barometric pumping had a minor effect on indoor air emissions for the conditions studied. Risk-based soil cleanup levels were much lower when biodecay was considered because of the existence of a threshold source concentration below which no emissions occur. Computed cleanup levels at NAPL-contaminated sites were strongly dependent on total petroleum hydrocarbon (TPH) content and COC soil concentration. The model was applied to two field sites with gasoline-contaminated ground water. Confidence limits of predicted indoor air concentrations spanned approximately two orders of magnitude considering uncertainty in model parameters. Measured contaminant concentrations in indoor air were within model-predicted confidence limits.     

Variable near-surface deformation along the Commerce segment of the Commerce geophysical lineament, southeast Missouri to southern Illinois, USA

Recent studies have demonstrated a plausible link between surface and near-surface tectonic features and the vertical projection of the Commerce geophysical lineament (CGL). The CGL is a 5- to 10-km-wide zone of basement magnetic and gravity anomalies traceable for more than 600 km, extending from Arkansas through southeast Missouri and southern Illinois and into Indiana. Twelve kilometers of high-resolution seismic reflection data, collected at four sites along a 175-km segment of the CGL projection, are interpreted to show varying amounts of deformation involving Tertiary and some Quaternary sediments. Some of the locally anomalous geomorphic features in the northern Mississippi embayment region (i.e., paleoliquefaction features, anomalous directional changes in stream channels, and areas of linear bluff escarpments) overlying the CGL can be correlated with specific faults and/or narrow zones of deformed (faulted and folded) strata that are imaged on high-resolution seismic reflection data. There is an observable change in near-surface deformation style and complexity progressing from the southwest to the northeast along the trace of the CGL. The seismic reflection data collaborate mapping evidence which suggests that this region has undergone a complex history of deformation, some of which is documented to be as young as Quaternary, during multiple episodes of reactivation under varying stress fields. This work, along with that of other studies presented in this volume, points to the existence of at least one major crustal feature outside the currently defined zone of seismic activity (New Madrid Seismic Zone) that should be considered as a significant potential source zone for seismogenic activity within the midcontinent region of the United States.     

Remote sensing and geomorphometry for studying relief production in high mountains

Mountain topography is the result of highly scale-dependent interactions involving climatic, tectonic, and surface processes. No complete understanding of the geodynamics of mountain building and topographic evolution yet exists, although numerous conceptual and physical models indicate that surficial erosion plays a significant role. Mapping and assessing landforms and erosion in mountain environments is essential in order to understand landscape denudation and complex feedback mechanisms. This requires the development and evaluation of new approaches in remote sensing and geomorphometry. The research herein evaluates the problem of topographic normalization of satellite imagery and demonstrates the use of terrain analysis using a digital elevation model (DEM) to evaluate the relief structure of the landscape in the western Himalaya. We specifically evaluated the Cosine-correction and Minnaert-correction methods to reduce spectral variation in imagery caused by the topography. Semivariogram analyses of the topography were used to examine the relationships between relief and surface processes. Remote-sensing results indicate that the Minnaert-correction method can be used to reduce the “topographic effect” in satellite imagery for mapping, although extreme radiance values are the result of not accounting for the diffuse-skylight and adjacent-terrain irradiance. Geomorphometry results indicate that river incision and glaciation can generate extreme relief, although the greatest mesoscale relief is produced by glaciation at high altitudes. At intermediate altitudes, warm-based glaciation was found to decrease relief. Our results indicate that glaciation can have a differential influence on the relief structure of the landscape. Collectively, our results indicate that scale-dependent analysis of the topography is required to address radiation transfer issues and the polygenetic nature of landscape denudation and relief production.     

Preserving Ground Water Samples With Hydrochloric Acid Does Not Result in the Formation of Chloroform

Water samples collected for the determination of volatile organic compounds (VOCs) are often preserved with hydrochloric acid (HCl) to inhibit the biotransformation of the analytes of interest until the chemical analyses can he performed. However, it is theoretically possible that residual free chlorine in the HCl can react with dissolved organic carbon (DOC) to form chloroform via the haloform reaction. Analyses of 1501 ground water samples preserved with HCl from the U.S. Geological Survey's National Water-Quality Assessment Program indicate that chloroform was the most commonly detected VOC among 60 VOCs monitored. The DOC concentrations were not significantly larger in samples with detectable chloroform than in those with no delectable chloroform, nor was there any correlation between the concentrations of chloroform and DOC. Furthermore, chloroform was detected more frequently in shallow ground water in urban areas (28.5% of the wells sampled) than in agricultural areas (1.6% of the wells sampled), which indicates that its detection was more related to urban land-use activities than to sample acidification. These data provide strong evidence that acidification with HCl does not lead to the production of significant amounts of chloroform in ground water samples. To verify these results, an acidification study was designed to measure the concentrations of all trihalomethanes (THMs) that can form as a result of HCl preservation in ground water samples and to determine if ascorbic acid (C₆H₈O₆) could inhibit this reaction if it did occur. This study showed that no THMs were formed as a result of HCl acidification, and that ascorbic acid had no discernible effect on the concentrations of THMs measured.