New terrestrial heat flow map of Europe after regional paleoclimatic correction application

Heat flow variations with depth in Europe can be explained by a model of surface temperature changes >10°C. New heat flow map of Europe is based on updated database of uncorrected heat flow values to which paleoclimatic correction is applied across the continent. Correction is depth dependent due to a diffusive thermal transfer of the surface temperature forcing of which glacial–interglacial history has the largest impact. It is obvious that large part of the uncorrected heat flow values in the existing heat flow databases from wells as shallow as few hundreds of meters is underestimated. This explains some very low uncorrected heat flow values 20–30 mW/m² in the shields and shallow basin areas of the craton. Also, heat flow values in other areas including orogenic belts are likely underestimated. Based on the uncorrected and corrected heat flow maps using 5 km × 5 km grid, we have calculated average heat flow values (uncorrected heat flow: 56.0 mW/m²; SD 20.3 mW/m² vs. corrected heat flow: 63.2 mW/m²; SD 19.6 m/Wm²) and heat loss for the continental part. Total heat loss is 928 E09 W for the uncorrected values versus corrected 1050 E09 W.     

Climate change inferred from analysis of borehole temperatures: First results from Alberta Basin,Canada

High quality temperature measurements have been made to depths of 30 to 220 m at 42 sites in 62 observational hydrogeological wells in Alberta. The temperature profiles commonly show near-surface inversions with a minimum temperature at depths of 30 to 50 m. Thermal modelling suggests a surface temperature history with warming reaching 2°C over the past 30 to 60 years. Recent climate warming evident from the analysis of the air temperature data in the region seems to provide at least a partial explanation of the increased ground temperatures. A sudden increase of the surface ground temperature caused by land clearing may be the other explanation, although modelling of such a sudden increase can only explain the observed temperature-depth data if the onset of such warming is 20–30 years old, which is in disagreement with the history of land development in the studied area. The effect of near-surface inversions of the temperature profiles also has been observed in the forested areas. The above support the climate based effect. The superposition of the climatic effect and man-made activity effect upon the ground warming is a very complicated process calling for considerably more research.     

The geothermal regime of the northern Yukon and Mackenzie delta regions of northwest Canada — studies of two regional profiles

Temperature data from deep petroleum exploration wells and thermal conductivity estimates based on net rock analysis data have been used to make terrestrial heat flow estimates along two profiles across the sedimentary strata of the Mackenzie Delta, northern Yukon, and offshore Beaufort Sea regions.Both profiles exhibit low heat flow values that range from 34 mWm^–2 to 58 mWm^–2, and little change occurs over large distances in the continental part of the area. Low heat flow values (<40 mWm^–2) occur in the Beaufort-Mackenzie Basin and Rapid Depression, both of which are areas of thick successions of Cretacecus and Tertiary clastic sedimentary strata. High heat flow values of almost 80 mWm^–2 occur to the south in the Taiga Nahoni Foldbelt and values as high as 60 mWm^–2 are indicated along the Aklavik Arch Complex, northeast of Aklavik.The regional variations of effective thermal conductivity are insufficient to account for the heat flow variations along the profiles, and so these may indicate deep radiogenic or other heat sources.     

Experimental studies of sublimation of highly volatile ices in relevance to the ices of the solar system

Studies of sublimation of complex ices prepared by deposition of gaseous CO, CH₄, N₂, and NH₃ molecules on a cold plate have been performed. The low pressure and low temperature system was used: 10^?9–10^?5 mbar and the lowermost temperature 10 K. Diagnostic of composition of evaporates (at an actual temperature) was done by means of the mass spectrometer. The latter allowed following simultaneously the partial pressure of five different ions or radicals escaping from the substrate. It has been found that highly volatile molecules that were used simultaneously with the low volatile ones to form the complex ices (mixtures or clathrates) present a different sublimation pattern than the sublimation of pure high-volatile ices. In particular, the high-volatile component sublimes at two or even three different temperature regimes: At low temperature that is typical for sublimation of this component, as well as at much higher temperatures. This effect seems to be important when degassing and outbursts from cometary nuclei are considered. It can be also important for modeling of cryovolcanic processes on the icy satellites.     

Modelling of Shape Changes of the Nuclei of Comets C/1995 O1 Hale–Bopp and 46P/Wirtanen Caused by Water Ice Sublimation

The aim of this modelling work is to assess shape changes of cometary nuclei caused by sublimation of ices. The simplest possible model is assumed with the nucleus being initially spherical and its thermal conductivity being neglected. We have calculated the time-dependent sublimation flux versus cometographic latitude. If the rotation axis of the comet is inclined to the orbital plane, then sublimation leads to non-symmetrical changes of the nucleus shape. Calculations were performed for the nuclei of comets Hale–Bopp and Wirtanen.     

Palaeo- and rock-magnetic investigations across Jurassic-Cretaceous boundary at St Bertrand’s Spring,Drôme,France: applications to magnetostratigraphy

Palaeo- and rock-magnetic investigations of the St Bertrand’s Spring (Le Ravin de Font de St Bertrand) locality in France were carried out in order to contribute to, and improve, the stratigraphy of the Jurassic-Cretaceous boundary interval. Magnetic susceptibility shows slightly diamagnetic behaviour in the lowermost part of the profile and an increase (paramagnetic) towards its middle and upper parts. Rock-magnetic measurements throughout the section show magnetite as the main magnetic fraction, together with traces of hematite. Additionally, thermal demagnetization indicates the presence of goethite. Our magnetostratigraphy indicates three normal/reversed polarity sequences; possibly encompassing the magnetozones M19r to the M17n. This suggests that the St Bertrand section straddles the Tithonian/Berriasian boundary and reaches the middle Berriasian sensu lato.     

Natural Gas Hydrates in the Offshore Beaufort–Mackenzie Basin—Study of a Feasible Energy Source II

In the offshore part of Beaufort–Mackenzie Basin depth of methane hydrate stability reaches more than 1.5 km. However, there are areas in the western part of the basin where there are no conditions of methane hydrate stability. Construction of the first contour maps displaying thickness of hydrate stability zones as well as hydrate stability zone thicknesses below permafrost in the offshore area, shows that these zones can reach 1200 m and 900 m, respectively. Depth to the base of ice-bearing relict permafrost under the sea (depth of the –1°C isotherm-ice-bearing permafrost base) and regional variations of geothermal gradient are the main controlling factors. Hydrostatic pressures in the upper 1500 m are the rule. History of methane hydrate stability zone is related mainly to the history of permafrost and it reached maximum depth in early Holocene. More recently, the permafrost and hydrate zone is diminishing because of sea transgression. Reevaluation of the location of possible gas hydrate occurrences is done from the analysis of well logs and other indicators in conjunction with knowledge of the hydrate stability zone. In the offshore Beaufort–Mackenzie Basin, methane hydrate occurs in 21 wells. Nine of these locations coincides with underlying conventional hydrocarbon occurrences. Previous analyses place some of the hydrate occurrences at greater depths than proposed for the methane hydrate-stability zone described in this study. Interpretation of geological cross sections and maps of geological sequences reveals that hydrates are occurring in the Iperk–Kugmallit sequence. Hydrate–gas contact zones, however, are possible in numerous situations. As there are no significant geological seals in the deeper part of the offshore basin (all hydrates are within Iperk), it is suggested that overlying permafrost and hydrate stability zone acted as the only trap for upward migrating gas during the last tens of thousand of years (i.e., Sangamonian to Holocene).     

Origin of diffuse interstellar bands: spectroscopic studies of their possible carriers

The results of astrophysical observations that provide evidence for the molecular origin of the diffuse interstellar bands (DIBs) are reviewed. It is established that molecular systems with a linear, planar or spherical carbon skeleton are good candidates as DIB carriers, and laboratory spectroscopic data concerning such systems are discussed. The characteristic features of the electronic spectra of fullerenes, polycyclic aromatic hydrocarbons, and of linear carbon chains and their ions are found to be consistent with the principal spectroscopic features of DIBs. Analysis of the astrophysical electronic spectra of several simple molecules that have so far been assigned indicates that polar molecules should be easier to detect in this way than those without a permanent electric dipole moment.     

Large ground surface temperature changes of the last three centuries inferred from borehole temperatures in the Southern Canadian Prairies, Saskatchewan

New temperature logs in wells located in the grassland ecozone in the Southern Canadian Prairies in Saskatchewan, where surface disturbance is considered minor, show a large curvature in the upper 100 m. The character of this curvature is consistent with ground surface temperature (GST) warming in the 20th century. Repetition of precise temperature logs in southern Saskatchewan (years 1986 and 1997) shows the conductive nature of warming of the subsurface sediments. The magnitude of surface temperature change during that time (11 years) is high (0.3–0.4°C). To assess the conductive nature of temperature variations at the grassland surface interface, several precise air and soil temperature time series in the southern Canadian Prairies (1965–1995) were analyzed. The combined anomalies correlated at 0.85. Application of the functional space inversion (FSI) technique with the borehole temperature logs and site-specific lithology indicates a warming to date of approximately 2.5°C since a minimum in the late 18th century to mid 19th century. This warming represents an approximate increase from 4°C around 1850 to 6.5°C today. The significance of this record is that it suggests almost half of the warming occurred prior to 1900, before dramatic build up of atmospheric green house gases. This result correlates well with the proxy record of climatic change further to the north, beyond the Arctic Circle [Overpeck, J., Hughen, K., Hardy, D., Bradley, R., Case, R., Douglas, M., Finney, B., Gajewski, K., Jacoby, G., Jennings, A., Lamourex, S., Lasca, A., MacDonald, G., Moore, J., Retelle, M., Smith, S., Wolfe, A., Zielinski, G., 1997. Arctic environmental change of the last four centuries, Science 278, 1251–1256.].