络合剂淋洗Cu污染粉土的土柱试验研究

以当前我国备受关注的土体污染为背景,通过土柱试验研究了不同络合剂对Cu的淋洗效果,结果表明:乙二胺四乙酸二钠二水合物（ethylenediaminetetraacetic acid disodium saltdihydrate,EDTA）淋洗效果最佳,柠檬酸（citric acid,CIT）次之,氨三乙酸三钠盐单水合物（nitrilotriacetic acid trisodium salt monohydrate, NTA）淋洗效果相对最差;使用不同浓度的EDTA淋洗负载量为150 mg/kg的Cu污染土,浓度增大并未有效促进Cu的解吸,而较小浓度（0.005 mol/L）的EDTA是有效且经济的浓度,其对Cu的去除率达84%;0.015 mol/L的EDTA淋洗不同负载量的Cu污染土,随负载量增加,淋洗率下降,最高去除率为84%,但去除量增加;研究结果可为重金属污染土的淋洗修复工艺提供理论参考依据。     

新疆哈密地区早泥盆世珊瑚动物群及其地质意义

新疆哈密地区下泥盆统发育,南部图拉尔根地区下泥盆统为大南湖组,北部三道白杨沟地区为卓木巴斯套组。在大南湖组中共发现四射珊瑚2属5种,床板珊瑚7属12种,并建立四射珊瑚组合Syringaxon moriense和床板珊瑚组合Pseudofavosites giganteus;在卓木巴斯套组共发现四射珊瑚5属7种,床板珊瑚2属2种,并建立四射珊瑚组合Orthopaterophyllum junggarense和床板珊瑚组合Pachyfavosites junggarensis。通过珊瑚在地层中的分布及组合的时代对比,确定前者的时代为早泥盆世埃姆斯期早期,后者的时代为埃姆斯期中晚期。通过与国内外典型的早泥盆世埃姆斯期珊瑚动物群的对比,认为哈密地区的珊瑚动物具有典型的早泥盆世温带动物群特征,在生物古地理区系上属于北方大区准噶尔-兴安省。     

Volume estimation and stage division of the Mahu landslide in Sichuan Province,China

The Mahu lake, the third deepest lake in China, is located on the west bank of the Jinsha River in Leibo county, Sichuan Province. It is a dammed lake created by an old landslide on the ancient Huanglang river, a tributary on the west bank of the Jinsha River. Previous studies (Wang and Lu in J Mt Res S1:44–47, 2000) suggested that this landslide was caused by an earthquake approximately 372 ka (Middle Pleistocene), during which a few hundreds of million cubic meters of debris were deposited between 1177 and 900 m a.s.l. (above sea level), covering an area of around 15 km². Our further investigations, including geodetic survey, borehole drilling, and field reconnaissance, combining with five chronological data, have made some new discoveries at this site. First, the toe of the landslide extends from 900 m a.s.l. down to 320 m a.s.l., i.e., the local bed elevation of the contemporary Jinsha River. Second, the area of the landslide deposits is 17.3 km² with a volume of 2.38 km³, much larger than the previous estimation. Thus, it should be one of the largest known landslides in China. And the lower elevation of the landslide’s toe also rules out the possibility that it is a hanging valley on the ancient Huanglang river. Our work suggests that this landslide was created by five events according to the overlapping characteristics of the deposits and five chronological data, which are old than 52,600 years, old than 16,000 years, old than 15,500 years, 5800 years, and old than 4200 years, respectively.     

西藏西北部浅变质石英砂岩岩石学特征及其构造意义

羌塘盆地中央隆起带主要由浅变质石英砂岩组成,由于化石匮乏、变形强烈,长期以来对这套浅变质石英砂岩成因的争议颇大,导致了对藏西北地区前中生代构造演化的认识长期模糊不清,其中,何处才是冈瓦纳大陆北界就是一个长期争论的议题。在西藏西北部,近东西走向的布尔嘎错断裂带将北部的查多岗日地块与南部的南羌塘地块分隔开,浅变质石英砂岩广泛出露于这两地块之内。沿近东西走向布尔嘎错断裂带断续产出的冈玛错蓝片岩、蛇绿岩等岩片大体呈南北向逆冲于浅变质石英砂岩之上,因此早期曾认为布尔嘎错断裂带是冈瓦纳大陆之北界。本文的调查与研究发现查多岗日和南羌塘地块内浅变质石英砂岩岩相学特征完全相同,均主要由石英组成,遭受了绿片岩相的变质作用,形成了钠长石+绿泥石+白云母组合,充填于早期石英颗粒之间,钠长石交代钾长石。这两地的浅变质石英砂岩均被未变质钙质胶结的钾长石石英砂岩平行不整合覆盖。碎屑锆石的阴极发光分析与U-Pb定年结果进一步证实了查多岗日与南羌塘地块内浅变质石英砂岩内的锆石来源完全相同。这些证据充分反映了查多岗日与南羌塘地块早期构造演化过程相似,源自同一大陆。碎屑锆石定年结果进一步表明浅变质石英砂岩的最大沉积年龄为520±8Ma,该岩石再被约480Ma的花岗岩脉侵入,因此其很可能形成于晚寒武世,而不整合面之上沉积岩的最大沉积年龄为460±8Ma,表明该不整合面上、下沉积岩之间存在明显的沉积间断,证实了该平行不整合面形成于奥陶纪。不整合面之下的浅变质石英砂岩因此与杨耀等(2014)报道的荣玛组相同,不整合面之上未变质长石石英砂岩则属于中上奥陶统塔石山组。查多岗日地块因此是西藏境内最北端的冈瓦纳大陆的碎块。在西藏西北部,冈瓦纳大陆北界为龙木错-帮达错-(83°40'E、35°N)-红脊山-荣玛乡。布尔嘎错断裂带不是冈瓦纳大陆之北界。     

Network-based triple-frequency carrier phase ambiguity resolution between reference stations using BDS data for long baselines

Network-based ambiguity resolution (AR) between reference stations is the prerequisite to realize a precise real-time kinematic positioning service. With the help of BDS triple-frequency signals, we can efficiently deal with the ionospheric delay and tropospheric delay, and achieve rapid and reliable AR. To overcome the inaccurate ionospheric delay estimated by the geometry-free three carrier ambiguity resolution (GF TCAR) technique, which leads to failure in the original ambiguity resolution, we propose an ionospheric-free (IF) TCAR method to resolve the ambiguity between the reference stations over long baselines. Taking full advantage of the known positions of the reference stations, the easily resolved extra-wide-lane (EWL) ambiguity, and the IF phase combinations, we can reliably fix the wide-lane (WL) ambiguity. A Kalman filter is applied to estimate precise IF ambiguities and the original ambiguity is resolved with the fixed WL ambiguity. A numerical analysis with triple-frequency BDS data from three long baselines of a CORS network is provided to compare the AR performance of GF TCAR with that of IF TCAR. The results show that both methods can reliably resolve the WL ambiguity with a remarkable correctly-fixed rate of higher than 99%, and the reliably-fixed rates of the IF TCAR slightly increase from 92.19, 94.67 and 94.61–98.26, 99.54 and 97.51% for the three baselines. Herein “correctly-fixed” and “reliably-fixed” mean the difference between the float ambiguity and the true one are less than ± 0.5 and ± 0.25 cycles, respectively. On the other hand, the AR performance of the original signals with the IF TCAR method is much better than that with the GF TCAR method attaining a 100% correctly-fixed rate, while the GF TCAR method can hardly fix the original ambiguity with the largest bias being as much as 4 cycles because of the amplified systematic bias.     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

基于阜新市的土壤多样性与土地利用类型关联性分析

以阜新市为研究对象,将土地利用动态演变的模拟和预测以及关联分析测度方法应用于土壤多样性和土地利用类型关联性分析的研究中。选取1985—2015年间8个时期的遥感影像进行土地利用分类,并基于土壤矢量数据,对阜新市土壤和土地利用的多样性进行初步分析和定量化研究,探究了土壤与土地利用之间的关联性。研究结果表明:对阜新市土壤多样性指数影响因子的关联度从大到小依次是城镇、农用地、林地、水域、其他,关联度值分别为0.850 6、0.747 7、0.779 5、0.803 3、0.641 9,选取城镇、农用地、林地和水域这4个因子作为多元线性回归模型中的自变量参数,对土壤多样性指数进行预测,得到相关系数R=0.990,因此,4个因子对土壤多样性指数影响具有较强的关联性。由此可见,大规模土地利用变化是引起土壤多样性变化的一个首要驱动因子。     

基于地理加权模型的农村居民点空间格局及影响因子分析——以湖北省麻城市为例

以湖北省麻城市2009年和2015年农村居民点为研究对象,采用区位指数和核密度测算法对农村居民点空间分布形态进行分析,运用传统最小二乘法和地理加权模型从全域和局部角度分析自然地貌、社会经济、生态限制等因素影响农村居民点空间演变的作用机制。研究得出:麻城市2009—2015年农村居民点用地面积增长率达6.92%,斑块主要以分散式外延扩张为主,空间结构演变总体上呈现沿沪汉蓉快速铁路和武麻公路向四周扩散的连续分布特征。从全域上看,农村居民点分布格局与坡度、公路、建制镇、风景名胜区、河流呈空间负相关关系;从局部影响程度来看,最大正向影响因子为人均收入和高程,负向影响因子主要是坡度和河流,其他影响因子随地理位置变化正负向影响均存在。     

基于独立成分分析的高光谱图像降维及分割

高光谱图像的高维数给图像的进一步处理带来了困难,为了解决这一问题,本文提出了一种基于独立成分分析的高光谱图像降维分割方法。首先,利用波段子空间划分和标准差对高光谱图像预处理,选择部分波段的高光谱图像作为实验对象;然后利用基于负熵的快速不动点算法对实验数据解混,再根据平均绝对权重系数对波段排序并选取;最后使用模糊C均值聚类算法对降维后的图像进行分割。实验结果表明,该方法能够有效实现高光谱图像降维,并获得较好的分割结果。     

黄骅坳陷古生界潜山储层沥青成因判识

正黄骅坳陷古生界潜山是大港油田重要的油气勘探领域,近年来,先后在王官屯、乌马营潜山古生界发现油气流,且均为石炭—二叠系煤系源岩供烃成藏,如王官屯潜山王古1井二叠系石盒子组发现天然气,同位素特征判断为煤成天然气。这些发现拓展了古生界潜山的勘探领域,表明了石炭—二叠系煤系烃源岩的油气充注范围不仅仅局限于奥陶系碳酸盐岩储层,石炭—二叠系的碎屑岩储层也可以充注成藏,证实了古生界潜山具有更大的油气勘探价值。随着勘探进程与理论认识的不断深化,