雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Geometric Derivation of the Delaunay Variables and Geometric Phases

We derive the classical Delaunay variables by finding a suitable symmetry action of the three torus T³ on the phase space of the Kepler problem, computing its associated momentum map and using the geometry associated with this structure. A central feature in this derivation is the identification of the mean anomaly as the angle variable for a symplectic S ¹ action on the union of the non-degenerate elliptic Kepler orbits. This approach is geometrically more natural than traditional ones such as directly solving Hamilton–Jacobi equations, or employing the Lagrange bracket. As an application of the new derivation, we give a singularity free treatment of the averaged J ₂-dynamics (the effect of the bulge of the Earth) in the Cartesian coordinates by making use of the fact that the averaged J ₂-Hamiltonian is a collective Hamiltonian of the T³ momentum map. We also use this geometric structure to identify the drifts in satellite orbits due to the J ₂ effect as geometric phases.     

CORROSION AND ADHERENCE AT SEA OIL-PLATFORM

Measurements of the adhesive corrosion and protective potentials of 3 Bohai Sea oilplatforms under different cathodic protection showed corrosion still occurred on these platforms undertheir designed protective potentials. Preliminary conclusions from indoor experiments on the relation betweenadhesive corrosion and cathodic protection showed adhering organisms caused the corrosion onthese platforms.     

沉积物粒度分析在厦门市第四纪环境研究和地层划分对比中的应用

采用MS2000型激光粒度分析仪进行测试，利用计算机粒度分析软件对数据进行整理和计算，绘制出样品的频率曲线、概率累积曲线以及粒度众数位值曲线等图件并进行沉积环境分析。厦门地区第四纪环境演化经历了中更新世同安组(含泥中粗砂、含泥细中砂、砂为主)海积一冲积一更新统上部龙海组(含泥粗中砂、含泥细中砂、含泥粗砂、粗砂、细中砂、含细砾中粗砂、中细砂等)冲积一洪冲积一更新世上部东山组(砂、砂砾、含泥中粗砂、粗砂、泥质中细砂、细砂、中粗砂等)冲洪积及部分海积(粉砂、细粉砂、含碳质泥、粘土、淤泥质粘土、粉砂质粘土等)一全新世长乐组(粉砂，淤泥质粘土、粉砂质粘土、碳质粘土、含砂淤泥质粘土，粉砂质亚粘土、粉细砂亚粘土等)海湾沉积。在解释环境变化的同时，说明粒度变化曲线在一定程度上可以作为地层划分的依据之一，并以此对研究区地层进行了详细划分。     

太阳表面米粒结构观测对比度分析

分析以观测系统焦面上和探测器测到的太阳表面米粒结构的对比度与观测系统口径，大气湍流相干长度以及系统探测灵敏度的关系，给出了不同口径，不同大气湍流相干长度以及不同系统探测灵敏度时的米粒结构对比值计算结果，此外还给出了实验结果。     

Magnetic susceptibility variations of the Edicaran cap carbonates in the Yangtze platform and their implications for paleoclimate

1 INTRODUCTION One of the most intriguing phenomena in the late Neoproterozoic (~750 to 543 Ma) is the globa occurrence of thin carbonates that directly overlie glacial deposits in almost every continent (Kennedy 1996; Hoffman et al., 1998; Hoffman and Schrag 2002; Brasier and Shields, 2000; James et al., 2001 Jiang et al., 2003; Nogueira et al., 2003). These “cap carbonates”, commonly several to tens of meters thick, have attracted enormous interests because o their unusually negati…     

Theory of quadrupolar sunspots and the active region of August, 1972

Energy is stored when the force-free magnetic field in an active region departs from a potential field, the departure showing up as a shear in the field. As soon as the field untwists, energy will be released to produce flares. Based on this idea, we derived an analytical solution of the equation of force-free field under the assumption of a constant force-free factor, and found expressions for seven important quantities for quadrupolar sunspots: the magnetic energy of the twisted field, that of potential field, the extractable free energy ΔM, the magnetic flux, the total current, the force-free factor and the field decay factor, in terms of three observables: the field intensity, the twist angle and the distance between two spots of the same polarity. The expression for ΔM can be useful in solar prediction work. For the active region of August, 1972, we found ΔM up to 6 × 10³² erg, sufficient to supply the energy of the observed flare activity. Observations of this active region are in good general agreement with our theoretical expectations: in the entire twisting of the quadrupolar sunspot group, each spot assumes the form of a complete spiral in the clockwise direction for each of the four spots.     

土壤中氟的形态分析

以宁夏盐池地区高氟土壤为例,采用连续提取法对土壤样品中各形态氟进行提取,离子色谱法测定各形态氟的含量。根据研究目的及土壤特点将氟的形态划分为水溶态、离子交换态、可还原态、可氧化态及残渣态5种形态;对各种形态连续提取过程中使用的提取液进行了选择。采用建立的方法获得提取土壤中F-的检出限为0.76μg/g;方法精密度(RSD,n=7)各形态氟为水溶态氟11.3%,离子交换态氟13.5%,可还原态氟10.7%,可氧化态氟8.9%。     

火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。