Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.     

GPS双频相位平滑伪距在卫星预报钟差精度评定中的应用

利用Hatch滤波对双频消电离层组合伪距观测值进行相位平滑讨论,对原Hatch滤波公式中的定权方法进行了改进.在此基础上,利用伪距与星地距比对法对广播星历中卫星预报钟差精度评定进行了研究.计算结果表明:载波相位平滑能有效地提高伪距观测量的精度,从而提高伪距与星地距比对法评估卫星预报钟差的可行性.利用双频消电离层相位平滑伪距计算的卫星钟差精度优于1 ns(1σ),测定的卫星钟差与实际卫星钟差不存在系统差.     

济南张夏组灰岩岩溶地下水供水潜力探讨

济南南部广布巨厚张夏组灰岩,其中赋存优质丰富的岩溶地下水。出露众多泉水,其流量为800～8000m3/d。该文通过简述济南地区张夏组灰岩岩溶地下水的赋存条件与水文地质特征,概略计算与评价其资源量,论证开发利用这一新水源的可行性,以期为济南供水与保泉开辟新途径。     

山东苍山王埝沟铁矿床地质特征及找矿方法探讨

王埝沟铁矿床为隐伏矿床,产于泰山岩群山草峪组地层中,发育2条主矿带,总体走向为280°-290°,平行展布,相向而倾,具不对称向斜构造特征。该铁矿床2条主矿带发育5个矿体,北翼矿带发育3个矿体,南翼矿带发育2个矿体,矿体呈层状、似层状产出,产状与地层产状一致。综合分析研究成矿地质条件及区域成矿理论,并充分利用地面高精度磁法剖面测量成果,二者有机结合的综合式找矿方法,是目前寻找深部沉积变质型“鞍山式”铁矿盲矿体行之有效的方法。     

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How forest gaps shaped plant diversity along an elevational gradient in Wolong National Nature Reserve?

Journal of Geographical Sciences - Understanding the underlying ecological processes that control plant diversity within (α-diversity) and among (β-diversity) forest gaps is important for...     

北斗三号组网卫星数据质量分析及单系统定轨精度初步评估

选取2018-01-23起10 d内16个iGMAS测站观测数据,对北斗三号卫星的观测数据质量及BDS单系统精密定轨精度进行评估。初步结果表明,老信号B1I、B3I北斗三号卫星的信噪比略强于二号卫星,噪声与多路径基本相当,均在0.1 m量级,新卫星不存在星内多路径偏差。新信号B1C/L1/E1频点GPS信噪比最强,Galileo和BDS卫星相当,B2a/L5/E5a和B2b/E5b各系统基本相当;噪声及多路径方面,B1C/L1/E1频点GPS优于BDS、Galileo卫星0.1 m量级,B2a/L5/E5a和B2b/E5b各系统基本相当,均在0.1 m量级,新信号中北斗三号卫星星内多路径偏差基本消失。单系统精密定轨试验中,分别进行有/无GEO卫星策略、太阳光压模型ECOM 五/九参数策略的比较,并使用卫星激光测距数据进行独立检核。初步结果表明,有GEO卫星、ECOM五参数光压模型的定轨精度最好,C19号卫星7个重叠弧段的平均定轨精度在沿迹向、法向、径向的精度分别为32 cm、16 cm、8 cm,与试验卫星的定轨精度基本相当。     

Different provenance of separate loess sites in Yangtze River Basin and its paleoenvironmental implications

The dust deposits in the Yangtze River Basin(YRB) have been widely distributed along the Yangtze River valley. Previous studies mainly concentrated in its provenance of each loess site,however, the differences in provenance of loess among different sites in this area have rarely been studied. Here, the geochemical characteristics of the20 μm fraction in the loess in separate Jiujiang,Xuancheng and Nanjing sites were analyzed. The result shows that the loess in Jiujiang and Nanjing sites, near Yangtze River riverway, share similar geochemical characteristics that may commonly derived from the detrital materials of Yangtze River.However, both sites have significantly different elemental compositions compared with Xuancheng site, which is ～60 km away from the Yangtze River riverway. These sites share different geochemical characteristics with Eastern Qinling Mountains and Xifeng section on the Chinese Loess Plateau, North China. Combining the distribution of the aeolian sand hills and the loess in this area published by previous studies, we suggest that the exposed river valley floodplain caused by weak summer monsoon provided abundant materials to form local dust cells controlled by strong winter monsoon during the glacial periods. Therefore, those local loess deposits should be identified as the "valley-sourced loess".These reveal the inherent connection between the monsoon system and the loess deposits in Yangtze River Basin.     

贵州省市州域经济差异的时空演变

区域经济差异一直是国内外研究的热点,本文以贵州省9个市州为研究单位,选取10个经济发展指标,运用全局主成分分析,结合GIS技术,测度了贵州省9个市州域2006～2016年10年来经济差异的时空演变。结果表明:贵州省各市州区域经济内部差异明显,经济增长存在较强空间关联性,上升区与下降区均集中分布;各项指标数值相对比较大的地区,最终得分不一定高。