Review of evidence for late Tertiary shorelines occurring on South Atlantic coasts

Recognition of (late) Tertiary shorelines on continental coasts is becoming increasingly common. It is argued that the elevations of such features are central to their approximate dating and the demonstration of contemporaneity with similar features elsewhere. South Atlantic coasts have not had a long history of investigation, yet there exist many diffuse observations, in both time and space, which are here drawn together into a preliminary synthesis and the case for widespread occurrences of late Tertiary shorelines in the region reviewed. This allows comparison with other areas from which Tertiary shorelines are known, the Atlantic seaboards of the Southeastern United States and Northwest Europe, for example.The coasts of oceanic islands are probably the best places to examine the legacy of late Cenozoic sea-level changes. It is suggested that, since many of the cliffed shores of these islands appear to be the result of a rapid emergence, coastal features predating this event might be preserved on the cliff-tops. Possible late Tertiary shorelines from South Atlantic islands are described, as are those which have been positively dated to this period, in the Eastern Canary Islands, for instance. Sedimentary and morphological indicators of Tertiary high sea-levels are described from Antarctic coasts. South American and African Atlantic continental margins. Evidence from the latter two areas is most suspect, owing to their generally more complex Quaternary tectonic histories. A summary of the evidence for Tertiary shorelines on South Atlantic coasts is tabulated.Methods which have been or could be used to date late Tertiary shorelines are described. Minimum age can be deduced from that of deposits resting on an erosional surface, maximum age from that of the youngest formation across which a surface is cut. More precise age can be estimated where a marine surface is sandwiched between datable non-marine formations or where periods of tectonic activity (responsible for differential surface deformation) can be dated. Elevations of surfaces can be used to estimate ages. Problems in both recognising and dating Tertiary shorelines are discussed. Recognition of their origin is made more difficult by their degraded state and, if they occur within a Quaternary erosional sequence, their antiquity may not be realised.It is suggested that fluctuations in the Antarctic ice sheet during the late Tertiary induced substantial glacio-eustatic changes of sea-level which may have been most marked in adjacent areas. This is considered to be the mechanism through which late Tertiary shorelines in the area were formed yet, considering the paucity of the morphological and sedimentary data, these should not be used as the basis for a eustatic chronology.     

NDCI法Ⅱ类水体叶绿素a浓度高光谱遥感数据估算

以太湖、巢湖为研究区,以Hyperion和HJ-1A卫星HSI高光谱数据以及实测水质浓度数据为实验数据,引入归一化叶绿素指数(NDCI),对Ⅱ类水体的高光谱叶绿素a浓度估算进行分析研究.首先对高光谱数据的光谱通道设置以及水体光谱特征进行分析,研究确定模型的最优波段.然后,将确定最优波段后的NDCI反射率因子作为变量与实测样本点数据进行回归分析,得到NDCI与叶绿素a浓度之间的回归关系,进行叶绿素a浓度的估算.与常用的比值法、一阶微分法和三波段法相比,NDCI的性能优于这3种方法,表明NDCI是一种计算简单、估算精度高、实用性强的Ⅱ类水体叶绿素a浓度估算方法.     

块系岩体间黏弹性性质对摆型波传播的影响

基于深部非连续自应力等级块系岩体构造理论,研究冲击载荷在块系岩体中以摆型波形式传播时岩块间黏弹性性质对摆型波传播的影响。当岩块间具有五种不同黏弹性性质时,通过对块系岩体的始端和末端区域中间岩块加速度响应计算及各岩块加速度正负摆幅幅值分析可知：岩块间黏性变化时,对岩块加速度衰减周期没有影响,但黏性增大时各岩块正负摆幅下降幅度比黏性周期增大时大;岩块间弹性变化时岩块加速度衰减周期均发生变化,但弹性减小时正负摆幅值向平衡位置平移,弹性周期减小时块系岩体的前半部分岩块正负摆幅曲线均出现波动且负摆波动较大,岩块间弹性梯级增大时,岩块加速度迅速衰减,同时各岩块加速度的正负摆幅曲线在初始端区域出现波动。     

Estimating periphyton standing crop in streams: a comparison of chlorophyll a sampling and visual assessments

Periphyton standing crop is often measured as chlorophyll a but there is increasing interest in using visual assessments of periphyton cover. Visual methods are rapid and require no sample analysis, but can be regarded as subjective with high inter-operator variability. We investigated variability in periphyton standing crop across operators, rivers and time, as determined visually and from chlorophyll a measurements. We found that visual assessments (comprising percentage cover estimates of up to eight periphyton categories) distinguished sites and occasions as effectively as chlorophyll a. Furthermore, an estimate of chlorophyll a could be derived from the visual assessments. Because our surveys were conducted in only three rivers, general applicability of the derivation of estimated chlorophyll a from the visual assessments warrants further investigation. The current recommendation of 20 views was sufficient for realistic visual assessments of average cover. Overall, our results indicated that inter-operator variability in visual assessments need not be a major concern, given adequate training.     

The ‘suitcase hypothesis’: Can entrainment of meroplankton by eddies provide a pathway for gene flow between Madagascar and KwaZulu-Natal,South Africa?

Similarities in the marine fauna found off the coasts of southern Madagascar and KwaZulu-Natal Province (KZN), South Africa, led to the development of the ‘suitcase project,’ with the aim of establishing whether eddies that form off southern Madagascar may package and transport biological material across the Mozambique Channel, facilitating connectivity and gene flow. Meroplankton (larval stages of fishes and benthic invertebrates) were collected on the Madagascan shelf and along a transect through a cyclonic eddy in the Mozambique Channel. The samples were analysed using microscopy and DNA barcoding, seeking to identify species known to be common to both the southeast coast of Madagascar and the east coast of South Africa and thereby to reveal potential indicators of connectivity between these regions. The greatest zooplankton biovolume in the upper 200 m occurred on the shelf, followed by in the western part of the eddy and in the region outside the eddy to the west, and was lowest in the region outside the eddy to the east. The meroplankton were dominated by taxa of coastal origin and these were also most abundant on the shelf and in the western part of the eddy, with the lowest abundances in the region outside the eddy to the east. The findings show greater zooplankton biovolumes and larval abundances and the presence of reef-associated larval assemblages on the Madagascan shelf and along the transect through the cyclonic eddy, providing support for the suitcase hypothesis that planktonic organisms are entrained within eddies as they propagate south-westwards of the Madagascan shelf.     

Misperceptions of climate-change risk as barriers to climate-change adaptation: a case study from the Rewa Delta, Fiji

While increasing research is focusing on the effective adaptation to climate change in richer (developed) countries, comparatively little has focused specifically on this subject in poorer (developing) countries such as most in the Pacific Islands region. A significant barrier to the development of effective and sustainable adaptive strategies for climate change in such places is the gap between risk and perceived risk. This study looks at a vulnerable location in Fiji—the densely populated Rewa River Delta where environmental changes resulting from shoreline retreat and floods are expected to increase over the next few decades and entail profound societal disruption. The numbers of people living in the Rewa Delta who know of climate change and could correctly identify its contributory causes are few although many rank its current manifestations (floods, riverbank erosion, groundwater salinization) as among their most serious environmental challenges. While lack of awareness is a barrier to adaptation, there are also cultural impediments to this such as short-term planning perspectives, spiritual beliefs, traditional governance structures. One way forward is to empower community leaders in places like the Rewa Delta to make appropriate decisions and for regional governments to continue working together to find solutions that acknowledge the variation in sub-regional trans-national vulnerability to climate change.     

Theoretical studies on metal thioarsenites and thioantimonides: synergistic interactions between transition metals and heavy metalloids

Recently we established that the ternary complex, CuAsS(SH)(OH) has an unusually high stability and makes a large contribution to the total concentrations of both Cu and As in sulfidic solutions equilibrated with Cu and As sulfide minerals. This ternary complex has an unusual structure, containing a bond which is formally Cu(I)–As(III), along with a broken As–S bond. We have now found that complexes with similar structures exist for Au⁺ and Tl⁺ coordinated to AsS(SH)(OH)^-. However, such a direct metal–metalloid bond is not a requirement for stability. In fact, TlAsS(SH)(OH) is unstable while AuAsS(SH)(OH) is highly stable (compared to the aquo ion). Zn²⁺, Cd²⁺, Hg²⁺ and Pb²⁺ also form bonds to the As of AsS(SH)(OH), but without breaking any As–S bonds, and HgAsS(SH)(OH)⁺ and PbAsS(SH)(OH)⁺ are particularly stable complexes. Calculated structures are shown for these complexes, gas-phase energies are calculated, and formation constants in aqueous solution are estimated. The SbS(SH)(OH)^- ion forms analogous complexes, with similar stabilities. However, the Au⁺ complex of SbS(SH)(OH)^- is slightly less stable than the Cu⁺ complex, opposite to the order found for the AsS(SH)(OH)^- ligand. The Au⁺ and AuSH complexes of AsSSHOH^- or AsS(SH)₂ ^- may be implicated in "invisible gold" in arsenian pyrites. Vibrational frequencies are given for the AuAsS(SH)₃ ^- complex and the XANES energies of this complex and Au(SH)₂ ^- are compared. The existence of such strong complexes may explain the many correlations observed between the concentrations of coinage metals and metalloids.     

A theory of VLF emissions

The work attempts to give a theoretical explanation of the triggering of VLF emissions by magnetospheric whistler morse pulses. First studied is the behaviour of resonant particles in a whistler wave train in an inhomogeneous medium. It is found that second order resonant particles become stably trapped in the wave. After 1–2 trapping periods such particles dominate the resonant particle distribution function, and produce large currents that are readily estimated.     

Migration pathways in the Central North Slope foreland basin, Alaska USA: solute and thermal constraints on fluid flow simulations

The North Slope foreland basin, Alaska, USA is an east–west asymmetrical trough‐shaped basin adjacent to the Brooks Range fold‐thrust mountain belt. Lower Cretaceous age rocks make up much of the sediment fill, including flysch‐like marine turbidites and shales of the Torok and Fortress Mountain formations and marine and sandstones, shales and conglomerates of the overlying Nanushuk group. Lower Cretaceous age rocks were deposited on top of a Palaeozoic and Mesozoic age passive margin sequence. We have conducted numerical simulations of fluid flow driven by topographic recharge in the Central North Slope foreland basin. These simulations are constrained by salinity estimates from well logs, location of oil and gas fields, vitrinite reflectance and heat flow measurements. Our model results indicate that there are two south to north pathways for fluid migration. The primary pathway for fluid movement is downward through the Fortress Mountain formation, then upwards along the interface between the Fortress Mountain and Torok Formation and finally northward through the permeable Nanushuk group. A smaller mass of groundwater moves along sands below the Torok formation and into offshore sediments north of Alaska. Very little meteoric water enters the underlying Palaeozoic rocks in our simulations, which could explain the presence of deep saline pore waters. Our results also show that permafrost is a primary control on the pathway and rate of fluid flow by controlling the distribution of surface recharge and discharge. For example, areas of high heat flow and low saline waters along the arctic coast may represent upward groundwater discharge because of the absence of permafrost. As surface temperatures were warmer in the Miocene, the absence of permafrost would produce a more local fluid circulation pattern and less transfer of heat energy from south to north.