Reventador Volcano 2005: Eruptive activity inferred from seismo-acoustic observation

Reventador Volcano entered an eruptive phase in 2005 which included a wide variety of seismic and infrasonic activity. These are described and illustrated: volcano-tectonic, harmonic tremor, drumbeats, chugging and spasmodic tremor, long period and very long period events. The recording of this simultaneous activity on an array of three broadband, seismo-acoustic instruments provides detailed information of the state of the conduit and vent during this phase of volcanic eruption. Quasi-periodic tremor at Reventador is similar to that observed at other volcanoes and may be used as an indicator of vent aperture. Variations in the vibration modes of the volcano, frequency fluctuations and rapid temporal fluctuations suggest the influx of new material, choking of the vent and possible modification of the conduit geometry during explosions and effusion over a period of six weeks.     

NDCI法Ⅱ类水体叶绿素a浓度高光谱遥感数据估算

以太湖、巢湖为研究区,以Hyperion和HJ-1A卫星HSI高光谱数据以及实测水质浓度数据为实验数据,引入归一化叶绿素指数(NDCI),对Ⅱ类水体的高光谱叶绿素a浓度估算进行分析研究.首先对高光谱数据的光谱通道设置以及水体光谱特征进行分析,研究确定模型的最优波段.然后,将确定最优波段后的NDCI反射率因子作为变量与实测样本点数据进行回归分析,得到NDCI与叶绿素a浓度之间的回归关系,进行叶绿素a浓度的估算.与常用的比值法、一阶微分法和三波段法相比,NDCI的性能优于这3种方法,表明NDCI是一种计算简单、估算精度高、实用性强的Ⅱ类水体叶绿素a浓度估算方法.     

Stratigraphy and sedimentology of the Upper Cretaceous to Paleogene Kilwa Group, southern coastal Tanzania

The geology of southern coastal Tanzania has remained poorly understood since the first comments on its stratigraphy were made over 100 years ago. However, new field surveys combined with shallow drilling along the coast between Kilwa and Lindi are beginning to resolve the depositional history and structural evolution of this region over the past 85 Ma. Here we present the first attempt to synthesize the results of these studies to provide a coherent sedimentological, litho- and sequence stratigraphic framework, including new geological maps, for the Upper Cretaceous and Paleogene of the coastal zone.Santonian to Oligocene sediments crop out along a broad coastal belt south of the Rufiji River from the Kilwa peninsula to Lindi Creek in southern Tanzania. During 55 Ma, over 1 km of a broadly homogeneous, mid to outer shelf clay-dominated succession was deposited across the passive margin, which we define here as the Kilwa Group. This lies disconformably across the shelf on Albian marls and is itself unconformably overlain by shallow water Miocene clays and more recent limestones, sands and gravels. Four formations can be identified within the Kilwa Group on the basis of characteristic secondary lithologies and facies, described here for the first time; the Nangurukuru, Kivinje, Masoko and Pande Formations. These formations include conformable stratigraphic intervals through both the Paleocene–Eocene and Eocene–Oligocene boundaries. Within the Kilwa Group, 12 sequence stratigraphic cycles can be identified at present, demonstrating relatively uniform and continual subsidence across the margin from Santonian to Early Oligocene time. A further major bounding surface is present between the Upper Cretaceous and Paleogene, but this may become partly conformable in the Lindi area. Although the principal lithology in all formations is clay or claystone, there are more permeable intervals containing pervasive coarser siliciclastic sediments and these have yielded traces of crude oil which is likely to have migrated from lower in the succession. The Kilwa Group thus also provides important new evidence for petroleum play development in the southern coastal zone.     

Earthquake source parameters at the sumatran fault zone: Identification of the activated fault plane

Fifteen earthquakes (M_w 4.1–6.4) occurring at ten major segments of the Sumatran Fault Zone (SFZ) were analyzed to identify their respective fault planes. The events were relocated in order to assess hypocenter uncertainty. Earthquake source parameters were determined from three-component local waveforms recorded by IRIS-DMC and GEOFON broadband lA networks. Epicentral distances of all stations were less than 10°. Moment tensor solutions of the events were calculated, along with simultaneous determination of centroid position. Joint analysis of hypocenter position, centroid position, and nodal planes produced clear outlines of the Sumatran fault planes. The preferable seismotectonic interpretation is that the events activated the SFZ at a depth of approximately 14–210 km, corresponding to the interplate Sumatran fault boundary. The identification of this seismic fault zone is significant to the investigation of seismic hazards in the region.     

Optimized similarity matrices applied to the study of carbonate rocks

The primary and early diagenetic components of carbonate rocks are commonly arranged systematically in a sort of ‘relay’ along a gradient formed by one or several environmental factors. Such a relay, if present, can be revealed by the optimization of a matrix of similarity coefficients. The technique presented uses presence/absence data and is simple and rapid. An illustration is given using data from some Dinantian limestones in southwest Britain.     

Eruption dynamics of the SW crater of Stromboli volcano,Italy — An interdisciplinary approach

We report on the evaluation of in situ measurements of eruption velocities and relative mass flux, collected by Doppler radar, as well as acoustic and infrared data, that were recorded at Stromboli volcano. Doppler radar observations were made alongside thermal, acoustic and seismic measurements, to (1) further investigate the complex waveforms of the SW crater by combining infrasonic, infrared and Doppler radar measurements, (2) establish a relationship between infrared, acoustic and Doppler radar measurements and (3) verify that all instruments observe the same behavior in terms of relative mass eruption rate. We also explore the relationship between kinetic and acoustic energy released during an eruption. Comparing the different methods to each other we are able to show that the mass erupted can be estimated either from the total reflected Doppler radar energy or from infrared observations. However, neither thermal nor reflected energy can provide a value in terms of absolute mass in kg. The erupted masses of different eruptions can only be evaluated relative to each other. Using the combined three data sets we especially focus on the eruption dynamics of the SW crater of Stromboli, namely its fluctuations in eruption strength. These pulses in one eruptive event, so called ’pulsations’ dominate more than 40% of the eruptions of SW crater. Previous models that explain pulsations to be generated by multiple consecutively exploding bubbles are supported by our combined analysis of infrasound, thermal data, particle velocities, and the reflected energy.     

Distribution of orogenic gold deposits in relation to fault zones and gravity gradients: targeting tools applied to the Eastern Goldfields, Yilgarn Craton, Western Australia

A quantitative spatial analysis of mineral deposit distributions in relation to their proximity to a variety of structural elements is used to define parameters that can influence metal endowment, deposit location and the resource potential of a region. Using orogenic gold deposits as an example, geostatistical techniques are applied in a geographic-information-systems-based regional-scale analysis in the high-data-density Yilgarn Craton of Western Australia. Metal endowment (gold production and gold ‘rank’ per square kilometer) is measured in incremental buffer regions created in relation to vector lines, such as faults. The greatest metal tonnages are related to intersections of major faults with regional anticlines and to fault jogs, particularly those of dilatant geometry. Using fault length in parameter search, there is a strong association between crustal-scale shear zones/faults and deposits. Nonetheless, it is the small-scale faults that are marginal or peripheral to the larger-scale features that are more prospective. Gravity gradients (depicted as multiscale edges or gravity ‘worms’) show a clear association to faults that host gold deposits. Long wavelength/long strikelength edges, interpreted as dominantly fault-related, have greater metal endowment and provide a first-order area selection filter for exploration, particularly in areas of poor exposure. Statistical analysis of fault, fold and gravity gradient patterns mainly affirms empirical exploration criteria for orogenic gold deposits, such as associations with crustal-scale faults, anticlinal hinge zones, dilational jogs, elevated fault roughness, strong rheological contrasts and medium metamorphic grade rocks. The presence and concurrence of these parameters determine the metallogenic endowment of a given fault system and segments within the system. By quantifying such parameters, the search area for exploration can be significantly reduced by an order of magnitude, while increasing the chance of discovery.     

Theoretical studies on metal thioarsenites and thioantimonides: synergistic interactions between transition metals and heavy metalloids

Recently we established that the ternary complex, CuAsS(SH)(OH) has an unusually high stability and makes a large contribution to the total concentrations of both Cu and As in sulfidic solutions equilibrated with Cu and As sulfide minerals. This ternary complex has an unusual structure, containing a bond which is formally Cu(I)–As(III), along with a broken As–S bond. We have now found that complexes with similar structures exist for Au⁺ and Tl⁺ coordinated to AsS(SH)(OH)^-. However, such a direct metal–metalloid bond is not a requirement for stability. In fact, TlAsS(SH)(OH) is unstable while AuAsS(SH)(OH) is highly stable (compared to the aquo ion). Zn²⁺, Cd²⁺, Hg²⁺ and Pb²⁺ also form bonds to the As of AsS(SH)(OH), but without breaking any As–S bonds, and HgAsS(SH)(OH)⁺ and PbAsS(SH)(OH)⁺ are particularly stable complexes. Calculated structures are shown for these complexes, gas-phase energies are calculated, and formation constants in aqueous solution are estimated. The SbS(SH)(OH)^- ion forms analogous complexes, with similar stabilities. However, the Au⁺ complex of SbS(SH)(OH)^- is slightly less stable than the Cu⁺ complex, opposite to the order found for the AsS(SH)(OH)^- ligand. The Au⁺ and AuSH complexes of AsSSHOH^- or AsS(SH)₂ ^- may be implicated in "invisible gold" in arsenian pyrites. Vibrational frequencies are given for the AuAsS(SH)₃ ^- complex and the XANES energies of this complex and Au(SH)₂ ^- are compared. The existence of such strong complexes may explain the many correlations observed between the concentrations of coinage metals and metalloids.