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931.
This paper reports REE data on resin-asphaltene components of oil from six oil-gas-bearing provinces and on bitumoids from
inferred oil-source rocks (domanikites and bazhenites). It was shown that, regardless of geological-tectonic structure of
the regions, oil composition, depth of reservoirs, and host lithologies, oil exhibits significant REE fractionation, and,
unlike bitumoids, positive Eu anomaly. The (Eu/Sm)n ratio increases from asphaltenes to resins and further to oils. Based on REE distribution in oil, source rocks, and bitumoids,
it was concluded that deep-seated fluids were one of the possible sources that defined the trace element composition of oil. 相似文献
932.
933.
J. M. Charnock C. M. B. Henderson J. F. W. Mosselmans R. A. D. Pattrick 《Physics and Chemistry of Minerals》1996,23(7):403-408
The X-ray absorption spectra of the transition metal L3,2-edges of the dichalcogenides FeS2 (pyrite), FeSe2, FeTe2, CoS2, CoSe2, CoTe2, NiS2, NiSe2 and NiTe2 have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe. 相似文献
934.
A.?Pulido-BoschEmail author J.?M.?Calaforra P.?Pulido-Leboeuf S.?Torres-García 《Environmental Geology》2004,46(5):583-590
The Messinian gypsum of Sorbas is intensively karstified, with hundreds of dolines and numerous, highly unusual exo- and endokarstic forms. Amongst these the tumuli are especially spectacular, as are the large caverns, adorned with numerous speleothems, some of which have not been described anywhere else in the World. The extraction of the gypsum has impacted practically all the elements of the environment (landscape, water, soil, subsoil, flora, fauna, etc.) and, in particular, all of the karstic forms. In addition to endangering the caves and the natural treasures that they contain, it affects the surface waters, markedly modifying the hydrographic network. Groundwaters, which now occur in the bottom of a quarry, are also affected. 相似文献
935.
Ajith G. Nair D.S. Suresh Babu K.T. Damodaran R. Shankar C.N. Prabhu 《Journal of Asian Earth Sciences》2009,34(2):115-122
The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10?6 m3 kg?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb2O5 (0.28%), Cr2O3 (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO2 (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe3+/Fe2+ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene. 相似文献
936.
Andrew D. Czaja Anatoliy B. Kudryavtsev George D. Cody J. William Schopf 《Organic Geochemistry》2009,40(3):353-364
The processes of organic maturation that occur during the permineralization of fossils and the detailed chemistry of the resulting products are incompletely understood. Primary among such processes is the geochemical alteration of biological matter to produce kerogen, such as that which comprises the cell walls of the fossils studied here: essentially unmetamorphosed, Eocene plant axes (specimens of the fossil fern Dennstaedtiopsis aerenchymata cellularly permineralized in cherts of the Clarno Formation of Oregon and the Allenby Formation of British Columbia). The composition and molecular structure of the kerogen that comprises the cell walls of such axes were analyzed using ultraviolet Raman spectroscopy (UV–Raman), solid state 13C nuclear magnetic resonance spectroscopy (13C NMR) and pyrolysis–gas chromatography–mass spectrometry (py–GC–MS).Cellularly well-preserved fern axes from both geologic units exhibit similar overall molecular structure, being composed primarily of networks of aromatic rings and polyene chains that, unlike more mature kerogens, lack large polycyclic aromatic hydrocarbon (PAH) constituents. The cell walls of the Allenby Formation specimens are, however, less altered than those of the Clarno chert, exhibiting more prevalent oxygen-containing and alkyl functional groups and comprising a greater fraction of rock mass.The study represents the first demonstration of the effectiveness (and limitations) of the combined use of UV–Raman, 13C NMR and py–GC–MS for the analysis of the kerogenous cell walls of chert-permineralized vascular plants. 相似文献
937.
938.
R. Kariyappa 《Solar physics》1994,154(1):19-27
From a 35-min time series of photographic spectra in the Caii H-line obtained at the Vacuum Tower Telescope (VTT) of the Sacramento Peak Observatory under high spatial, spectral, and temporal resolution, we have derived a large number of H-line profiles at the sites of the bright points in the interior of the supergranulation cells, and at the network elements, on a quiet region at the centre of the solar disc. It is shown that the bright points are associated with 3-min periodicity in their intensity oscillations whereas the network elements exhibit 7-min periodicity. It is surmised that the large difference in periods of the intensity oscillations, the strength of the magnetic fields, and the intensity enhancements at the sites of the bright points and the network elements themselves may probably be taken as evidence to argue that the mechanisms of heating in the two cases are dissimilar, irrespective of the sizes of these structures. 相似文献
939.
940.
R. N. Manchester 《Journal of Astrophysics and Astronomy》1995,16(2):233-244
Recent searches for millisecond and binary pulsars are reviewed, with particular emphasis on the nearly complete Parkes southern
survey. Correlations between several of the major parameters of these systems are discussed. 相似文献