Magma sources for Mesozoic anorogenic granites of the White Mountain magma series,New England,USA

The magma sources for granitic intrusions related to the Mesozoic White Mountain magma series in northern New England, USA, are addressed relying principally upon Nd isotopes. Many of these anorogenic complexes lack significant volumes of exposed mafic lithologies and have been suspected of representing crustal melts. Sm–Nd and Rb–Sr isotope systematics are used to evaluate magma sources for 18 felsic plutons with ages ranging from about 120 to 230 Ma. The possibility of crustal sources is further examined with analyses of representative older crust including Paleozoic granitoids which serve as probes of the lower crust in the region. Multiple samples from two representative intrusions are used to address intrapluton initial isotopic heterogeneities and document significant yet restricted variations (<1 in _Nd). Overall, Mesozoic granite plutons range in _Nd [T] from +4.2 to -2.3, with most +2 to 0, and in initial ⁸⁷Sr/⁸⁶Sr from 0.7031 to 0.709. The isotopic variations are roughly inversely correlated but are not obviously related to geologic, geographic, or age differences. Older igneous and metamorphic crust of the region has much lower Nd isotope ratios with the most radiogenic Paleozoic granitoid at _Nd [180 Ma] of -2.8. These data suggest mid-Proterozoic separation of the crust in central northern New England. Moreover, the bulk of the Mesozoic granites cannot be explained as crustal melts but must have large mantle components. The ranges of Nd and Sr isotopes are attributed to incorporation of crust by magmas derived from midly depleted mantle sources. Crustal input may reflect either magma mixing of crustal and mantle melts or crustal assimilation which is the favored interpretation. The results indicate production of anorogenic granites from mantle-derived mafic magmas.     

Na-rich carbonate inclusions in perovskite and calzirtite from the Guli intrusive Ca-carbonatite,polar Siberia

Carbonate phases, some rich in Na₂O and comparatively rich in SrO and BaO, occur as inclusions in perovskite and calzirtite (Ca₂Zr₅Ti₂O₁₆) in the carbonatite of the Guli complex, Siberia. This is the first record of alkali carbonates, akin to nyerereite [Na₂Ca(CO₃)₂], in plutonic igneous rocks. The inclusion populations suggest that the parental magma of the complex was Ca-rich but developed Na-rich differentiates during the latest stages. This points to the dominant calcic carbonatites of the complex not being derivatives of alkali-rich parental carbonatites. These alkali-rich carbonate inclusions (and rare inclusions of djerfisherite) have been preserved due to the resistance of perovskite and calzirtite to processes of leaching, hydrothermal alteration and weathering.     

An Example of Island-Arc Petrogenesis: Geochemistry and Petrology of the Southern Luzon Arc, Philippines

Volcanism throughout the Luzon arc is associated with eastwardsubduction of the South China Sea floor along the Manila Trench.The southern section of the arc, the focus of this study, extendsfrom the Lingayen-Dingalan fault to the small islands just southof Luzon. Two segments appear to exist along this section ofthe arc the northern Bataan and southern Mindoro segments whichare separated by the Macolod Corridor. The volcanic rocks have typical arc phenocryst mineralogies:olivine, clinopyroxene, plagioclase, and titanomagnetite inthe most mafic rocks and clinopyroxene, plagioclase, orthopyroxene,titanomagnetite, ? amphibole in the more felsic samples. Complexzoning, sieve textures, and decoupling of incompatible traceelements suggest that processes such as assimilation have takenplace. The rocks from the study area range from basalts to rhyolitesand show typical calc-alkaline features. The rocks of the MacolodCorridor and Mindoro segment are particularly enriched in largeion lithophile elements (LILE), light rare earth elements (LREE),and radiogenic Sr compared with the Bataan segment. The datafall within the mantle array on Sr-Nd isotopic diagrams andgrade toward higher Sr and lower Nd isotopic values from northto south. A likely source for the volcanics of this study is either amid-ocean ridge basalt (MORB)-type mantle that undergoes higherdegrees of partial melting than regions involved in MORB generationor a previously depleted source. We suggest that the high fieldstrength element (HFSE) anomalies have been derived throughdifferential element partitioning during fluid transport fromthe subducted lithosphere to the mantle wedge. Continental crustal material seems to play a significant roleparticularly in the Macolod Corridor and the Mindoro segment,based on the high LILE, La/Sm ratios, radiogenic Sr isotopes,and ¹⁸O values. The Macolod Corridor and the Mindoro segmenthave undergone source contamination by crustal material fromthe North Palawan-Mindoro crustal block either during the collisionof this block with the Manila Trench or by subduction of sedimentsrich in this crustal material. A similar component has alsobeen detected in the Bataan segment but in minor amounts. Thetrace element and isotopic differences between the northernand southern sections of the arc are interpreted in terms ofvariable composition (i. e., variable amounts of a crustal componentintroduced from the Palawan-Mindoro crustal terrain) of themetasomatic fluids released into the source.     

Directions and possibilities of mathematical geology

This paper considers the present state of mathematical geology. Three directions are recognized: applied, theoretical, and mathematical. Applied mathematical geology includes formal use of mathematics to solve problems and computer processing of data. Success is achieved by a correspondence of mathematical methods used to the nature of geological data. This correspondence can be demonstrated by purely mathematical means. Theoretical mathematical geology uses mathematics as a language of geology; however, a number of methodological problems must be solved: formalization of initial geological concepts and creation of a strict conceptual basis, substantiation of initial principles of mathematical simulation, creation of theoretical geological models, problems of elementary and coincidence in geology, and methodological substantiations of possibilities of any mathematical model to approximate geological models. The essense and significance of these problems are considered. The main task of mathematical geology is to prove its correspondence to the nature of the geological objects studied, geological data obtained, and geological problems solvable. Finally, the main problems of mathematical geology are not so much mathematical as geological and methodological.     

Evolution of nappes in the eastern margin of the Bohemian Massif: a kinematic interpretation

The entire pile of nappes in the eastern margin of the Bohemian massif is characterized by two stages of Variscan nappe emplacement each exhibiting a different kinematic and metamorphic evolution.The older emplacement (D1) probably occurred around 350-340 Ma ago and was synmetamorphic. The nappes show a typical systematic superposition of higher grade metamorphic units over lower grade ones. Thus, the crystalline complexes showing a HT-MP Barrovian imprint (Svratka allochthonous unit and Moldanubicum) were thrust over an intermediate unit affected by MTMP recrystallization (Bíte orthogneiss and its country rock), and at the base of the D1 nappe pile the Inner Phyllite Nappe (Biý Potok Unit) is characterized by LT/LP metamorphism.The second stage of tectonic evolution (D2) is characterized by a thin-skinned northward-oriented nappe emplacement that occurred under LT-LP conditions dated at 320-310 Ma. The whole nappe sequence formed during the first tectonometamorphic period (D1) was transported northward over the autochthonous »Deblín polymetamorphic and granitic complex« of Upper Proterozoic age and its Devonian sedimentary cover with very low metamorphism. During this second tectonic event the Brno granite massif (580 Ma) was only marginally incorporated in the Variscan nappe tectonics which resulted in kilometer-scale cover and basement duplexes. The tectonic evolution of the nappe pile ended with stage D3, represented by large- to medium-scale east-vergent folds with limited displacement.

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Zusammenfassung Der Deckenbau am Ostrand der Böhmischen Masse erfolgte in zwei aufeinanderfolgenden Stadien, die sich sowohl in ihrer Kinematik als auch in ihrer Metamorphoseentwicklung deutlich voneinander unterschieden.Die ältere Phase (D1 ca. 350-340 Ma) ist durch synmetamorphe Überschiebungen charakterisiert. Sie führt zu einer metamorphen Inversion der überschobenen Deckeneinheiten, so daß generell hohe metamorphe Einheiten schwach metamorphe tektonisch überlagern. Der Svratka Komplex und das Moldanubikum als hangendste Decken sind durch MP/HT Paragenesen vom Barrow-Typ gekennzeichnet. Beide Einheiten sind auf den MP/MT-metamorphen Bite-Gneis und seine Rahmengesteine überschoben. Die Bílý potok Einheit als liegende Decke zeigt nur noch eine LP/ LT Regionalmetamorphose.Das jüngere Stadium (D2 ca. 320-310 Ma) ist durch eine Thin-skinned Tektonik mit nordvergentem Deckentransport unter LP/LT Bedingungen charakterisiert. Der gesamte, invers metamorphe D1-Deckenstapel wird dabei nach N über den autochtonen Deblín Komplex bzw. seine devonische Sedimenthülle überschoben.Das Brno Granit Massiv (580 Ma) wird nur randlich in diesen variszischen Deckenbau einbezogen. Die tektonische Entwicklung endet mit einem mittel bis großräumigen E-vergenten Faltenbau (D3 phase).

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Résumé L'empilement des nappes a la bordure orientale du Massif de Bohème est caractérisé par deux stades de mise en place présentant différentes évolutions cinématiques et métamorphiques.La tectonique majeure de mise en place des nappes crustales intervient lors d'un métamorphisme de type barrowien, calé autour de 350-340 Ma. L'empilement qui en résulte montre une superposition systématique d'unités à fort degré de métamorphisme sur des unités moins métamorphiques. Ainsi les complexes cristallins, montrant des reliques de métamorphisme de haute à moyenne pression-haute température (unités cristallines de Svratka et du Moldanubien), chevauchent une unité intermédiaire affectée par un métamorphisme de moyenne à basse pression-moyenne température (l'orthogneiss de Bíte et son encaissant). A la base de cette pile édifiée durant la tectonique D1, l'unité des phyllites internes (unité de Bílý potok) est caractérisée par un métamorphisme de basse témperature-basse pression.Le second stade D2 de l'évolution tectonique est caractérisé par une tectonique pelliculaire à vergence nord datée à 320-310 Ma. L'empilement résultant de D1 est ainsi transporté vers le nord, au dessus du complexe autochtone d'âge protérozoïque supérieur (groupe de Deblín) et sa couverture sédimentaire dévonienne très faiblement métamorphisée.Le massif granitique de Brno (580 Ma) n'est que marginalement incorporé à cette tectonique de nappe varisque. Ceci se traduit par des duplex socle-couverture d'échelle plurikilométrique. L'évolution tectonique s'achève lors d'une troisième phase, marquée par de grands plis à vergence est. Le déplacement associé est alors d'amplitude limitée.

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, . , 350-340 . . , , - ( ), , - ( ). , D 1, (- ) - . D 2 , 320-310 ., D 1, , , ( ) . (580 . ) , »« -, . , .

     

New compositional and optical data for antimonian and bismuthian varieties of hemusite from Japan

Summary New compositional and optical data are reported for antimonian and antimonianbismuthian varieties of hemusite from epithermal Au-Ag-Cu deposits in Japan. The empirical formula for the antimonian variety, from the Iriki mine is: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00(S_7.85Se_0.15)_8.00, and that of the Sb-Bi variety from the Kawazu mine is: (Cu_5.84Fe_0.14Ag_0.01)_5.99Mo_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07(S_7.80Se_0.12)_7.92. The theoretical formula of hemusite is Cu⁺ ₄Cu²⁺ ₂MO⁴⁺Sn⁴⁺S₈, whilst the most probable formula of the Iriki hemusite is Cu⁺ _4.5CU²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, with Sb⁵⁺ substituting for Sn⁴⁺ and forming (SbS₄)^3– tetrahedra as might be expected, given that the metal to sulphur ratio is 1, and given the sphalerite-like structure of the mineral. However Bi³⁺ cannot be so accommodated, resulting in a deficiency in (S + Se) for Kawazu hemusite. Reflectance spectra for both are compared with those of the tungsten analogue (compositional) of hemusite, kiddcreekite. The relationship between hemusitesensu stricto and these newly reported varieties is discussed in terms of simple and coupled chemical substitutions, and inferences are drawn on the valency of Sb, Bi, Mo and Cu in the hemusite structure.

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Neue chemische und optische Daten für antimon- und bismuthführende Varietäten von Hemusit aus Japan

Zusammenfassung Neue chemische und optische Daten für antimon- und bismuthführende Hemusite auf epithermalen Au-Ag-Cu Lagerstätten in Japan werden vorgelegt. Die empirische Formel für die antimon-führende Varietät aus der Iriki-Mine ist: (Cu_5.83Fe_0.14Ag_0.01)_5.98Mo_1.03(Sn_0.54Sb_0.41Te_0.03Bi_0.02)_1.00 (S_7.85Se_0.15)_8.00, und die der Sb-Bi Varietät aus der Kawazu Mine ist: (Cu_5.84Fe_0.14Ag_0.01)_5.99M0_1.03(Sn_0.82Sb_0.11Bi_0.l0Te_0.04)_1.07 (S_7.80Se_0.12)_7.92. Die theoretische Formel von Hemusit ist Cu⁺ ₄Cu²⁺ ₂Mo⁴⁺Sn⁴⁺S₈, während die wahrscheinlichere Formel für den Hemusit von Iriki Cu⁺ ₄Cu²⁺ _1.5Mo⁴⁺Sn⁴⁺ _0.5Sb⁵⁺ _0.5S₈, mit Sb⁵⁺ an der Stelle von Sn⁴⁺, das(SbS₄)^3– Tetraeder bildet, wie zu erwarten ist, unter der Voraussetzung, da das Metall zu Schwefelverhältnis 1 und die Struktur sphaleritähnlich ist. Bi³⁺ kann jedoch nicht in dieser Weise untergebracht werden, und das führt zu einem Mangel an (S + Se) für den Hemusit von Kawazu. Die Reflektions-Spektren beider Minerale werden mit denen des Wolfram-Equivalents von Hemusit (Kiddcreekit) verglichen. Die Beziehung zwischen Hemusitsensu stricto und diesen jetzt beschriebenen Varietäten wird auf der Basis einfacher und gekoppelter chemischer Substitution diskutiert. Auf dieser Basis werden Schlüsse auf die Valenz von Sb, Bi Mo und Cu in der Hemusit-Struktur gezogen.

     

The structural state of the former lower continental crust in Calabria (S. Italy)

In the Northern Serre (S. Italy), a continuous section through a former lower continental crust is exposed (Schenk 1984, 1985). These granulite facies rocks have not been penetratively deformed during their uplift to higher crustal levels. Therefore, they allow to study the structural state of the lower continental crust. Most rockforming minerals, among them ortho- and clinopyroxene and cordierite, show recrystallization structures. Quarz basal subgrain boundaries are developed in lower levels of the lower crust and disappear toward higher levels. In addition to dimensional orientations of the rockforming minerals, the preferred crystallographic orientations of plagioclases, cordierite, amphibole, pyroxenes and, rarely, quartz reflect the strain orientation of the prograde high-T deformation. During this deformation, the stretching direction was constant NNE-SSW throughout the exposed lower crustal section. Shear indicators are rare. This points to the fact that deformation has been homogeneous and coaxial flattening. There is only a small variation in orientation and strength of textures throughout the exposed lower crust. Therefore, neighbouring layers of different composition rather than different deformation might serve as seismic reflectors in the former lower crust.

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Zusammenfassung In der nördlichen Serre (Süditalien) ist ein zusammenhängender Bereich einer ehemaligen kontinentalen Unterkruste aufgeschlossen (Schenk 1984, 1985). Diese granulitfaziellen Gesteine sind bei ihrem Aufstieg in höhere Krustenbereiche nicht durchgreifend überprägt worden. Deshalb läßt sich an ihnen noch der strukturelle Zustand der ehemaligen Unterkruste studieren. Außer in Feldspäten, Quarz und Amphibol tritt auch in Ortho- und Klinopyroxen und in Cordierit Rekristallisation auf. In tieferen Krustenniveaus sind im Quarz basisparallele Subkorngrenzen entwickelt, die in höheren Krustenbereichen nicht auftreten. Sowohl die Gestaltregelungen der gesteinsbildenden Minerale als auch die kristallographischen Plagioklas-, Cordierit-, Amphibol-, Pyroxen- und (seltener) Quarzregelungen spiegeln die Strain-orientierung der prograden hochtemperierten Deformation wider. Während dieser Deformation blieb die Streckung im gesamten Unterkrustenbereich konstant NNE-SSW orientiert. Scherindikatoren sind selten. Beides deutet darauf hin, daß die Deformation homogen und als koachsiale Plättung abgelaufen ist. Im gesamten aufgeschlossenen Unterkrustenbereich variieren weder Intensität noch Orientierung der kristallographischen und gestaltlichen Regelungen der gesteinsbildenden Minerale wesentlich. Deshalb sollten in der ehemaligen Unterkruste Lagen unterschiedlicher Deformation weniger als seismische Reflektoren in Frage kommen als Lagen unterschiedlicher Zusammensetzung.

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Résumé Le Massif de la Serre Septentrionale en Calabre (Sud de l'Italie) représente un tronçon d'une ancienne croûte continentale profonde (Schenk 1984, 1985). Les roches du faciès granulite qui le constituent n'ont pas subi de déformation penetrative lors de leur ascension dans les niveaux plus superficiels de la croûte. Leur étude permet donc de reconstruire les caractéristiques structurales de l'ancienne croûte profonde. Non seulement les feldspaths, le quartz et l'amphibole, mais encore l'orthopyroxène, le clinopyroxène et la cordiérite ont recristallisé. Dans les niveaux les plus profonds de la croûte on observe dans les cristaux de quartz des bordures de sous-grains parallèles à la base. Celles-ci n'apparaissent plus dans les niveaux plus superficiels. L'orientation des cristaux des minéraux constitutifs des roches, de même que l'orientation des réseaux cristallins du plagioclase, de la cordiérite, de l'amphibole, du pyroxène et (mais plus rarement) du quartz réflètent la direction de contrainte de la phase de déformation prograde de haute température. Pendant cette phase de déformation, la direction d'extension est demeurée NNE-SSW. Les témoins de cisaillement sont rares, ce qui montre que la déformation s'est effectuée de façon homogène, en relation avec un aplatissement coaxial. Les textures varient très peu en orientation comme en intensité dans toute la coupe de croûte profonde exposée. En conséquence, l'existence de réflecteurs sismiques devrait refléter des différences dans les compositions minéralogiques des roches plutôt que dans leurs caractéristiques structurales.

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Sublethal abnormalities in embryos of winter flounder,Pseudopleuronectes americanus,from Long Island Sound

Sublethal abnormalities were examined in developing embryos of the winter flounder,Pseudopleuronectes americanus, as part of a study of its early reproductive success in Long Island Sound and two sites in Boston Harbor. These sites represented varying levels of anthropogenic contamination that were possibly affecting reproduction, as ascertained by chromosomal abnormalities and lowered developmental rates in the embryos. Effort was focused on examination of blastula and tail-bund embryos from field-captured females spawned at the laboratory. Abnormalities observed included evidence of cytotoxicity and chromosome damage. Embryos of fish from New Haven were usually the most aberrant, while embryos from other sites, notably Hempstead, Shoreham, and both Boston Harbor stations, showed subtle indications of abnormality.     

Can Brans-Dicke universes in five dimensions be interpreted as 4-dimensional general relativity cosmologies?

The 5-dimensional Jordan-Brans-Dicke cosmologies in vacuum are found for the Bianchi type I metric, their relation with general relativity cosmologies is studied. Two solutions are possible, both produce effective pressure and energy density in the 4-dimensional G.R.-universes. One is a power-law relation, with two cases, the first one is forp _eff=_eff and the other forp _eff=_eff(– 1 < < 1) has a behaviour as the open flat universe. The second solution is an exponential only valid forp _eff=–_eff. In all cases the three-space expansion reaches infinity ast and the fifth dimension can be made to decrease approaching zero. The scalar field can increase or decrease with time.     

Cosmological implications of BL Lac objects

It has become clear in recent years that relativistic beaming is a good explanation for the BL Lac phenomenon. Of studies based on the relativistic beaming model of BL Lac objects, we note that the orientation of jet's axis to the line-of-sight is very small and, therefore, the observed flux emitted from a rapidly moving source is orders of magnitude higher than the flux in its rest-frame:F _obs = ^{3 +} F _intr, where is the bulk relativistic Doppler factor. Then the observed apparent magnitudem _v must be corrected for this effect. For our 39 samples, the corrected apparent magnitudem _v ^corr and logZ have a good correlation.