Present day serpentinization in New Caledonia,Oman and Yugoslavia

Geochemical evidence for modern low-temperature serpentinization has been found in three new localities. Apparently the low-temperature reactions are a common mode of formation of the lizardite-chrysotile and brucite assemblage. Possibly the ¹⁸O content of serpentine formed at low temperatures is in part inherited from the pyroxene and olivine.     

Contrasting soils and landscapes of the Piedmont and Coastal Plain, eastern United States

The Piedmont and Coastal Plain physiographic provinces comprise 80 percent of the Atlantic Coastal states from New Jersey to Georgia. The provinces are climatically similar. The soil moisture regime is udic. The soil temperature regime is typically thermic from Virginia through Georgia, although it is mesic at altitudes above 400 m in Georgia and above 320 m in Virginia. The soil temperature regime is mesic for the Piedmont and Coastal Plain from Maryland through New Jersey. The tightly folded, structurally complex crystalline rocks of the Piedmont and the gently dipping “layer-cake” clastic sedimentary rocks and sediments of the Coastal Plain respond differently to weathering, pedogenesis, and erosion. The different responses result in two physiographically contrasting terrains; each has distinctive near-surface hydrology, regolith, drainage morphology, and morphometry.The Piedmont is predominantly an erosional terrain. Interfluves are as narrow as 0.5 to 2 km, and are convex upward. Valleys are as narrow as 0.1 to 0.5 km and generally V-shaped in cross section. Alluvial terraces are rare and discontinuous. Soils in the Piedmont are typically less than 1 m thick, have less sand and more clay than Coastal Plain soils, and generally have not developed sandy epipedons. Infiltration rates for Piedmont soils are low at 6–15 cm/h. The soil/saprolite, soil/rock, and saprolite/rock boundaries are distinct (can be placed within 10 cm) and are characterized by ponding and/or lateral movement of water. Water movement through soil into saprolite, and from saprolite into rock, is along joints, foliation, bedding planes and faults. Soils and isotopic data indicate residence times consistent with a Pleistocene age for most Piedmont soils.The Coastal Plain is both an erosional and a constructional terrain. Interfluves commonly are broader than 2 km and are flat. Valleys are commonly as wide as 1 km to greater than 10 km, and contain numerous alluvial and estuarine terrace sequences that can be correlated along valleys for tens of kilometers. Coastal Plain soils are typically as thick as 2 to 8 m, have high sand content throughout, and have sandy epipedons. These epipedons consist of both A and E horizons and are 1 to 4 m thick. In Coastal Plain soils, the boundaries are transitional between the solum and the underlying parent material and between weathered and unweathered parent material. Infiltration rates for Coastal Plain soils are typically higher at 13–28 cm/h, than are those for Piedmont soils. Indeed, for unconsolidated quartz sand, rates may exceed 50 cm/h. Water moves directly from the soil into the parent material through intergranularpores with only minor channelization along macropores, joints, and fractures. The comparatively high infiltration capacity results in relatively low surface runoff, and correspondingly less erosion than on the Piedmont uplands.Due to differences in Piedmont and Coastal Plain erosion rates, topographic inversion is common along the Fall Zone; surfaces on Cenozoic sedimentary deposits of the Coastal Plain are higher than erosional surfaces on regolith weathered from late Precambrian to early Paleozoic crystalline rocks of the Piedmont. Isotopic, paleontologic, and soil data indicate that Coastal Plain surficial deposits are post-middle Miocene to Holocene in age, but most are from 5 to 2 Ma. Thus, the relatively uneroded surfaces comprise a Pliocene landscape. In the eastern third of the Coastal Plain, deposits that are less than 3.5 Ma include alluvial terraces, marine terraces and barrier/back-barrier complexes as morphostratigraphic units that cover thousands of square kilometers. Isotopic and soil data indicate that eastern Piedmont soils range from late Pliocene to Pleistocene in age, but are predominantly less than 2 Ma old. Thus, the eroded uplands of the Piedmont “peneplain” comprise a Pleistocene landscape.     

Molecular simulations of metal adsorption to bacterial surfaces

The atomic-scale interactions that occur between cations and the metal-binding cell wall components common to many gram-positive bacteria were investigated using molecular simulations techniques. We examined the adsorption of Cd and Pb onto peptidoglycan and teichoic acid components of the bacterial cell wall using classical energy force field methods. Within the framework of molecular mechanics and the Cerius² modeling software, we used energy minimization, conformational analysis, and molecular dynamics to examine the different components of the cell wall and to determine relative binding energies and structural configurations of the cell wall components, both with and without the metals present. Electronic structure calculations of representative metal-organic complexes validate the more practical classical methods required in simulating the large number of atoms associated with the cell wall components. The classical force field simulations were conducted in both gas phase and solvated periodic cells. Force field-based simulation techniques can adequately describe the interactions of Cd with the cell wall, defining both metal ion coordinations and binding distances. However, the classical force field approach is inconsistent in describing the observed Pb-cell wall interactions due to possible limitations in the force field parameters, the propensity for Pb to form hydroxides at circumneutral pH, or the dominance of other adsorption mechanisms.     

Neodymium isotopic evidence for the tectonic assembly of Late Archean crust in the Slave Province,northwest Canada

The ca. 2.7–2.5 Ga Slave Province is a granitegreenstone terrane comprising deformed sedimentary and subordinate volcanic belts extensively intruded by granitoid rocks. The Nd isotopic data are reported for 58 samples of supracrustal and granitoid rocks exposed along a 400 km, east-west, transect at 65°N across the structural grain of the province. Initial _Nd values reveal distinctly different crustal sources in the eastern compared to the western parts of the province, as expected from tectonic assembly of the province through accretion of juvenile crust to older continental crust. Supracrustal sequences (ca. 2.71–2.65 Ga) from the central and eastern parts of the province have positive _Nd(1) values (+0.3 to +3.6), consistent with juvenile sources and formation remote from significantly older crust. Syn to late-deformation (ca. 2.63–2.60 Ga), mantle-derived diorites and related tonalites (type I) from the central and eastern parts of the province have similar initial _Nd values (-0.1 to +2.7). In contrast, samples from the westernmost plutons, which intrude exposed pre-3.1 Ga crust, have much lower _Nd(1) values (-1.0 to4.6) suggesting contamination of these magmas by older crust. The _Nd(1) values of post-deformation granites (s.s.) (type II) also vary systematically across the province: values for granites west of longitude 110°30W range from-0.2 to -5.3; those to the east range from +0.6 to +3.7. These data suggest mixed crustal sources dominated by Mid to Early Archean material ( _Nd-2.6 to- 17 at 2.6 Ga) for the western granitoid rocks and juvenile sources for the eastern granites. The Nd isotopic data are consistent with the geology of the province in that exposures of Mid to Early Archean crustal rocks, predating the principal 2.7–2.5 Ga orogenic event are restricted to the western part of the province. The asymmetric pattern defined by the Nd isotopic data indicates the presence of distinct crustal rocks beneath the Slave Province. Similar isotopic variations observed across Phanerozoic collisional orogens have been interpreted to reflect tectonic assembly of crust by accretion of juvenile crustal terranes to an older continental margin. This process may also have been an important mechanism in the cratonization of the Slave Province.     

Sugarloaf Mountain,central Arizona,USA: A small-scale example of Miocene basalt-rhyolite magma mixing to yield andesitic magmas

Sugarloaf Mountain is a 200-m high volcanic landform in central Arizona, USA, within the transition from the southern Basin and Range to the Colorado Plateau. It is composed of Miocene alkalic basalt (47.2–49.1?wt.% SiO₂; 6.7–7.7?wt.% MgO) and overlying andesite and dacite lavas (61.4–63.9?wt.% SiO₂; 3.5–4.7?wt.% MgO). Sugarloaf Mountain therefore offers an opportunity to evaluate the origin of andesite magmas with respect to coexisting basalt. Important for evaluating Sugarloaf basalt and andesite (plus dacite) is that the andesites contain basaltic minerals olivine (cores Fo_76-86) and clinopyroxene (～Fs_9-18Wo_35-44) coexisting with Na-plagioclase (An_48-28Or_1.4–7), quartz, amphibole, and minor orthopyroxene, biotite, and sanidine. Noteworthy is that andesite mineral textures include reaction and spongy zones and embayments in and on Na-plagioclase and quartz phenocrysts, where some reacted Na-plagioclases have higher-An mantles, plus some similarly reacted and embayed olivine, clinopyroxene, and amphibole phenocrysts.Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ～61 to 64?wt.% SiO₂ is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77–105 in andesites vs 114–166?ppm in basalts; Zr 149–173 vs 183–237; Nb 21–25 vs 34–42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well ? although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8–16?km and 850° to 980?°C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing ‘collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (～20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.     

A method of alternating characteristics with application to advection-dominated environmental systems

We present a numerical method for solving a class of systems of partial differential equations (PDEs) that arises in modeling environmental processes undergoing advection and biogeochemical reactions. The salient feature of these PDEs is that all partial derivatives appear in linear expressions. As a result, the system can be viewed as a set of ordinary differential equations (ODEs), albeit each one along a different characteristic. The method then consists of alternating between equations and integrating each one step-wise along its own characteristic, thus creating a customized grid on which solutions are computed. Since the solutions of such PDEs are generally smoother along their characteristics, the method offers the potential of using larger time steps while maintaining accuracy and reducing numerical dispersion. The advantages in efficiency and accuracy of the proposed method are demonstrated in two illustrative examples that simulate depth-resolved reactive transport and soil carbon cycling.     

Remote measurement of river morphology via fusion of LiDAR topography and spectrally based bathymetry

This study developed and evaluated a hybrid approach to remote measurement of river morphology that combines LiDAR topography with spectrally based bathymetry. Comparison of filtered LiDAR point clouds with surveyed cross‐sections indicated that subtle features on low‐relief floodplains were accurately resolved by LiDAR but that submerged areas could not be detected due to strong absorption of near‐infrared laser pulses by water. The reduced number of returns made the active channel evident in a LiDAR point density map. A second dataset suggested that pulse intensity also could be used to discriminate land from water via a threshold‐based masking procedure. Fusion of LiDAR and optical data required accurate co‐registration of images to the LiDAR, and we developed an object‐oriented procedure for achieving this alignment. Information on flow depths was derived by correlating pixel values with field measurements of depth. Highly turbid conditions dictated a positive relation between green band radiance and flow depth and contributed to under‐prediction of pool depths. Water surface elevations extracted from the LiDAR along the water's edge were used to produce a continuous water surface that preserved along‐channel variations in slope. Subtracting local flow depths from this surface yielded estimates of the bed elevation that were then combined with LiDAR topography for exposed areas to create a composite representation of the riverine terrain. The accuracy of this terrain model was assessed via comparison with detailed field surveys. A map of elevation residuals showed that the greatest errors were associated with underestimation of pool depths and failure to capture cross‐stream differences in water surface elevation. Nevertheless, fusion of LiDAR and passive optical image data provided an efficient means of characterizing river morphology that would not have been possible if either dataset had been used in isolation. Copyright © 2011 John Wiley & Sons, Ltd.     

Ionospheric measurements of relative coronal brightness during the total solar eclipses of 11 August, 1999 and 9 July, 1945

Swept-frequency (1/10 MHz) ionosonde measurements were made at Helston, Cornwall (50°06N, 5°18W) during the total solar eclipse on August 11, 1999. Soundings were made every three minutes. We present a method for estimating the percentage of the ionising solar radiation which remains unobscured at any time during the eclipse by comparing the variation of the ionospheric E-layer with the behaviour of the layer during a control day. Application to the ionosonde date for 11 August, 1999, shows that the flux of solar ionising radiation fell to a minimum of 25±2% of the value before and after the eclipse. For comparison, the same technique was also applied to measurements made during the total solar eclipse of 9 July, 1945, at Sörmjöle (63°68N, 20°20E) and yielded a corresponding minimum of 16 ± 2%. Therefore the method can detect variations in the fraction of solar emissions that originate from the unobscured corona and chromosphere. We discuss the differences between these two eclipses in terms of the nature of the eclipse, short-term fluctuations, the sunspot cycle and the recently-discovered long-term change in the coronal magnetic field.