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991.
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994.
碱性体系在线氢化物发生原子荧光光谱法测定铜矿石中痕量砷锑铋 总被引:10,自引:4,他引:6
建立了一个碱性体系在线氢化物发生原子荧光光谱法测定铜矿石中痕量砷、锑、铋的分析方法。设计了在线氢化物发生流路及操作程序。选择了碱性体系氢化物发生的各项最佳条件,避免了Cu、Fe等大量基体元素的干扰。方法检出限为As0.6μg/L,Sb0.4μg/L,Bi0.9μg/L,As、Sb、Bi的工作曲线均在0~400μg/L内呈良好的线性,经铜矿石国家一级标准物质分析验证,砷锑铋的测定结果与标准值吻合,相对标准偏差(RSD,n=5)在4.2%~8.8%。 相似文献
995.
M. Hoyos V. Soler J. C. Cañaveras S. Sánchez-Moral E. Sanz-Rubio 《Environmental Geology》1998,33(4):231-242
The Candamo Cave contains an important group of paleolithic paintings which have been seriously deteriorated due to mass tourism.
In this work, an analysis was carried out of different climatic parameters (CO2, temperature, humidity, 222Rn) during annual cycles with the cave closed to the public and during an experimental period of controlled visits. The effect
of visits on the geochemical characteristics of karstic water was also analyzed together with the cave ventilation.
The natural variations in the cave air CO2 were above 3000 ppm, the increase produced through visits was only 100–110 ppm and since the humidity is almost permanently
at saturation point, the critical parameter which limits the visitor capacity becomes air temperature. The temperature changes
during the annual cycle are of the order of 1 °C in the external part and less than 0.5 °C in the internal part of the cave
and a maximum increase of 0.13 °C was observed during the period of the visits. The 222Rn and CO2 concentration minimums in the summer period (July–October) show that this is the most propitious time for visits, since the
greatest ventilation is produced in the cave at this time and, therefore, the greatest capacity for recovery. The geochemistry
of the water, on the other hand, indicated that this is the period of the year in which processes of wall corrosion can be
most easily introduced, although this would be of limited magnitude. The visitor capacity calculated was 29 visitors/day.
Received: 29 August 1996 · Accepted: 23 June 1997 相似文献
996.
The coupled rotation of the inner core 总被引:1,自引:0,他引:1
The rotation of the inner core (IC) is influenced by the rest of the Earth through a number of coupling mechanisms. Among four possible coupling mechanisms, gravitational, pressure, viscous and electromagnetic, the first two torques are dominant. Numerous existing IC gravitational torque estimates have been shown to agree very well with one another Xu & Szeto 1996 ). It is shown in this paper that different estimates of the IC pressure torque are also in good agreement.
The coupled rotation of the IC has been investigated in the frequency domain by several research groups (Mathews et al. 1991a,b; De Vries & Wahr 1991 ; Dehant et al. 1993; Jiang 1993 ). Not all of these efforts obtained two IC-related rotational modes, the inner-core wobble (ICW) and the free-inner-core nutation (FICN). We investigate this problem in the time domain and confirm the existence of the two modes. The periods of ICW and FICN are in good agreement with those obtained by other researchers. In studying the effects of coupling torques on the IC rotational modes we have found that depending on whether the IC net torque is 'restoring' or otherwise, an increased torque magnitude will respectively shorten or lengthen the ICW period. We have also found that the sense of FICN is determined by the orientation of the net coupling torque on the IC. 相似文献
The coupled rotation of the IC has been investigated in the frequency domain by several research groups (Mathews et al. 1991a,b; De Vries & Wahr 1991 ; Dehant et al. 1993; Jiang 1993 ). Not all of these efforts obtained two IC-related rotational modes, the inner-core wobble (ICW) and the free-inner-core nutation (FICN). We investigate this problem in the time domain and confirm the existence of the two modes. The periods of ICW and FICN are in good agreement with those obtained by other researchers. In studying the effects of coupling torques on the IC rotational modes we have found that depending on whether the IC net torque is 'restoring' or otherwise, an increased torque magnitude will respectively shorten or lengthen the ICW period. We have also found that the sense of FICN is determined by the orientation of the net coupling torque on the IC. 相似文献
997.
Li Zhonghua Su Youjing and Liu ZhuyinSeismological Bureau of Yunnan Province Kunming China 《中国地震研究》1998,(4)
Results of analysis of variation of cross fault short-baseline and short-range leveling in Western Yunnan Earthquake Test Site (WYETS), results show that among five observation stations of cross fault short-baseline and short-range leveling in WYETS before the Lijiang MS7.0 Earthquake occurred in February 1996 only Yongsheng observation station (epicentral distance 82 km) located at Chenghai fault shows great variation about one year before the earthquake. And the nearest observation station, Lijiang (epicentral distance 42 km); presents great coseismic variation, but does not show obvious anomalous variation before the earthquake. There are no significant variations related to the earthquake at the other three observation stations. Two methods are used in analysis of the observed data and some valuable results have been obtained. 相似文献
998.
Su Chin CHEN 《国际泥沙研究》1998,(3)
RESERVOIRSEDIMENTATIONANDLANDUSEINTAIWANWUSHEHWATERSHEDSuChinCHEN1ABSTRACTWushehReservoirisagorgetypehydropowerReservoironW... 相似文献
999.
Annual and seasonal variations in the low-latitude topside ionosphere are investigated using observations made by the Hinotori satellite and the Sheffield University Plasmasphere Ionosphere Model (SUPIM). The observed electron densities at 600 km altitude show a strong annual anomaly at all longitudes. The average electron densities of conjugate latitudes within the latitude range ±25° are higher at the December solstice than at the June solstice by about 100% during daytime and 30% during night-time. Model calculations show that the annual variations in the neutral gas densities play important roles. The model values obtained from calculations with inputs for the neutral densities obtained from MSIS86 reproduce the general behaviour of the observed annual anomaly. However, the differences in the modelled electron densities at the two solstices are only about 30% of that seen in the observed values. The model calculations suggest that while the differences between the solstice values of neutral wind, resulting from the coupling of the neutral gas and plasma, may also make a significant contribution to the daytime annual anomaly, the E × B drift velocity may slightly weaken the annual anomaly during daytime and strengthen the anomaly during the post-sunset period. It is suggested that energy sources, other than those arising from the 6% difference in the solar EUV fluxes at the two solstices due to the change in the Sun-Earth distance, may contribute to the annual anomaly. Observations show strong seasonal variations at the solstices, with the electron density at 600 km altitude being higher in the summer hemisphere than in the winter hemisphere, contrary to the behaviour in NmF2. Model calculations confirm that the seasonal behaviour results from effects caused by transequatorial component of the neutral wind in the direction summer hemisphere to winter hemisphere. 相似文献
1000.
E. Reyes L. Prez del Villar A. Delgado G. Cortecci R. Núez M. Pelayo J. S. Czar 《Chemical Geology》1998,150(3-4):293-315
The El Berrocal granite/U-bearing quartz vein system has been studied as a natural analogue of a high-level radioactive waste repository. The main objective is to understand the geochemical behaviour of natural radionuclides occurring under natural conditions. In this framework, the carbonatation processes have been studied from a mineralogical and isotopic (
and
) point of view, since carbonate anions are powerful complexing agents for U(VI) under both low-temperature hydrothermal and environmental conditions. The carbonatation processes in the system are identified by the presence of secondary ankerite, with minor calcite, scattered in the hydrothermally altered granite, and Mn calcite in fracture filling materials. The isotopic signatures of these carbonates lead us to conclude that ankerite and calcite from the former were formed at the end of the same hydrothermal process that altered the granite, at a temperature range of between 72° and 61°C for ankerite, and between 52° and 35°C for calcite. The effect of edaphic CO2 on both carbonates, greater on calcite than on ankerite, is demonstrated. Calcites from fracture fillings are, at least, binary mixtures, in different proportions, of hydrothermal calcite, formed between 25° and <100°C, and supergenic calcite, formed at ≤25°C. According to their
signatures, the effect of edaphic CO2 in both calcites is also evident. It is assumed that: (i) hydrothermal calcite from fracture fillings and ankerite from the hydrothermally altered granite are the result of the same hydrothermal process, their chemical differences being due to the intensity of the water/rock interaction which was stronger in the altered granite than in the fractures; and (ii) all of these carbonatation processes are responsible for ancient and recent migration/retention of uranium observed in the hydrothermally altered granite and fracture fillings. 相似文献