Pollen‐ and diatom based environmental history since the Last Glacial Maximum from the Andean core Fúquene‐7, Colombia

The late Pleistocene–Holocene ecological and limnological history of Lake Fúquene (2580 m a.s.l.), in the Colombian Andes, is reconstructed on the basis of diatom, pollen and sediment analyses of the upper 7 m of the core Fúquene‐7. Time control is provided by 11 accelerator mass spectrometry (AMS) ¹⁴C dates ranging from 19 670 ± 240 to 6040 ± 60 yr BP. In this paper we present the evolution of the lake and its surroundings. Glacial times were cold and dry, lake‐levels were low and the area was surrounded by paramo and subparamo vegetation. Late‐glacial conditions were warm and humid. The El Abra Stadial, a Younger Dryas equivalent, is reflected by a gap in the sedimentary record, a consequence of the cessation of deposition owing to a drop in lake‐level. The early Holocene was warm and humid; at this time the lake reached its maximum extension and was surrounded by Andean forest. The onset of the drier climate prevailing today took place in the middle Holocene, a process that is reflected earlier in the diatom and sediment records than in the pollen records. In the late Holocene human activity reduced the forest and transformed the landscape. Climate patterns from the Late‐glacial and throughout the Holocene, as represented in our record, are similar to other records from Colombia and northern South America (the Caribbean, Venezuela and Panama) and suggest that the changes in lake‐level were the result of precipitation variations driven by latitudinal shifts of the Intertropical Convergence Zone. Copyright © 2003 John Wiley & Sons, Ltd.     

The influence of various seawater components on the buffer capacity for CO2

A series of experiments was performed using artificial seawater samples of increasing complexity, in order to identify, qualitatively and quantitatively, the contribution of main seawater components on the buffer capacity for CO₂.The results show that magnesium plays the most important role in the uptake, enhancing the capacity of the carbonate system alone by more than 100%.     

Radiological and geochemical characteristics of an ultramafic massif (NE Portugal) regarding the site aptness to host a near surface repository for low and intermediate level radwaste

The search for suitable sites to install near-surface repositories for low to intermediate level radioactive wastes has increased in the recent years, reflecting both the continuous rise in radioactive materials applications by the society and the increasing awareness of public perception regarding radwaste management. International recommendations towards the application of higher safety standards to low and intermediate level waste disposal sites being developed by the International Atomic Energy Agency (IAEA), and the European Commission decision that each Member State must safely dispose its own radwaste in its territory, according to national radwaste management plans, has leading to new soundly scientific studies. In Portugal, possible locations for that purpose are under study since 2006, following the pre-requisites indicated by IAEA. One of these sites overlaps a significant portion of an ultramafic massif, corresponding to an allochthonous and metamorphosed ophiolite complex. In the surveyed area of this massif, the prevailing rock type consists of (serpentinised) peridotites, occasionally containing irregular bodies of (amphibolitised) gabbros, over which an irregular/ill-developed regolith exists. The activities of ⁴⁰K, ¹³⁷Cs, ²¹⁰Pb, ²²⁶Ra and ²³²Th measured in samples representing three consecutive levels of the regolith upper portion in 13 stations confirm the heterogeneity put in evidence through in situ γ-ray surveys previously performed. The available dataset also demonstrates that radionuclide contents decrease prominently with depth, becoming closer to the bedrock values (up to ca. 41 Bq kg^?1 for ⁴⁰K in flaser-gabbros and near zero for all the remaining cases) but never reaching them. Therefore, the low/moderate radionuclide activity in the regolith upper portion reflect the contribution of sources that are independent of the lithological background; i.e. they indicate external and miscellaneous contributions to the “soil”-forming components, most of them coming from (dry or wet) atmospheric deposition. The chemical composition of the (serpentinised) peridotites and (amphibolitised) gabbros in the surveyed area, as well as their alteration products included in regolith, is homogeneous enough to be used as a faithful reference in monitoring studies of any kind. In addition, the significant ¹³⁷Cs activities measured in some top “soil” samples (up to 92 Bq kg^?1) strongly suggest that there are mineralogical specificities of the peridotite-derived regolith able to fix that radionuclide. This particular feature reinforces the existing criteria that favour the peridotites of Morais as a suitable host for a near surface repository of low to intermediate level radwaste.     

Lavras do Sul: A New Equilibrated Ordinary L5 Chondrite from Rio Grande do Sul,Brazil

The new Brazilian chondrite, Lavras do Sul, was found in 1985 at Lavras do Sul, Rio Grande do Sul State-Brazil (33°30′48″S; 53°54′65″W). It consists of a single mass weighing about 1 kg, covered by a black fusion crust with grayish interior. Four polished thin sections were prepared from a slice weighing 67 g on deposit at the Museu Nacional/UFRJ. It consists mostly of chondrules and chondrule fragments dispersed in a recrystallized matrix. Most chondrules are poorly defined and range in size from 300 to 2,000 μm, although some of them show distinct outlines, particularly when viewed under cross-polarized transmitted and reflected light. The texture of chondrules varies from non-porphyritic (e.g., barred-olivine, radial-pyroxene) to porphyritic ones (e.g., granular olivine as well as olivine-pyroxene). The meteorite contains mainly olivine (Fa_24.9), low-Ca pyroxene (Fs_22.6) and metal phases, with minor amounts of plagioclase, chromite and magnetite. Mössbauer Spectroscopy studies indicate that the metal phase is kamacite, tetrataenite and antitaenite. Veins of secondary iddingsite crosscut the thin section and some ferromagnesian silicates. The chemical composition indicates that Lavras do Sul is a member of the low iron L chondrite group. The poorly delineated chondritic texture with few well-defined chondrules, the occurrence of rare clinopyroxene and plagioclase (and maskelynite) with apparent diameters ranging from 5 to 123 μm led us to classify Lavras do Sul as an equilibrated petrologic type 5. The shock features of some minerals suggest a shock stage S3, and the presence of a small amount of secondary minerals such as iddingsite and goethite, a degree of weathering W₁. The meteorite name was approved by the Nomenclature Committee (Nom Com) of the Meteoritical Society (Meteoritic Bulletin Nº99).     

Depth of faulting and ancient heat flows in the Kuiper region of Mercury from lobate scarp topography

Mercurian lobate scarps are interpreted to be the surface expressions of thrust faults formed by planetary cooling and contraction, which deformed the crust down to the brittle–ductile transition (BDT) depth at the time of faulting. In this work we have used a forward modeling procedure in order to analyze the relation between scarp topography and fault geometries and depths associated with a group of prominent lobate scarps (Santa Maria Rupes and two unnamed scarps) located in the Kuiper region of Mercury for which Earth-based radar altimetry is available. Also a backthrust associated with one of the lobate scarps has been included in this study. We have obtained best fits for depths of faulting between 30 and 39 km; the results are consistent with the previous results for other lobate scarps on Mercury.The so-derived fault depths have been used to calculate surface heat flows for the time of faulting, taking into account crustal heat sources and a heterogeneous surface temperature due to the variable insolation pattern. Deduced surface heat flows are between 19 and 39 mW m^?2 for the Kuiper region, and between 22 and 43 mW m^?2 for Discovery Rupes. Both BDT depths and heat flows are consistent with the predictions of thermal history models for the range of time relevant for scarp formation.     

Mortality risk assessment through stationary space–time covariance functions

Dynamic life tables arise as an alternative to the standard (static) life tables with the aim of incorporating the evolution of mortality over time. These tables can be considered as a two-way table on a grid equally spaced in either the vertical (age) or horizontal (year) directions, and the data can be decomposed into a deterministic large-scale variation (trend) plus a stochastic small-scale variation (residuals). In this context, space–time geostatistical methods can be used for fitting and predicting the dynamic mortality. We use four different space–time covariance functions for fitting and predicting mortality in Spain during the period 1980–2005. In particular, we aim at showing the behavior of separable versus nonseparable fitted structures on one hand, and the behavior of simple structures given by combinations of products and sums versus more complicated negative structures on the other hand.     

A field study of orographic precipitation anomalies during high velocity winds using an aerofoil rain gauge

Summary This study was prompted by a need to explain an anomaly in the apparent precipitation distribution over a prominent mountain subject to a high velocity westerly airstream. Historical data reveal that the lee receives 58% more precipitation than the summit. A novel rain gauge with a vertically orientated collecting orifice, 3 standard rain gauges and complementary wind data were procured from 3 sites on the mountain to assess the effect of the airstream on the precipitation distribution. The catch efficiency of standard rain gauges decrease after the wind velocity exceeds 2.5 ms^–1 Results indicate that the summit actually receives 59% more precipitation than the lee, where a vortex directly affects the precipitation distribution over, and east, of the mountain.With 11 Figures