Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA

An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.     

Decades of Drought, Years of Hunger: Archival Investigations of Multiple Year Droughts in Late Colonial Chihuahua

Unusually severe or prolonged drought ranks among the most devastating and calamitous of all extreme climate events, contributing to wildfires, crop failure, livestock death, food shortages and famine. The response of human activities and the natural environment to such historical weather perturbations provides a guide to where the most critical sensitivities to future climate changes may lie (McCarthy et al., 2001, ‘Climatic change 2001: Impact adaptation, and vulnerability’, from 3rd Assesment Report of IPCC). The reconstruction of regional climatic histories and investigations of the impacts of – and social response to – extreme droughts in history are thus of crucial significance if we are to understand and anticipate the potential repercussions of future events (Wigley, 1985, Nature 316, 106–107; Grove and Conterio, 1995, Clim. Change 30, 223). Chihuahua, in the arid Northwest of Mexico, is one of the most seriously and frequently drought affected regions of the country (Garcia, 2000, available at www.sequia.edu.mx/proyectos/vulnera.html). Prolonged drought in the 1930s, 1950s and 1990s contributed to water scarcity, harvest failure, illness, livestock disease, abandonment and water conflict and served to highlight the particular vulnerability of agrarian society in this region to climatic variability (Sandoval, 2003, Ingeneria Hidraulica en Mexico 18(2), 133–155). Recent investigations using tree ring analysis have identified several phases of such prolonged drought over the last seven centuries. In this paper we use archival documents to investigate the impacts of such periods in late colonial Chihuahua and to explore how society in the region responded to and coped with them.     

Long-term neutralisation potential of red mud bauxite with brine amendment for the neutralisation of acidic mine tailings

Acid mine drainage is an environmental problem produced when sulphide in mine tailings dams comes in contact with O₂, bacteria and water. Oxidation occurs and a succession of reactions is responsible for producing acid and metals in the environment. One solution proposed is to use red mud bauxite (RMB) that is very alkaline to neutralise acidic tailings. Previous experiments showed that RMB has a good neutralisation capacity for a short time, but the long-term neutralisation potential is uncertain. So brine was added to RMB to verify if it can improve long-term alkalinity retention of RMB. Some authors have presented results where seawater or other natural or artificial Ca- and Mg-rich brines were used with RMB to convert the basicity (mainly NaOH) and other soluble alkalinity into low solubility hydroxide, carbonate and hydroxycarbonate minerals. Results showed that neutral pH conditions were maintained over the entire test for RMB and a mixture of RMB with brine. Addition of brine to RMB slightly lowered the pH compared to RMB alone. RMB alone lost a lot of dissolved alkalinity at the beginning of the test. Most of the alkalinity was lost in water after a few flushes for RMB samples. The addition of brine helped to keep neutralisation potential over more cycles of leaching.     

Morphometrical analysis of torrential flows-prone catchments in tropical and mountainous terrain of the Colombian Andes by machine learning techniques

Natural Hazards - Assessment of susceptibility to torrential flows at the catchment scale is a necessary step for prioritising zones that can be identified by hazard and risk maps. In the Andean...     

Prediction of California Bearing Ratio from Index Properties of Soils Using Parametric and Non-parametric Models

This work proposes a methodology to obtain from the soils properties the best prediction model for the California bearing ratio index. The methodology proposes three different prediction techniques: (1) the multiple linear regression, a classical parametric technique; and two non-parametric techniques: (2) the local polynomial regression (LPR) and (3) the radial basis network. The LPR is a known statistical method, but in the geotechnical engineering field is not in common use. Besides, although several research works have been published in this field, they do not include a robust procedure for making good comparison between different models. Here, a cross validation method is proposed with this aim. A data set of 96 samples from Peruvian soils is used to illustrate the methodology. To validate the proposed methodology, a data set from the literature is also analyzed.     

New Hamiltonian expansions adapted to the Trojan problem

A number of studies, referring to the observed Trojan asteroids of various planets in our Solar System, or to hypothetical Trojan bodies in extrasolar planetary systems, have emphasized the importance of so-called secondary resonances in the problem of the long term stability of Trojan motions. Such resonances describe commensurabilities between the fast, synodic, and secular frequency of the Trojan body, and, possibly, additional slow frequencies produced by more than one perturbing bodies. The presence of secondary resonances sculpts the dynamical structure of the phase space. Hence, identifying their location is a relevant task for theoretical studies. In the present paper we combine the methods introduced in two recent papers (Páez and Efthymiopoulos in Celest Mech Dyn Astron 121(2):139, 2015; Páez and Locatelli in MNRAS 453(2):2177, 2015) in order to analytically predict the location of secondary resonances in the Trojan problem. In Páez and Efthymiopoulos (2015), the motion of a Trojan body was studied in the context of the planar Elliptic Restricted Three Body or the planar Restricted Multi-Planet Problem. It was shown that the Hamiltonian admits a generic decomposition \(H=H_b+H_{sec}\). The term \(H_b\), called the basic Hamiltonian, is a model of two degrees of freedom characterizing the short-period and synodic motions of a Trojan body. Also, it yields a constant ‘proper eccentricity’ allowing to define a third secular frequency connected to the body’s perihelion precession. \(H_{sec}\) contains all remaining secular perturbations due to the primary or to additional perturbing bodies. Here, we first investigate up to what extent the decomposition \(H=H_b+H_{sec}\) provides a meaningful model. To this end, we produce numerical examples of surfaces of section under \(H_b\) and compare with those of the full model. We also discuss how secular perturbations alter the dynamics under \(H_b\). Secondly, we explore the normal form approach introduced in Páez and Locatelli (2015) in order to find an ‘averaged over the fast angle’ model derived from \(H_b\), circumventing the problem of the series’ limited convergence due to the collision singularity at the 1:1 MMR. Finally, using this averaged model, we compute semi-analytically the position of the most important secondary resonances and compare the results with those found by numerical stability maps in specific examples. We find a very good agreement between semi-analytical and numerical results in a domain whose border coincides with the transition to large-scale chaotic Trojan motions.     

Quantifying deforestation and secondary forest determinants for different spatial extents in an Amazonian colonization frontier (Rondonia)

Spatial patterns of deforested areas and secondary forest are analyzed in terms of the spatial variation in location factors at different spatial extents. The spatial extents considered are old and new agrarian colonization projects and the administrative units of two different municipalities in Rondonia: Vale do Anari and Machadinho d'Oeste. A grid database was constructed including land cover and potential location factors based on biophysical, accessibility, socioeconomic and policy data. Results of the spatial analyses confirmed the hypothesis that different extents yield different relationships between land use/cover patterns and their location factors, particularly between old and new agrarian colonization projects. It emphasizes that current patterns of forest, secondary forest and pasture/agriculture can only be understood with a combination of policy, accessibility, biophysical and socioeconomic factors while accounting for the historical pathways of change. Because we are dealing with different trajectories of land use/cover change, static analysis of the spatial pattern without acknowledging these trajectories will lead to erroneous interpretations of the current and future land use/cover dynamics.     

Internal structure of the aeolian sand dunes of El Fangar spit, Ebro Delta (Tarragona, Spain)

This paper presents an analysis of the dune field dynamics of El Fangar Spit in the Ebro Delta (Spain), associating it with the internal structure of dunes carried out with ground-penetrating radar and supported by data from topographic DGPS. These analyses are of great importance to ascertain the state of the internal structure of dunes as an important element in their stability and, therefore in their evolution. The internal structure shows accretion and progradation sequences of dunes over beach deposits, which depend on dune morphology (height, crest orientation) and location, as well as the processes acting on them.