Measurements of meteor smoke particles during the ECOMA-2006 campaign: 1. Particle detection by active photoionization

We present a new design of an in situ detector for the study of meteor smoke particles (MSPs) in the middle atmosphere. This detector combines a classical Faraday cup with a xenon-flashlamp for the active photoionization/photodetachment of MSPs and the subsequent detection of corresponding photoelectrons. This instrument was successfully launched in September 2006 from the Andøya Rocket Range in Northern Norway. A comparison of photocurrents measured during this rocket flight and measurements performed in the laboratory proves that observed signatures are truly due to photoelectrons. In addition, the observed altitude cut-off at 60 km (i.e., no signals were observed below this altitude) is fully understood in terms of the mean free path of the photoelectrons in the ambient atmosphere. This interpretation is also proven by a corresponding laboratory experiment. Consideration of all conceivable species which can be ionized by the photons of the xenon-flashlamp demonstrates that only MSPs can quantitatively explain the measured currents below an altitude of 90 km. Above this altitude, measured photocurrents are most likely due to photoionization of nitric oxide. In conclusion, our results demonstrate that the active photoionization and subsequent detection of photoelectrons provides a promising new tool for the study of MSPs in the middle atmosphere. Importantly, this new technique does not rely on the a priori charge of the particles, neither is the accessible particle size range severely limited by aerodynamical effects. Based on the analysis described in this study, the geophysical interpretation of our measurements is presented in the companion paper by Strelnikova, I., et al. [2008. Measurements of meteor smoke particles during the ECOMA-2006 campaign: 2. results. Journal of Atmospheric and Solar-Terrestrial Physics, this issue, doi:10.1016/j.jastp.2008.07.011].     

Bladed Texture and Exploration Implications. A Case Study from the Kuklitsa Deposit,Krumovgrad Goldfield,SE Bulgaria

This study demonstrates that the bladed texture, which is common in epithermal, low-sulfidation (adularia-sericite) precious metal deposits, can serves as exploration vector towards precious metal mineralization. The paper presents two styles of bladed texture in the Kuklitsa gold deposit (Krumovgrad goldfield, SE Bulgaria) observed at both different altitude and lateral position in respect to regional low-angle detachment fault. The first style has formed as a crackle breccia just above the detachment fault where bladed texture consists of 10–20 vol % pseudorhombic adularia, 90-80 vol % quartz, scarce pyrite, and electrum, which is often observed under optical microscope. The second style is present in steep veins which fill listric faults of sharp tectonic contacts. It is developed at a higher level relative to the detachment fault. Bladed texture there consists of 1–2 vol % pseudorhombic adularia, 99-98 vol % quartz, and scarce both electrum and pyrite. Electrum of the two styles of bladed texture comprises only gold and silver but in different proportions with a higher gold content for the first style: fineness of 765, on average, for the first style vs. fineness of 692 for the second one. In this way, it is found that the adularia abundance correlates positively with the electrum one and negatively with the quartz abundance. The author uses the proportions of adularia, quartz and electrum, the fineness of electrum, and the relative distance to the detachment fault to conclude that the first style of bladed texture has been formed at higher temperature relative to the second style. The author infers that the first style is promising for mineralization of higher grade. Methods used comprise field observations and sampling, optical and electron microscopy, powder X-ray diffraction and electron microprobe analysis.

     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Mid-Miocene thermal impact on the lithosphere by sub-lithospheric convective mantle material: Transition from high- to moderate-Mg magmatism beneath Vitim Plateau,Siberia

High-Mg lavas are characteristic of the mid-Miocene volcanism in Inner Asia.In the Vitim Plateau,small volume high-Mg volcanics erupted at 16-14 Ma.and were followed with voluminous moderate-Mg lavas at 14-13 Ma.In the former unit,we have recorded a sequence of(1) initial basaltic melts,contaminated by crustal material,(2) uncontaminated high-Mg basanites and basalts of transitional(K-Na-K) compositions,and(3) picrobasalts and basalts of K series;in the latter unit a sequence of(1) initial basalts and basaltic andesites of transitional(Na-K-Na) compositions and(2) basalts and trachybasalts of K-Na series.From pressure estimation,we infer that the high-Mg melts were derived from the sublithospheric mantle as deep as 150 km,unlike the moderate-Mg melts that were produced at the shallow mantle.The 14-13 Ma rock sequence shows that initial melts equilibrated in a garnet-free mantle source with subsequently reduced degree of melting garnet-bearing material.No melting of relatively depleted lithospheric material,evidenced by mantle xenoliths,was involved in melting,however.We suggest that the studied transition from high-to moderate-Mg magmatism was due to the mid-Miocene thermal impact on the lithosphere by hot sub-lithospheric mantle material from the Transbaikalian low-velocity(melting) domain that had a potential temperature as high as 1510℃.This thermal impact triggered rifting in the lithosphere of the Baikal Rift Zone.     

Biological reduction of chlorinated solvents: Batch-scale geochemical modeling

Simulation of biodegradation of chlorinated solvents in dense non-aqueous phase liquid (DNAPL) source zones requires a model that accounts for the complexity of processes involved and that is consistent with available laboratory studies. This paper describes such a comprehensive modeling framework that includes microbially mediated degradation processes, microbial population growth and decay, geochemical reactions, as well as interphase mass transfer processes such as DNAPL dissolution, gas formation and mineral precipitation/dissolution. All these processes can be in equilibrium or kinetically controlled. A batch modeling example was presented where the degradation of trichloroethene (TCE) and its byproducts and concomitant reactions (e.g., electron donor fermentation, sulfate reduction, pH buffering by calcite dissolution) were simulated. Local and global sensitivity analysis techniques were applied to delineate the dominant model parameters and processes. Sensitivity analysis indicated that accurate values for parameters related to dichloroethene (DCE) and vinyl chloride (VC) degradation (i.e., DCE and VC maximum utilization rates, yield due to DCE utilization, decay rate for DCE/VC dechlorinators) are important for prediction of the overall dechlorination time. These parameters influence the maximum growth rate of the DCE and VC dechlorinating microorganisms and, thus, the time required for a small initial population to reach a sufficient concentration to significantly affect the overall rate of dechlorination. Self-inhibition of chlorinated ethenes at high concentrations and natural buffering provided by the sediment were also shown to significantly influence the dechlorination time. Furthermore, the analysis indicated that the rates of the competing, nonchlorinated electron-accepting processes relative to the dechlorination kinetics also affect the overall dechlorination time. Results demonstrated that the model developed is a flexible research tool that is able to provide valuable insight into the fundamental processes and their complex interactions during bioremediation of chlorinated ethenes in DNAPL source zones.     

Great Silk Road on the Territory of Kazakhstan: From Past to Future

The Great Silk Road is a trade route linking the East and West which gave impetus to the development of ancient society, and Kazakhstan is the heart of the trade route. At the initial stage, intensive transaction of goods took place between the West and East through The Great Silk Road. This paper reviewed the history of development of the Silk Road and suggested that today to construct the "New Silk Road", Kazakhstan should face many issues, and take many steps to become a Eurasian hub through taking full of advantages. Above all, developing mechanisms of integration and sustainable development is our urgent need.     

Strontium stable isotopes fractionate in the soil environments?

This study shows that the stable isotopic composition of strontium (the ⁸⁸Sr/⁸⁶Sr ratio expressed as δ^88/86Sr value relative to the NBS987 standard) varies significantly in sedimentary terrestrial environments. The abundances of ⁸⁶Sr, ⁸⁸Sr isotopes were analyzed by MC-ICP-MS “Nu Plasma”. All studied rocks and waters show δ^88/86Sr values that are distinctly different from the measured NBS987 standard (yielding 0.01 ± 0.05‰, all errors are reported as 2σ). Modern corals from the northern Gulf of Aqaba, Red Sea yielded significantly different value than seawater (δ^88/86Sr = 0.22 ± 0.07‰, compared to 0.35 ± 0.06‰, respectively), in an excellent correlation with the δ^88/86Sr analyses reported by Fietzke and Eisenhauer [Fietzke, J., Eisenhauer, A., 2006. Determination of temperature-dependent stable strontium isotopes (⁸⁸Sr/⁸⁶Sr) fractionation via bracketing standard MC-ICP-MS. Geochm. Geophys. Geosyst. 7 (no. 8)] on other coral samples. All carbonate samples that originated in the marine environment: corals (porites and acropora from the northern Gulf of Aqaba); Cretaceous limestone and runoff from the Judea Mountains as well as lacustrine evaporitic aragonite (Dead Sea); and Red Sea and Atlantic seawater yield an average δ^88/86Sr value of 0.26 ± 0.1‰. On the other hand, secondary materials (products of chemical weathering) from the terrestrial environment of the Judea Mountain such as terra rossa soil and speleothem calcite (that derives its Sr from the above-lying soil) yielded significantly lower δ^88/86Sr value of − 0.17 ± 0.06‰. This indicates that strontium isotopes fractionate in the soil environment calling for a possible development of strontium isotopes as a tracer for processes of chemical weathering and pedogenesis.     

Quantifying sediment storage on the floodplains outside levees along the lower Yellow River during the years 1580–1849

The lower Yellow River channel was maintained by artificial levees between 1580 and 1849. During this period, 280 levee breaches occurred. To estimate sediment storage on the floodplains outside the levees, a regression model with a decadal time step was developed to calculate the outflow ratio for the years when levee breaching occurred. Uncertainty analysis was used to identify the likely outflow ratio. Key variables of the model include annual water discharge, a proxy for levee conditions, and potential bankfull discharge of the channel before flood season. Uncertainty analysis reveals an outflow ratio of 0.35–0.56. We estimate that during this period, 18.8–30.1% of the total ~312 Gt of sediment load was deposited on the floodplains outside the levees. Human-accelerated erosion in the Loess Plateau caused a 4-fold increase in sediment delivery to the lower Yellow River, which could not be accommodated by channel morphodynamic changes. As a result, 21.2–27.5% of the total sediment load was deposited within the levees, creating a super-elevated channel bed that facilitated an uncommonly high breach outflow ratio. Hence, the factor of a large super-elevation relative to the mean main channel depth should be considered when designing diversions to restore floodplains. © 2018 John Wiley & Sons, Ltd.