Determination of Iodine in Thirty Two International Geochemical Reference Materials

Thirty two geochemical reference samples have been analysed for their iodine contents by a pyrohydrolysis extraction technique, followed by colourimetry. In spite of the existence of few reported values for iodine, limiting comparison with results from this study, the four available "reference" values show good agreement with the work reported here.     

Upper-Level Winds over Southern Ontario: O-QNet Wind Profiler and NARR Comparisons

Upper-level winds are primarily measured by tracking the position of radiosonde balloons as they rise through the atmosphere. Radiosondes are released from a global network at 0000 utc and 1200 utc each day, and data are quickly available to the world's weather services, as well as to the public. The network is relatively coarse spatially, and there are normally only two soundings per day. In an endeavour to provide better spatial and temporal upper-level regional wind measurements, the O-QNet (a demonstration very high frequency wind profiler network for Ontario and Quebec) was installed and has been operated by York, Western, and McGill Universities with support from Mardoc Inc., The Weather Network, and Environment and Climate Change Canada. Initial funding was provided by the Canada Foundation for Innovation, the Ontario Innovation Trust, and Mardoc Inc. The present paper reports primarily on comparisons between winds measured by the O-QNet profilers and the winds reported in the North American Regional Reanalysis (NARR). There is good agreement between the two, which provides support for the use of NARR data to investigate longer term variations in upper-level winds associated with climate change for this region.     

Load Settlement Behaviour of Fly ash Mixed with Waste Sludge and Cement

One of the effective utilization strategies for fly ash and waste sludge is to use it as a fill material to raise low lying areas. Bearing capacity and settlement are the required input for the design of foundations on such fills. To determine the bearing capacity, plate load tests were carried out on the compacted beds of fly ash, fly ash-waste sludge and fly ash-waste sludge–cement. The tests were conducted by keeping 90, 95 and 100 % relative compaction, fresh and fresh submerged conditions, aged (28 days) and aged (28 days) submerged conditions as variables of the tests. The load-settlement curves were plotted for fly ash and mix blends. The minimum load was obtained for fly ash under submerged condition, further the test results show that the fly ash becomes flowable on submergence. On the other hand when the fly ash was mixed with waste sludge and cement, the load carrying capacity was found to improve to a greater extent. Test beds prepared with fly ash–cement-waste sludge under as compacted condition (fresh) show very high load carrying capacity (1600–2180 kN/m²). An analytical method has also been validated for fly ash–cement-waste sludge mix which was developed to estimate the settlement of footing resting on fly ash taking into account the pre-consolidation stresses. The non linearity of load-settlement behavior was appropriately modeled, on the basis of available plate load test data incorporated in the method. The method requires as input, the pre-consolidation stress and Young’s modulus of compacted mix of fly ash-waste sludge–cement. A comparison of load-settlement values observed in plate load tests and predicted values for the mix 47 %FA + 45 %S + 8 %C, using the proposed method shows good agreement. Hence, this relationship may also be useful to the field engineers to check the reported load-settlement values for such types of mixes in the field.     

Groundwater aggressiveness assessment according to EN 206-1: data,methods and application on groundwater in the Horna Nitra basin,Slovakia

The history of groundwater aggressiveness evaluation procedures applied in the Slovak Republic is summarized and compared with the newly adopted European technical standard STN EN 206-1. The methodology of data acquiring and processing for groundwater aggressiveness evaluation was proposed. The procedure included basic principles of data mining, requested number of chemical analyses and ways of groundwater aggressiveness assessment. Ways of results interpretation and graphical visualization were proposed, too. The procedure was applied in the area of the Horna Nitra in Slovakia. A total number of 953 groundwater analyses were used to assess the groundwater aggressiveness. The resulting map of zoning comprised eight groundwater aggressiveness zones. Zones with the non-aggressive degree (X0) groundwater to moderately aggressive degree (XA2) were delineated. The aggressiveness was caused mainly by presence of aggressive carbon dioxide (depending on the rock type in the area) and by lowered pH values in association with increased sulfate contents in areas of brown coal mining activities and in heavy industrialized areas. The compilation of a locality map was proposed, where for each municipality type and degree of aggressiveness is assessed. It should serve to local authorities as background information within the decision-making process connected to the permission of construction work.     

Ion-Acoustic Wave Generation by Two Kinetic Alfvén Waves and Particle Heating

In this paper we have investigated the beat wave excitation of an ion-acoustic wave at the difference frequency of two kinetic (or shear) Alfvén waves propagating in a magnetized plasma with β<1 (β=8π n _e0 T _e/B ₀ ² , where n _e0 is the unperturbed electron number density, T _e is the electron temperature, and B ₀ is the external magnetic field). On account of the interaction between two kinetic Alfvén waves of frequencies ω ₁ and ω ₂, the ponderomotive force at the difference frequency ω ₁−ω ₂ leads to the generation of an ion-acoustic wave. Also because of the filamentation of the Alfvén waves, magnetic-field-aligned density dips are observed. In this paper we propose that the ion-acoustic wave generated by this mechanism may be one of the possible mechanisms for the heating and acceleration of solar wind particles.     

Where will widening occur in an outwash braidplain? A new approach to detecting controls on fluvial lateral erosion in a glacierized catchment (north-western Spitsbergen,Svalbard)

The dynamics of fluvial system evolution depend on fluvial processes and their driving forces associated with climatic variations, which affect changes in the morphology of river channels and floodplains. Neither channel slope and morphology, nor the properties of fluvial sediment have previously been considered as determinants of active braidplain widening on outwash plains (formed from valley/alpine glaciers and confined by pre-existing topography) in the High Arctic region and in the forefields of retreating glaciers. Factors determining widening of braidplain activity of the Waldemar River outwash (north-western Spitsbergen, Svalbard) were analysed on the basis of geomorphological, sedimentological, glaciological and meteorological research, and indicate significant multiple correlations between meltwater discharge, precipitation, braidplain width, morphology of the braided channel and the textural features of braidplain deposits. The capability of multivariate adaptive regression splines to detect these relationships was described, and threshold values were identified. The results indicate that the rate of active braidplain widening is proportional to the meltwater outflow in proglacial rivers, which can decrease despite a growing rate of glacial ablation. A proposed model enables us to predict zones of braidplain prone to widening activity in the High Arctic (humid) outwash fans and plains as well as fans developed in arid intermountain basins. The necessary conditions to activate braidplain widening processes were (1) spatial changes in the outwash feeding system due to glacier terminus retreat and (2) crossing the thresholds in passive factors (S and d₅₀) controlling lateral erosion intensity. As a result, the braidplain reached a new dynamic equilibrium, in which high-magnitude–low-frequency extreme meltwater discharges were of particular importance in terms of braidplain dynamics and are the dominant controls on the pattern of distributary channels.     

Changes in The Dynamics And Thermal Regime of The Permafrost and Active Layer of The High Arctic Coastal Area in North‐West Spitsbergen,Svalbard

In this paper changes in the active layer of the high arctic coastal area in north‐west Spitsbergen, Svalbard are described. Analysis includes both the ground thawing depth and its near‐surface thermal structure. The study was conducted on the Kaffiøyra Plain (Svalbard) at several fixed sites, which represent places typical of the region: a sandy beach, a tundra plain and a moraine ridge. The results show that in recent years, at two measurement points a significantly deeper thawing was observed. In 1996–2012 on the beach and on the moraine the trend of active layer thickness change was +1.3 cm yr^?1 and +2.5 cm yr^?1, respectively. Generally, in the years 2008–2012 the mean thickness of the active layer in the Kaffiøyra region increased by 3% to 6%. Even at the spatially close sites, within similar environments, there are significant differences in the thickness of the active layer. Measurements show that significant changes also occurred in the thawed ground temperature. Mean values of the observed near‐surface temperature in recent years (2007–2011) were higher by more than 1.0°C, in comparison to the mean in the late 1970s.     

Dating of small gully formation and establishing erosion rates in old gullies under forest by means of anatomical changes in exposed tree roots (Southern Poland)

Small gullies occur in forested gully systems on the undulating loess plateau in southern Poland. The old gully hillslopes are mainly covered with 200-year old beech trees in contrast with the surface of the summit plateau, which is cultivated agricultural land. Beech roots are exposed in the gullies through erosion. Wood vessels in the root tree rings divide into early wood and late wood and, after the roots are exposed, start to make fewer vessels. These anatomical changes in root tree rings allow us to date erosion episodes.Small gullies form in a different manner on the valley floor and on hillslopes. In valley bottoms, erosion features are often formed at some distance from one another, and in time small gullies combine to form a single, longer one. Depending on local conditions, such as the hillslope profile, hillslopes may exhibit headward erosion or may be eroded downwards. Hilllope gullies may be transformed into side valleys as a result of gradual widening and deepening.Dating the exposure of roots indicates that small gullies had already formed in the valley system by 1949. Intensive gully erosion was recorded between 1984 and 2002, during intense precipitation in 1984 and, of particular note, during the extraordinary flood of 1997 which affected all of Central Europe. The mean rate of small gully erosion in the old gully system studied is 0.63 m/year. On hillslopes the mean gully erosion rate is 0.21–0.52 m/year, and on the valley bottoms 0.18–1.98 m/year. High bottom erosion rates resulted from the emergence of long gullies during the erosion episodes in 1984 and 1997. Sheet flow in valley floors intensifies at times of heavy rainfall which causes long gullies to form.Taking into account the fact that conditions favoured erosion, the rate at which the old gullies under forest were transformed should be considered slow. New side gullies form slowly within the valley and it appears that if erosion progressed at the rate observed, new side valleys would take a few hundred years to form.     

Coupling between landslides and eroding stream channels reconstructed from spruce tree rings (examples from the Carpathians and Sudetes – Central Europe)

The analysis of the positive feedback between landslides and erosion requires determination of the precise temporal and spatial relations between events of colluvium delivery and fluvial erosion. In our study we use decennial datasets on the occurrence of landsliding and erosion achieved through dendrochronological methods. Four sites covering areas of landslide slopes and adjacent valley floors with stream channels were studied. Landsliding on slopes was dated from the tree‐ring eccentricity developed in stems tilted due to bedrock instability. Erosion in channels was dated using the wood anatomy of roots exposed by erosion of the soil cover. Analysis of the temporal relations between dated landsliding, erosion and precipitation record has revealed that two types of repeating sequences can be observed: (1) rainfall → landsliding → erosion; (2) rainfall → erosion → landsliding. These sequences are an indication of the occurrence of slope‐channel positive feedback in the sites studied. In the first type, landsliding triggered by rainfall delivers colluvia into the valley floor and causes its narrowing, which in turn causes increased erosion. In the second type erosion triggered by rainfall disturbs the slope equilibrium and causes landsliding. Landsliding and erosion, once triggered by precipitation, can occur alternately in years with average precipitation and reinforce one another. Bidirectional coupling between landsliding and channel erosion was shown notably through the effects of channel shifting and forced sinuosity and by increased erosion of the slopes opposite the active landslides. Observations also suggest that the repetition of sequences described over longer periods of time can lead to a general widening of the valley floor at the expense of slopes and to a gradual change of the valley cross‐profile from narrow, V‐shaped into a wide flat‐bottomed. Thus landsliding–erosion coupling/positive feedback was recognized as an important factor shaping hillslope–valley topography of the mid‐mountain areas studied. Copyright © 2014 John Wiley & Sons, Ltd.