Hydrogeochemistry of the Goulburn Valley region of the Murray Basin, Australia: implications for flow paths and resource vulnerability

Groundwater in the Goulburn region of the Murray Basin (Australia) contains solutes derived mainly from evapotranspiration of rainfall-derived marine aerosols, silicate dissolution, and ion exchange. ¹⁴C data indicate that groundwater in the Shepparton Formation recharges vertically across the region, whereas groundwater in the Calivil–Renmark Formation shows a greater component of lateral flow. The overall pattern of geochemical and stable isotope variations implies that long-term vertical groundwater flow into the Calivil–Renmark Formation has occurred over thousands of years. Elevated C, N, and F concentrations, together with variable Cl/Br ratios and ¹⁸O values, suggest that short-term (years to decades) flow of surface water into the Calivil–Renmark Formation also occurs locally. The high degree of vertical flow implies that the high-quality groundwater resources of the Calivil–Renmark Formation are vulnerable to surface contamination. Groundwater in both the Shepparton and Calivil–Renmark Formations yields ¹⁴C ages of up to 20 ka that imply that, overall, recharge rates are low and that, consequently, the groundwater resource in both formations could be impacted by over abstraction.

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Resumen Las aguas subterráneas de la región de Goulburn, en la cuenca del río Murray (Australia), contienen solutos procedentes principalmente de la evaporación de agua de lluvia, disolución de silicatos e intercambio iónico. Aunque la variabilidad espacial de la hidrogeoquímica es reducida, el contenido total de sales disueltas en las aguas subterráneas de la formación no confinada de Shepparton es generalmente mayor que el del acuífero inferior confinado de la Formación Calivil–Renmark. Los datos de ¹⁴C, ³H y geoquímica sugieren que la recarga del acuífero de la Formación Shepparton es por infiltración (vertical) en toda la región, mientras que la Formación Calivil–Renmark tiene una mayor proporción de aportes laterales. Sin embargo, a escala local se produce recarga vertical en la Formación Calivil–Renmark, hecho que indica que este recurso es vulnerable a la contaminación. Las aguas subterráneas de ambas formaciones tienen edades de hasta 20.000 años, según datos de ¹⁴C, lo que implica que las tasas de recarga son bajas y, en consecuencia, que podría haber impactos asociados a la sobreexplotación del recurso. Las aguas subterráneas recientes de la región se caracterizan por relaciones molares muy variables de Cl/Br (de 50 a 1.200), reflejando la química de una precipitación semiárida que se ve modificada posteriormente por disolución de halita, asociada con terrenos secos y riego con aguas salinas. Las aguas subterráneas más profundas presentan relaciones más uniformes de Cl/Br (entre 500 y 800), y probablemente reflejan que la recarga se produjo en condiciones climáticas más húmedas que las actuales.

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Résumé Les eaux souterraines de la région de Goulburn dans le bassin de Murray (Australie) contiennent des solutés provenant essentiellement de lévaporation des pluies, de la dissolution de silicates et déchanges dions. Alors quil y a peu de variations spatiales du chimisme des eaux souterraines, les concentrations en sels dissous totaux des eaux souterraines de laquifère libre de la formation de Shepparton sont en général plus élevées que celles des eaux souterraines de laquifère captif sous-jacent de la formation de Calivil-Renmark. Des données de carbone-14, de tritium et de géochimie indiquent que laquifère de la formation de Shepparton est rechargé verticalement dans toute la région, tandis que laquifère de la formation de Calivil-Renmark présente une plus forte composante découlement latéral. Toutefois, localement, il se produit une recharge verticale de laquifère de la formation de Calivil-Renmark, ce qui indique que cette ressource est vulnérable à la contamination. Les eaux souterraines des formations de Shepparton et de Calivil-Renmark présentent toutes deux des âges carbone-14 de plus de 20 ka, ce qui implique des taux de recharge très faibles et, par conséquent, que leur ressource peut être affectée par des prélèvements excessifs. Les eaux souterraines récentes dans cette région sont caractérisées par un rapport molaire Cl/Br très variable (de 50 à 1200), qui reflète le chimisme de pluies en région semi-aride modifié en conséquence par la dissolution de la halite associée à la salinité due aux terres sèches et à lirrigation. Les eaux souterraines plus profondes possèdent des rapports Cl/Br plus uniformes (de lordre de 500 à 800) et reflètent probablement des eaux de recharge sous des conditions climatiques plus humides que les conditions actuelles.

     

ACHONDRITE ALHA77005: ALTERATION OF CHROMITE AND OLIVINE

The olivine crystals of the 77005 achondrite are brown except for colorless shock lamellae, mottled patches, and grains adjacent to pools of impact melt. Sporadic dark alteration patches in brown olivine and Cr-rich spinel gave the following average electron-microprobe analyses: (olivine) P₂O₅ 0.9, SiO₂ 57.9, TiO₂ 0, Al₂O₃ 0.7, Cr₂O₃ 0.4, V₂O₃ 0, Fe₂O₃ (assumed oxidation state) 17.0, MgO 1.6, CaO 0.2, Na₂O 0, K₂O 1.8, SO₃ (assumed oxidation state) 9.2, Cl 0.1, sum 89.8 wt. %; (spinel) P₂O₅3.5, SiO₂2.1, TiO₂.2.2, Al₂O₃2.1, Cr₂O₃ 13.4, V₂O₃ 0.8, Fe₂O₃ 40.7, MgO 0.9, CaO 0.1, Na₂O 0, K₂O 2.0, SO₃ 11.1, Cl 0.1, sum 79.0 wt.%. Ion-microprobe analyses revealed H in both. Rare orange patches in brown olivine from another area gave SiO₂ 33–35, FeO 30-28, MgO 28–32, sum 93 wt. %. Thermal metamorphism under dry oxidizing conditions is discussed as a possible alternative to shock-induced oxidation for generation of the brown olivine (McSween and Stöffler). Because alteration patches transgress shock lamellae, and because sulfatic alteration occurs in fusion crusts of Antarctic meteorites (Gibson et al., 1983), alteration of the 77005 achondrite at the Antarctic surface is preferred to a complex series of processes needed for pre-terrestrial alteration.     

Relating Radar Remote Sensing of Biomass to Modelling of Forest Carbon Budgets

This paper addresses the use of radar remote sensing to map forest above-ground biomass, and discusses the use of biomass maps to test a dynamic vegetation model that identifies carbon sources and sinks and predicts their variation over time. For current radar satellite data, only the biomass of young/sparse forests or regrowth after disturbances can be recovered. An example from central Siberia illustrates that biomass can be measured by radar at a continental scale, and that a significant proportion of the Siberian forests have biomass values less than 50 tonnes/ha. Comparison between the radar map and calculations by the Sheffield Dynamic Global Vegetation Model (SDGVM) indicates that the model considerably overestimates biomass; under-representation of managed areas, disturbed areas and areas of low site quality in the model are suggested reasons for this effect. A case study carried out at the Büdingen plantation forest in Germany supports the argument that inadequate representations of site quality and forest management may cause model overestimates of biomass. Comparison of the calculated biomass of stands planted after 1990 with biomass estimates by radar allows identification of forest stands where the growth conditions assumed by the model are not valid. This allows a quality check on model calculations of carbon fluxes: only calculations for stands where there is good agreement between the data and the model predictions should be accepted. Although the paper only uses the SDGVM model, similar effects are likely in other dynamic vegetation models, and the results show that model calculations attempting to quantify the role of forests as carbon sources or sinks could be qualified and potentially improved by exploiting remotely sensed measurements of biomass.     

Scalar fluxes from urban street canyons. Part I: Laboratory simulation

Flow over urban surfaces depends on surface morphology and interaction with the boundary layer above. However, the effect of the flow on scalar fluxes is hard to quantify. The naphthalene sublimation technique was used to quantify scalar vertical fluxes out of a street canyon under neutral conditions. For an array of eight canyons with aspect ratio H/W=0.75 (here, H is building height and W is the street width), increased flux was observed in the first two or three canyons for moderate and low roughness upstream. This is consistent with predictions of the length scale for initial adjustment of flow to an urban canopy. The flux was constant after the initial adjustment region and thus dependent only on local geometry. For a street canyon in the equilibrium part of the array, each facet of the street canyon was coated with naphthalene to simulate scalar release from street, walls and roof, to evaluate the effect of street canyon geometry on fluxes for H/W=0.25, 0.6, 1 and 2. Fluxes from the roof and downstream wall were considerably larger than fluxes from the street and upstream wall, and only the flux from the downstream wall exhibited a simple decrease with H/W. For each H/W there was a monotonic decrease between downstream wall, street and upstream wall transfer. This suggests that flow decelerates around the recirculation region in the lee of the upstream building, i.e. a recirculating jet rather than a symmetrical vortex. The addition of a second source within the street canyon resulted in reduced fluxes from each facet for H/W>0.25, due to increased concentration of naphthalene in the canyon air.     

Eclogites of the Snowbird tectonic zone: petrological and U-Pb geochronological evidence for Paleoproterozoic high-pressure metamorphism in the western Canadian Shield

Eclogite occurs within the southern domain of the East Athabasca mylonite triangle in northern Saskatchewan. Situated at the boundary between the Archean Rae and Hearne Provinces of the western Canadian Shield, the East Athabasca mylonite triangle is a fundamental exposure of the ~3,000-km-long Snowbird tectonic zone. The eclogite occurs in association with a variety of lower crustal high-pressure granulites that record a complex metamorphic history from 2.6 to 1.9 Ga. Temperatures of the eclogite facies metamorphism are constrained by garnet-clinopyroxene exchange thermometry at 920–1,000 °C. Minimum pressure conditions are recorded by the jadeite+quartz=albite geobarometer at 1.8–2.0 GPa. A near-isothermal decompression path to granulite facies conditions is inferred from retrograde reaction textures involving the formation of granulite facies assemblages such as orthopyroxene-plagioclase and pargasite-plagioclase. U-Pb IDTIMS zircon geochronology of the eclogite yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,904.0±0.3 Ma, which we interpret as the time of peak eclogite facies metamorphism. SHRIMP in situ analyses of metamorphic zircons included within omphacitic clinopyroxene support this interpretation with a weighted mean ²⁰⁷Pb/²⁰⁶Pb date of 1,905±19 Ma. Inclusion suites of high-pressure phases and the petrographic setting of zircon are a direct link between zircon growth and eclogite facies metamorphism. Zircon from one eclogite sample has older cores that are 2.54 Ga, which is a minimum age for the emplacement or earliest metamorphism of the gabbroic protolith. U-Pb rutile data indicate slow cooling at ~1°C/Ma below ~500 °C from 1.88 to 1.85 Ga. The formation and exhumation of the eclogites at ca.1.9 Ga has important implications for the tectonic significance of the Snowbird tectonic zone during the Paleoproterozoic. The eclogites described here are consistent with transport of continental crust to mantle depths during the Paleoproterozoic, followed by rapid buoyancy-driven exhumation to normal lower crustal depths.Editorial responsibility: T.L. Grove     

An Eburnean base metal source for sediment-hosted zinc-lead deposits in Neoproterozoic units of Namibia: Lead isotopic and geochemical evidence

The lead isotopic composition of galena from the Neoproterozoic sediment-hosted Zn-Pb sulphide deposit at Rosh Pinah and the oxidised Zn deposit at Skorpion in the Pan-African Gariep Belt, southwestern Namibia, as well as that of galena from minor occurrences in the wider Rosh Pinah ore province was investigated and is compared with that of other major sediment-hosted base metal ore deposits hosted by Neoproterozoic strata in southwestern Africa and Brazil. The isotope data were supplemented by a geochemical provenance study of the argillitic host rock to the Rosh Pinah deposit and its stratigraphic equivalents. The pre-orogenic Rosh Pinah deposit and the inferred progenitor for the secondary Skorpion deposits have very similar Pb isotopic compositions. In contrast, syn-orogenic deposits (e.g. Tsumeb-type) show a larger proportion of radiogenic Pb from the country rocks that were infiltrated by orogenic ore fluids.In all examples studied, the ore Pb has elevated ²⁰⁷Pb/²⁰⁴Pb ratios compared to Pb that evolved according to average crustal Pb growth models. The isotopic composition of the ore Pb is in agreement with that of the oldest crustal component known from the pre-Gariep basement, i.e. an Eburnean (c. 2.0 Ga) volcanic arc, best preserved in the Richtersveld Terrane, that represents the largest volume of post-Archaean juvenile crust in southern Africa. Erosion of that arc provided the main sediment source for the metasedimentary siliciclastic host to the Rosh Pinah deposit. Derivation of the Pb, and by analogy Zn, from this Eburnean volcanic arc is therefore inferred for the formation of Rosh Pinah-type syn-rift, early diagenetic replacement mineralisation.The calculated ₂- and ₂-values for the Rosh Pinah ore province (around 10.2 and 42, respectively) are higher than predicted by conventional Pb crustal growth models and are similar to those found in the wider region of southern Africa (Otavi Mountain Land) and eastern Brazil. The obtained data highlight not only that calculated Pb model ages may have no geochronological significance but might also point to a common crustal evolution of this part of SW-Gondwana.Editorial handling: M. Chiaradia     

GLORIA survey of the oceanic-continental transition of the Havre-Taupo back-arc basin

A GLORIA (Geological Long-Range Inclined Asdic) side-scan sonar survey, covering 23,000 km², provides the first complete imagery of an active and contiguous, oceanic to continental back-arc system, namely, the Havre Trough to Taupo Volcanic Zone (TVZ) New Zealand. Havre Trough tectonism and volcanism relates to a series of laterally discontinuous, mutiple spreading rifts which terminate southward at the 3-km-deep Ngatoro Basin. A 45-km sinistral offset attributed toen echelon synthetic shearing separates the basin from the actively spreading TVZ. Sonographs reveal a youthful and complex volcanic seascape with 20 newly discovered seamounts, whereas flanking regions are mantled with a largely featureless mud blanket.