Garnet re‐equilibration by coupled dissolution–reprecipitation: evidence from textural,major element and oxygen isotope zoning of ‘cloudy’ garnet

The analysis of texture, major element and oxygen isotope compositions of cloudy garnet crystals from a metapelite sampled on Ikaria Island (Greece) is used to assess the model of growth and re‐equilibration of these garnet crystals and to reconstruct the pressure–temperature–fluid history of the sample. Garnet crystals show complex textural and chemical zoning. Garnet cores (100–200 μm) are devoid of fluid inclusions. They are characterized by growth zoning demonstrated by a bell‐shaped profile of spessartine component (7–3 mol.%), an increase in grossular from 14 to 22 mol.% and δ¹⁸O values between 9.5 ± 0.3‰ and 10.4 ± 0.2‰. Garnet inner rims (90–130 μm) are fluid inclusion‐rich and show a decreasing grossular component from 22 to 5 mol.%. The trend of the spessartine component observed in the inner rim allows two domains to be distinguished. In contrast to domain I, where the spessartine content shows the same trend as in the core, the spessartine content of domain II increases outwards from 2 to 14 mol.%. The δ¹⁸O values decrease towards the margins of the crystals to a lowest value of 7.4 ± 0.2‰. The outer rims (<10 μm) are devoid of fluid inclusions and have the same chemical composition as the outermost part of domain II of the inner rim. Garnet crystals underwent a four‐stage history. Stage 1: garnet growth during the prograde path in a closed system for oxygen. Garnet cores are remnants of this growth stage. Stage 2: garnet re‐equilibration by coupled dissolution–reprecipitation at the temperature peak (630 < T < 650 °C). This causes the creation of porosity as the coupled dissolution–reprecipitation process allows chemical (Ca) and isotopic (O) exchange between garnet inner rims and the matrix. The formation of the outer rim is related to the closure of porosity. Stage 3: garnet mode decreases during the early retrograde path, but garnet is still a stable phase. The resulting garnet composition is characterized by an increasing Mn content in the inner rim’s domain II caused by intracrystalline diffusion. Stage 4: dissolution of garnet during the late retrograde path as garnet is not a stable phase anymore. This last stage forms corroded garnet. This study shows that coupled dissolution–reprecipitation is a possible re‐equilibration process for garnet in metamorphic rocks and that intra‐mineral porosity is an efficient pathway for chemical and isotopic exchange between garnet and the matrix, even for otherwise slow diffusing elements.     

Cosmochemical and spectroscopic properties of Northwest Africa 7325—A consortium study

This work is part of a project to build an infrared database in order to link IR data of planetary materials (and therefore possible Mercury material) with remote sensing observations of Mercury, which will probably be obtained by the MERTIS instrument on the forthcoming BepiColombo mission. The unique achondrite Northwest Africa (NWA) 7325, which has previously been suggested to represent the first sample from Mercury, was investigated by optical and electron microscopy, and infrared and Raman spectroscopy. In addition, the oxygen, strontium, xenon, and argon isotopes were measured and the abundance of selected trace elements determined. The meteorite is a cumulate rock with subchondritic abundances of HFSE and REE and elevated Sr contents, which underwent a second heating and partial remelting process. Oxygen isotope measurements show that NWA 7325 plots in the ureilite field, close to the ALM‐A trachyandesitic fragment found in the unique Almahata Sitta meteorite breccia. On the other hand, mineralogical investigations of the pyroxenes in NWA 7325 provide evidence for similarities to the lodranites and acapulcoites. Furthermore, the rock is weakly shocked and argon isotope data record ancient (~4.5 Ga) plateau ages that have not been reset. The sample records a cosmogenic exposure age of ~19 Ma. Systematics of Rb‐Sr indicate an extreme early volatile depletion of the precursor material, similar to many other achondrite groups. However, despite its compositional similarities to other meteorite groups, our results suggest that this meteorite is unique and unrelated to any other known achondrite group. An origin for NWA 7325 as a sample from the planet Mercury is not supported by the results of our investigation. In particular, the evidence from infrared spectroscopy indicates that a direct relationship between NWA 7325 and the planet Mercury can be ruled out: no acceptable spectral match between laboratory analyses and remote sensing observations from Mercury has been obtained. However, we demonstrate that infrared spectroscopy is a rapid and nondestructive method to characterize mineral phases and thus an excellent tool for planetary surface characterization in space missions.     

Verification of the RAMS-based operational weather forecast system in the Valencia Region: a seasonal comparison

Natural Hazards - The meteorological model Regional Atmospheric Modeling System (RAMS) in its version 4.4 has been applied operationally within the Valencia Region. The model output is being used...     

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.     

Masses of the local group and of the M81 group estimated from distortions in the local velocity field

Based on high precision measurements of the distances to nearby galaxies with the Hubble telescope, we have determined the radii of the zero velocity spheres for the local group, R₀ = 0.96±0.03Mpc, and for the group of galaxies around M 81/M 82, 0.89±0.05Mpc. These yield estimates of M_T = (1.29±0.14)· 10¹² M_⊙ and (1.03±0.17)· 10¹² M_⊙, respectively, for the total masses of these groups. The R₀ method allows us to determine the mass ratios for the two brightest members in both groups, as well. By varying the position of the center of mass between the two principal members of a group to obtain minimal scatter in the galaxies on a Hubble diagram, we find mass ratios of 0.8:1.0 for our galaxy and Andromeda and 0.54:1.00 for the M82 and M81 galaxies, in good agreement with the observed ratios of the luminosities of these galaxies. __________ Translated from Astrofizika, Vol. 49, No. 1, pp. 5–22 (February 2006).     

Rotational atmospheric circulation during North Atlantic-European winter: the influence of ENSO

The dominant variability modes of the North Atlantic-European rotational flow are examined by applying a principal component analysis (PCA/EOF) to the 200?hPa streamfunction mid-winter anomalies (Jan?CFeb monthly means). The results reveal that, when this norm is used, the leading mode (EOF1) does not correspond to the traditional North Atlantic Oscillation (NAO, which appears in our analysis as the second leading mode, EOF2) but is the local manifestation of the leading hemispheric streamfunction EOF. The regression of this regional mode onto the global SST field exhibits a clear El Ni?o signature, with no signal over the Atlantic, while the associated upper height anomalies resemble the Tropical/Northern Hemisphere (TNH) pattern. East of North America, this TNH-like wavetrain produces a meridional dipole-like pattern at lower levels. Although in some ways this pattern resembles the NAO (EOF2), the dynamics of these two modes are very different in that only EOF2 is associated with a latitudinal shift of the North Atlantic stormtrack. Thus, the choice of the streamfunction norm in the EOF analysis allows the separation of two different phenomena that can produce similar dipolar surface pressure anomalies over the North Atlantic but that have different impact on European climate. These two modes also differ on their contribution to variability at lower levels: while NAO-EOF2 is mostly confined to the North Atlantic, TNH-EOF1 has a more annular, global character. At upper levels NAO-EOF2 also produces a global pattern but with no annular structure, reminiscent of the ??circumglobal?? teleconnection.     

Modeling Forest Emissivity at L-Band and a Comparison With Multitemporal Measurements

This letter describes recent advances in modeling forest emissivity at L-band. The formulation is based on a previously developed discrete model and includes a new representation of forest litter. Comparisons with multitemporal radiometric data collected in the framework of the ldquoBray 2004rdquo experiment, which was carried out within Les Landes forest, are shown and discussed. Input variables are given by using detailed ground measurements. In general, the model reproduces both absolute values and temporal variations of measured brightness temperature. The contribution of the litter to overall emission was found to be important.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

A computer program for interpreting vertical magnetic anomalies of spheres and horizontal cylinders

Summary A common computer program for the interpretation of vertical magnetic anomalies of spheres and horizontal cylinders has been developed. The input consists of the observed anomalies noted against their distances measured from an arbitrary point in the profile and a code number for each model. The program is written so that the positions and magnitudes of the maximum and minimum anomalies are located and their ratios and signs are used to define the initial parameters of the model under consideration. The errors resulting from these approximate values are derived and are solved for the increments to be given to the initial values. The process is repeated until the sum of the squares of the errors is less than 0.25% of the sum of the squares of the observed anomalies. The method has been tested on various theoretical examples and the results justify the validity of the programme.