Position-domain integrity risk-based ambiguity validation for the integer bootstrap estimator

Integrity monitoring for ambiguity resolution is of significance for utilizing the high-precision carrier phase differential positioning for safety–critical navigational applications. The integer bootstrap estimator can provide an analytical probability density function, which enables the precise evaluation of the integrity risk for ambiguity validation. In order to monitor the effect of unknown ambiguity bias on the integer bootstrap estimator, the position-domain integrity risk of the integer bootstrapped baseline is evaluated under the complete failure modes by using the worst-case protection principle. Furthermore, a partial ambiguity resolution method is developed in order to satisfy the predefined integrity risk requirement. Static and kinematic experiments are carried out to test the proposed method by comparing with the traditional ratio test method and the protection level-based method. The static experimental result has shown that the proposed method can achieve a significant global availability improvement by 51% at most. The kinematic result reveals that the proposed method obtains the best balance between the positioning accuracy and the continuity performance.     

改进型经验正交函数海洋声速剖面预报方法

鉴于深海温跃层以下往往声速值缺乏,声速剖面不完整的原因,提出一种声速剖面的预报方法:在传统经验正交函数预报法基础上,首先改进协方差矩阵的求解方法,将原始数据的空间信息和时间信息有效地融合到协方差矩阵中,通过由大量实测数据统计得出的时间函数的经验公式,得到合成剖面,将二者结合,把不完整剖面垂直向下延拓到海底,较为有效地解决了传统方法求解协方差矩阵和时间函数较粗糙的问题,给出了完整的海洋声速剖面的准确预报.实测数据检验结果表明,改进方法的预报精度比传统方法有了很大提高.     

威海近岸人工鱼礁布设对生物资源恢复效果

为了解人工鱼礁投放对区域内海洋生物资源恢复效果,于2013年3月至2014年1月在北黄海近岸人工鱼礁投放区进行调查。结果显示,该海区发现浮游动物53种,其中优势种为浮游桡足类。夏秋季底栖生物幼体成为季节性优势种。游泳动物共发现14种,主要为常见的礁区鱼类。底栖动物共12种,其中棘皮动物海燕为绝对优势种,为近岸养殖生物的主要敌害生物,主要的底栖资源优势种为虾蟹类与软体动物。投礁区的浮游动物与游泳动物物种数明显多于未投礁区,表明人工投礁有助于生物群落的恢复,提高生物多样性,改善区域生态系统。但该海域大型底栖藻类较少,还应进一步对大型底栖藻类增殖以提高海域初级生产。     

储层毛细管压力曲线在东海油气储量计算中的应用

本文阐述了利用储层毛细管压力曲线计算含油炮和度的方法,该方法在东海油气储量计算中取得良好的结果。     

Oil source analysis of Upper Tertiary Shawan Formation in Chepaizi area,in the northwest margin of Junggar basin

Well che89, located in the Chepaizi area in the northwest margin of Junggar basin, acquires high production industrial oil flow, which is an important breakthrough in the exploration of the south foreland slope area of Junggar basin. The Chepaizi area is near two hydrocarbon generation depressions of Sikeshu and Shawan, which have sets of hydrocarbon source rock of Carboniferous to Jurassic as well as Upper Tertiary. Geological and geochemical parameters are proper for the accumulation of mixed source crude oil. Carbon isotope, group composition and biomarkers of crude oil in Upper Tertiary of well Che89 show that the features of crude oil in Upper Tertiary Shawan Formation are between that of Permian and Jurassic, some of them are similar to these two, and some are of difference, they should be the mixed source of Permian and Jurassic. Geochemical analysis and geological study show that sand extract of Lower Tertiary Wulunguhe Formation has the same source as the crude oil and sand extract of Upper Tertiary Shawan Formation, but they are not charged in the same period. Oil/gas of Wulunguhe Formation is charged before Upper Tertiary sedimentation, and suffered serious biodegradation and oxidation and rinsing, which provide a proof in another aspect that the crude oil of Upper Tertiary Shawan Formation of well Che89 is not from hydrocarbon source rock of Lower Tertiary.

     

内蒙古翁公敖包航磁异常的推断与解释

文章对内蒙古四子王旗—土默特右旗中北部近年发现的翁公敖包航磁异常进行推断与解释,在对找矿有望的航磁异常进行筛选后,对翁公敖包航磁异常进行了野外地质-地球物理查证,确定异常为铁矿所致;采用向上延拓、垂向导数、斜导数及小波变换等方法对航磁异常进行数据转换处理,以获取铁矿体的横向及纵向分布信息,取得了较好的效果。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

西部开发过程中土地利用控制的必要性及措施

从西部开发的历史经验与教训、土地利用的不合理现状等方面，阐述国家在实施西部地区大开发战略中加强土地利用控制的必要性及其重要意义。在此基础上，提出土地利用控制的目标与任务。分析了对西部经济发展、自然生态环境建设与保护等密切相关的耕地、林地和草地等在土地利用与控制中存在的问题，进而提出相应的土地利用控制措施与对策。     

民乐、山丹6.1级地震异常及台站实现短临预报的思考

在综合分析了民乐-山丹6.1级地震前张掖中心台范围内震兆异常特征的基础上,总结了本次地震前该台的短临预报过程及存在的问题,对今后台站如何搞好地震短临预报工作进行了探讨.     

遥感技术在地质灾害调查及灾害规律研究中的应用——以辽宁省建昌县为例

地质灾害与地质环境条件、人类工程活动关系密切,严重威胁着人类生命财产安全,制约社会经济的可持续发展。运用遥感技术对辽宁省建昌县进行地质灾害调查,利用ENVI5.3软件对高分二号数据进行预处理,建立遥感解译标志并开展了野外验证,最终解译滑坡、崩塌、泥石流、地面塌陷等地质灾害点75个;同时,利用Arcgis10.4空间分析功能,对遥感解译地质灾害点与地貌、坡度、坡向、构造、水系及人类工程活动等因子进行叠加分析,基本查清了研究区地质灾害规模、空间分布特征和发育规律,为研究总结区域上地质灾规律及有效预防提供了详实可靠的基础资料。