The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Heavy metal pollution in sediments of a typical mariculture zone in South China

The heavy metal inventory and the ecological risk of the estuarine sediments in Hailing Bay, an important maricultural zone along the southern coast of China, were investigated. Results show that the surface sediments were mainly polluted by As (2.17-20.34 mg/kg), Ni (1.37-42.50mg/kg), Cu (1.21-58.84 mg/kg) and Zn (11.69-219.22 mg/kg). Furthermore, the aquafarming zone was significantly more polluted than the non-aquafarming zone, and cluster analysis suggested additional sources of heavy metal input in the aquafarming zone. As, Cr, Cu, Ni, Pb and Zn were mainly present in the non-bioavailable residual form in the surface sediments, whereas Cd was predominantly in the highly mobile acid soluble and reducible fractions. The ecological risk of the polluted sediments stemmed mainly from Cd, and from As, Cu and Pb to less degrees. The highest potential risks occurred near the aquaculture base, indicating the need to control heavy metal inputs from aquafarming activities.     

多源数据融合的城市体检评估

融合遥感影像、社会开放大数据、统计资料等多源数据,以长沙市为例,围绕生态宜居、健康舒适、安全韧性、交通便捷、风貌特色、整洁有序、多元包容、创新活力等8个方面构建城市体检指标体系,运用归一法和层次分析法对城市自然本底和运行体征展开计算评估,结果发现：1）长沙市人居环境整体良好,城市生态宜居和整洁有序度较高,交通便捷和安全韧性建设亟需加强,风貌特色、健康舒适、创新活力、多元包容等仍有改善空间。2）各区县专题发展水平不均,在保留区域功能特色的基础上,应该着重解决发展的短板。3）城市中心城区人口密度、空气质量优良天数、万车死亡率等指标达到最高水平,但在便民服务设施完整覆盖度、住宅建筑更新和开发、群体包容等方面与城市发展需求还有一定差距。根据多源数据城市体检结果可知,长沙市未来需要以问题和需求为导向,精准治理“城市病”,努力提高城市居民生活满意度、幸福感和归属感。     

A linear tessellation model to identify spatial pattern in urban street networks

Street patterns reflect the distribution characteristics of a street network and affect the urban structure and human behavior. The recognition of street patterns has been a topic of interest for decades. In this study, a linear tessellation model is proposed to identify the spatial patterns in street networks. The street segments are broken into consecutive linear units with equal length. We define five focal operations using neighborhood analysis to extract the geometric and topological characteristics of each linear unit for the purpose of grid-pattern recognition. These are then classified by Support Vector Machine, and the result is optimized based on Gestalt principles. The experimental results demonstrate that our method is effective for mining grid patterns in a street network.     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域,为人-地系统耦合研究提供了新的视角,并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵,基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系,运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性,并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年,河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）;（2）河西走廊地区的城市经济脆弱性具有明显的空间特征,经历了东西高、中部低到整体较高的演变过程;（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子,提出针对性优化措施。     

青藏高原东部表层土壤色度的空间变化特征及其环境意义

认识青藏高原东部现代表土的色度特征及其空间分布,理解其与现代气候因子之间的联系,对于高原地区黄土-古环境重建和揭示第四纪环境变化历史具有重要意义。通过对研究区表层土壤色度的详细分析,对比现代气候资料,探讨了青藏高原东部表层土壤色度的空间变化特征及其环境意义。结果表明：① 高原东部表土色度参数空间变化特征差异显著,表现为随纬度升高,土壤亮度呈先减小后增大的趋势,而红度和黄度则逐步减小;随经度的升高,黄度先增大后减小,而红度值逐步减小;红度和黄度整体随着海拔上升而呈先减小后升高的特征。这些变化特征和差异是表土色度对高原东部复杂地理环境和水热条件变化响应的结果。② 在高原的干旱-半湿润区,土壤亮度对降水的响应敏感;红度和黄度对大尺度的温度变化响应较敏感,而较冷的环境下,红度对温度响应复杂,但与降水存在一定的联系。红度/黄度比值主要指示了气候控制下的赤铁矿和针铁矿的变化和竞争,对干旱-半湿润区域的降水变化响应较为敏感。青藏高原东部现代表土色度与气候密切相关,其空间变化特征一定程度上反映了该地区现代气候因子的空间变化;另一方面由于该区地形和气候复杂多变,部分色度指标与气候关系复杂,在重建青藏高原东部黄土古环境变化历史时需要谨慎。     

南极长城站海雾特征分析

本文根据对海雾气象要素场、大气层结和天气形势的分析及其持续时间和季节、年际变化的统计分析,结合个例,讨论了南极长城站海雾的特征和形成机制。认为长城站海雾大多为平流冷却雾,高频率的偏北风和南大洋极锋附近显著的经向海温梯度是长城站多海雾的根本原因;夏半年海雾要多于冬半年,海雾的年际分布差异明显;海雾可出现于0-17m/s的各级风力中,3-11m/s偏北风最有利于海雾的维持;气温为-2-4℃、气-海温差为0-2℃时最易出现海雾;海雾的发生一般伴有稳定的大气层结;"东高西低"是长城站海雾的主要天气形势;海雾的持续时间取决于高压在南极半岛维持时间的长短,平均有10个小时。     

双核型空间结构模式及其在世界地理研究中的应用

作者在我国沿海和沿江地区的空间结构进行深入研究的基础上,发现了一种新的空间结构模式,即双核型空间结构模式。本文在对这一模式进行理论分析的基础上,初步探讨也该模式在世界地理研究中的应用：①指出全球最大的双核结构由全球最大的港口城市鹿特丹和全球最大的内河港口城市杜伊斯堡所组成;②作为推动美国区域经济发展的最重要的一个轴线－“美国经济地理横轴”,是一由芝加哥和纽约组成的双核结构;③新旧首都构成一特殊的双     

塔克拉玛干沙漠腹地大气气溶胶散射特征研究

利用沙漠腹地塔中气象站积分浊度计的2004年观测资料,结合同期PM10质量浓度、能见度和常规气象资料,分析了塔克拉玛干沙漠腹地气溶胶散射系数的变化特征,以及气溶胶散射系数与PM10质量浓度、能见度的关系。研究表明,2004年塔中气溶胶散射系数、PM10质量浓度、能见度日平均值分别为124.74±187.30 Mm-1,538.9±841.7 μg·m-3,12 748±7 274 m。塔中气溶胶散射系数小时平均值出现频率最高的区间主要在100 Mm-1以下,中午气溶胶散射系数小,早晚气溶胶散射系数大;冬春两季的凌晨空气中含有较多的粒子,气溶胶散射系数较大;气溶胶散射系数小时平均值与PM10质量浓度变化规律基本一致,2004年1—6月的气溶胶质量散射系数平均值为0.37 m2·g-1;散射系数与能见度日平均值非线性相关较好,两者呈负幂函数关系。