Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.     

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.     

铁屑微电解法深度处理医院废水

用铁屑微电池原理深度处理了医院废水 ,分析了废水pH、铁屑用量、反应时间对处理效果的影响。结果表明 ,最佳的反应条件为 :废水进水pH为 3.5 ,铁屑用量为 12 .5 % ,常温反应 80min。     

基于交互式分割技术和决策级融合的SAR图像变化检测

为免去去除斑点噪声的预处理操作及克服选择分布模型的限制,本文结合差异图的特点和一种不涉及分布模型的交互式分割方法,产生不同“种子点”下的变化检测结果后,再利用投票策略对其进行决策级的融合给出最终的变化检测结果。分割中,将每个像素的特征设为差异图及由静态小波变换分解差异图再丢弃高频系数后重构得到的各层表示中,其对应位置上的灰度值构成的矢量。此特征及决策级融合的策略使本文的变化检测技术对SAR图像中的斑点噪声具有一定的鲁棒性。在无需对SAR图像做预处理的情况下,对真实SAR图像数据集的变化检测结果,其效果优于其他相关技术的。     

基于感兴趣区域在区域层面上决策的SAR图像变化检测的方法研究

在现有的变化检测方法中,针对差分图像的方法得到了广泛的应用,但现有该框架下的技术都在在像素层面上决策产生的变化检测结果,这易使结果中存在诸如有噪声般散落的杂点、连通区域内有孔洞及边缘不平滑等缺陷。为此,本文给出一种在区域层面上决策生成变化检测结果的技术,其核心为抽取并处理感兴趣区域,而关键在于获取合适的抽取感兴趣区域的标签和如何在区域层面上生成变化检测结果。为使抽取的感兴趣区域包含几乎所有的变化类信息,我们用平稳小波变换和模糊C-均值(Fuzzy C-Means, FCM)算法分两步获取抽取感兴趣区域的标签;为在区域层面上生成变化检测结果,我们依据标签搜索感兴趣区域内所有的连通区域,并把每个连通区域看作为一个数据点,再由阈值技术处理这些数据点生成最终的变化检测结果。对真实SAR图像数据集的变化检测结果表明,其主观效果和客观性能都优于其他相关技术的。     

Episodic crustal growth of North China as revealed by U-Pb age and Hf isotopes of detrital zircons from modern rivers

Clastic sedimentary rocks are samples of the exposed continental crust. In order to characterize the crustal growth history of North China and its possible regional variations, 479 concordant detrital zircons in three sand samples from the lower reach of the Yellow River (which drains the Tibet-Qinghai Plateau, the Western Qinling Orogen, the Qilian Orogen and the North China Craton) and two sand samples from the Luan River and the Yongding River (which run entirely within the North China Craton) were measured for U-Pb age and Lu-Hf isotopic compositions by excimer laser-ablation ICP-MS and MC-ICP-MS. Although regional variations exist, concordant detrital zircons from the Yellow River reveal three major age groups of 2.1-2.5 Ga, 1.6-2.0 Ga, and 150-500 Ma. Detrital zircons from the smaller Luan and Yongding Rivers show three broadly similar major age groups at 2.3-2.6 Ga, 1.6-2.0 Ga, and 140-350 Ma, but with narrower age ranges. Compared to the Luan and Yongding River zircons, the Yellow River zircons are characterized by a significant number of Neoproterozoic grains. Although Hf isotopic compositions show both juvenile crustal growth and crustal reworking for all age groups, much of the crustal growth of North China occurred in the Neoarchean and Mesoproterozoic. All three rivers are characterized by a common prominent group of Hf crust formation model ages at 2.4-2.9 Ga with a peak at 2.7-2.8 Ga. A less significant age group lies between 1.4 and 1.8 Ga for the Yellow River, and between 1.6 and 1.9 Ga for the Yongding River and Luan River. Crustal growth rates based on Hf continental crust formation model ages suggest 45% and 90% of the present crustal volume was formed by 2.5 Ga and 1.0 Ga, respectively, for the drainage area of the Yellow River. In comparison, 60% and 98% of the present crustal volume of the North China Craton was generated by 2.5 Ga and 1.0 Ga, respectively, for the Luan and Yongding Rivers. The 2.7-2.8 Ga age peak observed in all river samples agrees well with the coeval major peak for global crustal growth. However, the other suggested global peaks of crustal growth at 3.4 and 3.8 Ga are insignificant in North China. Taken together with our previous studies of the Yangtze Craton, which show insignificant crustal growth at 2.7-2.8 Ga, we suggest that these advocated worldwide crust formation peaks be re-examined and treated carefully. Our results also show that Phanerozoic zircons may have been derived from crustal sources separated from the mantle up to 2.0 Ga ago before the zircons crystallized, suggesting long-term preservation, reworking and recycling of the continental crust.     

Changes in production potentials of rapeseed in the Yangtze River Basin of China under climate change: A multi-model ensemble approach

Rapeseed is one of the major oil crops in China and it is very sensitive to climate change. The Yangtze River Basin is the main rapeseed production area in China. Therefore, a better understanding of the impact of climate change on rapeseed production in the basin is of both scientific and practical importance to Chinese oil industry and food security. In this study, based on climate data from 5 General Circulation Models (GCMs) with 4 representative concentration pathways (RCPs) in 2011–2040 (2020s), 2041–2070 (2050s) and 2071–2100 (2080s), we assessed the changes in rapeseed production potential between the baseline climatology of 1981–2010 and the future climatology of the 2020s, 2050s, and 2080s, respectively. The key modelling tool – the AEZ model – was updated and validated based on the observation records of 10 representative sites in the basin. Our simulations revealed that: (1) the uncertainty of the impact of climate change on rapeseed production increases with time; (2) in the middle of this century (2050s), total rapeseed production would increase significantly; (3) the average production potential increase in the 2050s for the upper, middle and lower reaches of the Yangtze River Basin is 0.939, 1.639 and 0.339 million tons respectively; (4) areas showing most significant increases in production include southern Shaanxi, central and eastern Hubei, northern Hunan, central Anhui and eastern Jiangsu.     

水力梯度对喀斯特峡谷形成的影响——以猫跳河、六冲河为例

通过对猫跳河和六冲河流域上喀斯特峡谷的研究,发现其分布和形态类型同水力梯度有密切的对应关系。选取能描述喀斯特峡谷形态类型的高宽比作为参量,对其水力梯度进行定量分析,从实践上证明了喀斯特峡谷与水力梯度的关系。然后从水文地貌的角度出发,论证了喀斯特峡谷的形成是适应水流以大水力比降和高效转化能量的结果;水流以最佳通道运行导致了喀斯特峡谷具有地表地下双重结构,水力比降的大小影响河流的下切侵蚀力,大比降有利于喀斯特峡谷的形成      

晋东南山西组主煤层热演化生烃史及热源分析

以晋城矿区山西组主煤层为代表,利用时间-温度指示法、有机质变质程度法、挥发分产率法对该煤层煤化作用历史进行了定量分析,指出其埋藏历史经历了4个发展阶段:(1)P₁-T₃的快速沉降阶段,平均沉降速度达94m/Ma;(2)J₁的逐渐抬升阶段,抬升幅度大于750m;(3)J₂的缓慢沉降阶段,平均沉降速率为10m/Ma;(4)J₃-现代的再次回返阶段。主煤层热演化主要发生在埋藏历史的第1阶段和第4阶段的J₃-K时期,前者为深成变质作用,主要生成湿气且难于保存;后者为异常高热古地温场所致,促使主煤层出现二次生烃作用,为裂解气阶段,主要生成干气,易于保存。最后指出晚中生代异常高温古地温场是由于上地幔顶界面隆起、地壳变薄、岩浆作用加剧、热流值增高所致。而上地幔顶界面的隆起则与幔柱构造中的热幔柱上涌辐射有关。