A study of Mg and K isotopes in Allende CAIs: Implications to the time scale for the multiple heating processes

Abstract— The measurements of magnesium and potassium isotopic compositions of refractory minerals in Allende calcium‐aluminum‐rich inclusions (CAIs), 7R‐19–1, HN3–1, and EGG3 were taken by secondary ion mass spectrometry (SIMS). The 7R‐19–1 contains ¹⁶O‐rich and ¹⁶O‐poor melilite grains and define a single isochron corresponding to an initial ²⁶Al/²⁷Al ratio of (6.6 ± 1.3) × 10^?5. The Al‐Mg isochron, O isotope measurements and petrography of melilite in 7R‐19–1 indicate that ¹⁶O‐poor melilite crystallized within 0.4 Myr after crystallization of ¹⁶O‐rich melilite, suggesting that oxygen isotopic composition of the CAI‐forming region changed from ¹⁶O‐rich to ¹⁶O‐poor within this time interval. The ¹⁶O‐poor melilite is highly depleted in K compared to the adjacent ¹⁶O‐rich melilite, indicating evaporation during remelting of 7R‐19–1. We determined the isochron for ⁴¹Ca‐⁴¹K isotopic systematics in EGG3 pyroxene with (4.1 ± 2.0) × 10^?9 (2s?) as an initial ratio of ⁴¹Ca/⁴⁰Ca, which is at least two times smaller than the previous result (Sahijipal et al. 2000). The ratio of ⁴¹Ca/⁴⁰Ca in the EGG3 pyroxene grain agrees within error with the value obtained by Hutcheon et al. (1984). No evidence for the presence of ⁴¹K excess (decay product of a short‐lived radionuclide ⁴¹Ca) was found in 7R‐19–1 and HN3–1. We infer that the CAI had at least an order of magnitude lower than canonical ⁴¹Ca/⁴⁰Ca ratio at the time of the CAI formation.     

Multifractal and Chaotic Analysis of Vrancea (Romania) Intermediate-depth Earthquakes: Investigation of the Temporal Distribution of Events

The Vrancea seismic region contains an isolated cluster of events beneath the Carpathian Arc Bend in Romania, dipping to about 200 km depth. Seismic activity mainly occurs at intermediate depths (h > 60 km). The main goal of the paper is to perform an in-depth, complex analysis of the occurrence times of these intermediate-depth events. We also try to show the versatility of the methods used to characterize different aspects of the seismicity evolution and to offer a user-friendly software toolbox to do most of the related computations. The earthquake catalog used in this study spans from 1974 to 2002 and includes only the intermediate-depth events. In the first part of the paper, we analyze the multifractal characteristics of the temporal distribution of earthquakes. The study reveals two distinct scaling regimes. At small scales we found a clear nonhomogeneous, multifractal pattern, while at large scales the temporal distribution of events shows a monofractal, and close to Poissonian (random), behavior. The multifractal behavior at small scales (minutes-hours) is shown to be clearly an effect of the short aftershock sequences that occurred after some major Vrancea earthquakes. In the second part of the paper we analyze whether our temporal series shows a persistent (or anti-persistent) long-term behavior, by using the Detrended Fluctuation Analysis (DFA) method. The results suggest that the analyzed temporal series of Vrancea earthquakes is a non-correlated process. In part three of the paper we seek to determine whether the dynamics of our earthquake system (described by the occurrence time of Vrancea earthquakes) is deterministically chaotic, deriving from a rather simple evolution law, or whether it is stochastic and is generated by a system that possesses many degrees of freedom. The results suggest that our signal is stochastic (probably does not possess an attractor). The limited time-span of the catalog and the analysis performed in this paper cannot rule out the emergence of an interesting, quasi-deterministic and low-dimensional structure in the case of major Vrancea earthquakes.Acknowledgement One of the authors (BE) is grateful to the Japanese Ministry of Education for providing him a Monbusho scholarship for studying in DPRI, Kyoto University. We thank Z.R. Struzik, M Holschneider, J. Mori and D. Kaplan for their useful comments, and acknowledge the support of the staff of DPRI, Kyoto University and the National Inst. for Earth Physics, Bucharest. We thank the two reviewers, M.B. Geilikman and M. Anghel, for their useful suggestions which improved the quality of this work.     

Composition of rhodizite

Summary A chemical analysis of rhodizite from Manjaka, Madagascar, establishes the new formula CsAl₄Be₄B₁₁(OH)₄O₂₅. Space group P43m; a₀ 7.317±0.001 Å; density 3.44±0.01 (meas.), 3.47 (calc.); Z=1. The index of refraction, 1.693±0.001 (Na), and the unit cell dimension are identical within the limits state for material from lithia-pegmatites at Manjaka, Antsongombato, Antandrokomby and Ambalalehifotsy, in Madagascar. Hardness 81/2.

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Zusammenfassung Eine chemische Analyse von Rhodizit an Material von Manjaka, Madagaskar, liefert die neue Formel CsAl₄Be₄B₁₁(OH)₄O₂₅. Raumgruppe P43m, a₀=7,317±0,001 Å; Dichte 3,44±0,01 (exp.), 3,47 (ber.); Z=1. Der Brechungsindex, 1,693±0,001 (Na), und die Gitterkonstante sind innerhalb der angegebenen Grenzen für Material von den Lithium-Pegmatiten bei Manjaka, Antsongombato, Antandrokomby und Ambalalehifotsy auf Madagaskar gleich. Härte 81/2.

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Dedicated to ProfessorF. Machatschki on the occasion of his 70th birthday.     

Spin rates of fast-rotating asteroids and fragments in impact disruption

We present a new experimental result of fragment spin-rate in impact disruption, using a thin glass plate. A cylindrical projectile impacts on a side (edge) of the plate. Dispersed fragments are observed using a high-speed camera and the spin rates of fragments are measured. We find that the measured fragment spin-rate decreases with increasing size. Assuming that the rotational energy of fragments is supplied from the residual stress, the spin rate ω decreases with increasing fragment size r as ω∼r−1, which explains the above experimental results. This size-dependence is similar to that of the observed spin rates of small fast-rotating asteroids. Our results suggest that spin rates of fragments of small asteroids immediately after disruption may have a similar size-dependence, and can provide constraints on the subsequent spin-state evolution of small asteroids due to thermal torques.     

The partitioning of Pt-Re-Os between solid and liquid metal in the Fe-Ni-S system at high pressure: Implications for inner core fractionation

Coupled ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os enrichments of plume-derived lavas have been suggested to reflect contributions of materials from the outer core (Brandon et al., 1998). This hypothesis is based on the assumption that the Earth’s liquid outer core has high Pt/Os and slightly high Re/Os ratios as a result of the crystallization of the solid inner core, and shows coupled enrichments in the ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os ratios, reflecting the decay of ¹⁹⁰Pt and ¹⁸⁷Re to ¹⁸⁶Os and ¹⁸⁷Os, respectively. Partitioning experiments of Pt-Re-Os between solid and liquid metal were performed at 5-20 GPa and 1250-1400 °C, to examine the effects of pressure in the Fe-Ni-S system. The ratios (D_Os/D_Pt, D_Os/D_Re) of measured partition coefficients of Pt, Re and Os are almost constant with increasing pressure. D_Os/D_Pt increases significantly, whereas D_Os/D_Re decreases, with increasing sulphur content in the liquid metal. On the basis of the present experimental results, it is unlikely that the required Pt-Re-Os fractionation is generated during inner core crystallization, assuming that the light element in the Earth’s core is sulphur.     

Non-uniform across-shelf variations in thickness, grain size, and frequency of turbidites in a transgressive outer-shelf, the Middle Pleistocene Kakinokidai Formation, Boso Peninsula, Japan

Across-shelf variations in thickness, grain size, and frequency of sandstone beds in a transgressive outer-shelf succession were investigated from the Middle Pleistocene (ca. 0.7 Ma) Kakinokidai Formation on the Boso Peninsula, Japan. The transgressive deposits are generally muddy and contain slumps and slump scars. The intercalated sandstone beds are interpreted to have been formed from turbidity currents as a response to erosion and resuspension of sandridge-complex deposits in the southwestern upslope area during storm events. Mapping of volcanic ash beds and a transgressive surface in the base of the formation permits detailed bed-by-bed correlation of the outer-shelf sandstone beds. Although, overall, thickness, grain size, and frequency of sandstone beds decrease in the downslope direction, some sandstone beds locally thin out and coarsen in association with slump scars in the surrounding muddy deposits. These sandstone beds subsequently thicken and fine, and finally thin out in the farther downslope area. In addition to the local thinning of sandstone beds, the frequency of sandstone beds first decreases and then increases in the farther offshore direction. From this evidence, we concluded that these non-uniform patterns of across-outer-shelf variations in thickness, grain size, and frequency of sandstone beds were caused by the local increases in flow speeds and subsequent expansion and reduced speeds of turbidity currents, along with a local increase in the seafloor gradient that was induced by the development of slump scars in the transgressive outer-shelf floor. These physiographic features in the outer shelf are interpreted not to have permitted monotonous downslope thinning and fining of sandstone beds, compared with the bed-shape models of depletive turbidity currents and with the proximality trend of shelf sandstones from modern and ancient highstand-stage shelf systems.     

Holocene climate reconstructions from tandem trace-element and stable-isotope composition of ostracodes from Coldwater Lake, North Dakota, U.S.A.

The geochemistry of ostracode shells and bulk carbonates in a 19-meter sediment core documents at century-scale resolution the evolution of water chemistry in Coldwater Lake, North Dakota, providing a continuous paleohydrologic record of Holocene climate change in the northern Great Plains. A combination of ¹⁸O, ¹³C, Mg/Ca and Sr/Ca in ostracode calcite aided by Sr/Ca in bulk carbonates are used to constrain the paleoclimatic reconstructions. A fresh-water phase in the early Holocene, indicated by the absence of Candona rawsoni and low concentrations of Sr/Ca in bulk carbonate, was followed by a sharp increase in salinity between 10800 and 8900 yr B.P. The climate was predominately dry during the late part of the early Holocene and most of the middle Holocene (8900–5000 yr B.P.), when the lake was very sensitive and recorded a series of dry and wet oscillations. Maximum salinity occurred around 5500 yr B.P. and was followed by a gradual decrease between 5000 and 2400 yr B.P. From 2400 yr B.P. the ¹⁸O, Mg/Ca, and Sr/Ca in the ostracodes indicate generally wet conditions interrupted by a series of lesser salinity and temperature oscillations lasting until 600 yr B.P. Ostracode geochemistry indicates that a warm and dry climate returned at about the time of the Little Ice Age (600–150 yr B.P.). Ostracode ¹³C shows a ong-term increasing trend during the Holocene, which suggests that lake productivity and atmospheric CO₂ exchange made greater contributions to the hypolimnetic carbon pool as the lake became shallower with time.     

Radionuclides produits par le rayonnement cosmique dans la météorite Saint-Séverin

]The activities of 18 radionuclides in 4 samples from the Saint-Séverin meteorite have been measured after chemical separation. The results show that the DI sample from the D piece has been less irradiated than the samples B₂, B₃ and B₄ from the B piece. This is based on activities of isotopes produced both by spallation as ²⁶Al, ⁵³Mn, ⁵⁴Mn, ⁵⁵Fe, ⁵⁷Co and by thermal neutron capture as ⁵⁹Ni and ⁶⁰Co.Comparison of experimental values to calculated production rates suggests that the D piece was connected to the main body of the meteorite by a small surface, and that the DI sample in this piece was opposite to the main body of the meteorite.     

Distributions of polycyclic aromatic hydrocarbons and alkylated polycyclic aromatic hydrocarbons in Osaka Bay,Japan

Contaminations in sediments by polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs were investigated at 44 sites in Osaka Bay, Japan. Concentrations of total PAHs and alkylated PAHs were in the range 6.40–7800 ng/g dry weights and 13.7–1700 ng/g dry weights, respectively. The PAH concentrations tended to be higher along the shoreline in the vicinities of big ports, industrialized areas, and densely populated regions such as the cities of Osaka and Kobe. The major sources appeared to be pyrogenic or both pyrogenic and petrogenic at most of the sites. PAH concentrations were remarkably high at a site near Kobe, where the concentrations of dibenzo(a,h)anthracene and benzo(g,h,i)perylene exceeded the effects-range-medium concentration and eight PAHs were above the corresponding effects-range-low concentrations. Those PAHs may have been derived from the great fire associated with the large earthquake in 1995.