Sediment community metabolism associated with continental shelf hypoxia, Northern Gulf of Mexico

Net fluxes of respiratory metabolites (O₂, dissolved inorganic carbon (DIC), NH₄ ⁺, NO₃ ^?, and NO₂ ^?) across the sediment-water interface were measured using in-situ benthic incubation chambers in the area of intermittent seasonal hypoxia associated with the Mississippi River plume. Sulfate reduction was measured in sediments incubated with trace levels of³⁵S-labeled sulfate. Heterotrophic remineralization, measured as nutrient regeneration, sediment community oxygen consumption (SOC), sulfate reduction, or DIC production, varied positively as a function of temperature. SOC was inversely related to oxygen concentration of the bottom water. The DIC fluxes were more than 2 times higher than SOC alone, under hypoxic conditions, suggesting that oxygen uptake alone cannot be used to estimate total community remineralization under conditions of low oxygen concentration in the water column. A carbon budget is constructed that compares sources, stocks, transformations, and sinks of carbon in the top meter of sediment. A comparison of remineralization processes within the sediments implicates sulfate reduction as most important, followed by aerobic respiration and denitrification. Bacteria accounted for more than 90% of the total community biomass, compared to the metazoan invertebrates, due presumably to hypoxic stress.     

Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA

An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.     

Gabbro and related rock emplacement beneath rifting continental crust: UPb geochronological and geochemical constraints for the Galicia passive margin (Spain)

The thinned continental crust of the west Galicia margin is bound by a belt of serpentinized peridotites (‘peridotite ridge’) lying about 300 km off the coast in the North Atlantic ocean. From this ridge, a gabbro and a chlorite rock were studied in an attempt to substantiate rift-related subcontinental magmatism, occurring prior to sea-floor spreading. U-Pb dating of 13 different zircon fractions yields a precise age of 122.1 ± 0.3 Ma (2σ) for the emplacement of the chlorite rock protolith, from which more than 50% of Si and alkali-calc-alkali elements were lost during greenschist facies tectonometamorphism. Sr and Nd isotope signatures suggest that the gabbro and chlorite rock protoliths were derived from mantle sources that were moderately depleted in LILE, relative to a chondritic reservoir. No evidence for the presence of continental material in the magma source regions can be observed. From the new zircon age of 122.1 ± 0.3 Ma, and earlier determined³⁹Ar⁴⁰Ar age of 122.0 ± 0.6 Ma for amphibole from the same locality, it can be documented that magma formation, solidification and unroofing of the mantle rocks occurred during a short period of time of about 3.4 Ma, which means that the peridotite ridge detached from the continent and rose to the surface immediately after, or even coevally with mantle melting.     

A distinction between ice-pushed and ice-lifted landforms on lacustrine and marine coasts

Study of a small lake, Second Roach Pond, in Maine, U.S.A. clarifies the distinction between shoreline features created by ice push which occurs on both lacustrine and marine coasts, and those created by ice lift related to tidal action in the marine environment. Ice lifting occurred as littoral sediments were frozen into the lake ice, followed by a rise in water level due to damming of the lake before the nival melt each spring. In the period 1905 to 1969 prominent barricades were constructed by this means. A classification based on this distinction is proposed. Ice-pushed landforms include ramparts, ridges in coarse and fine sediments, stone pavements, ice keel grooves, pushed boulder grooves, and tails off promontories. Ice-lift features include boulder barricades, perched stones, stone garlands, and ice keel depressions.     

Direct dating of Plio-Quaternary pumices by Ar/Ar step-heating and single-grain laser fusion methods: the example of the Monts-Dore massif (Massif Central, France)

K-feldspars separated from Plio-Quaternary pumice flows of the Monts-Dore massif (Massif Central, France) give ⁴⁰Ar/³⁹Ar saddle-shaped age spectra. Laser-probe analysis of hand-picked single grains gives ages in agreement with those of overlying and underlying lava flows previously dated by the conventional K-Ar method. The laser-probe ages are lower than the minimum ages measured on the populations of grains by the step-heating method. As previously suggested by Lo Bello and co-workers for the pumice flow of Neschers belonging to the same volcanic massif, the saddle-shaped age spectra are ascribed to the different Ar-release patterns of two populations of K-feldspars: (1) young sanidine phenocrysts of the pumices; and (2) old K-feldspars plucked from the Hercynian basement during the explosive eruption. Measurements of both the granitic rocks from surrounding areas and the granitic xenoliths included in pumices give ages around 330 Ma and show that most of the xenocrysts included in the pumices did not lose significant amounts of argon during the eruption. With the ⁴⁰Ar/³⁹Ar step-heating method, we were able to detect contamination of Quaternary K-feldspars by Hercynian K-feldspars as low as 0.25. Because pumice flows of the Monts-Dore massif crop out over large areas, these new ages will be useful for establishing a precise stratigraphy of the European Plio-Quaternary.     

Source rock and asphaltene biomarker characterization by pyrolysisgas chromatography-mass spectrometry-multiple ion detection

Biomarkers produced by microscale pyrolysis of extracted source rocks, kerogens and asphaltenes have been analysed directly by gas chromatography-mass spectrometry in the MID mode. A series of experiments have been undertaken. These include an investigation into the production of the hopanes at different pyrolysis temperatures and a comparison of results obtained from Curie point pyrolysis and the Chemical Data Systems pyroprobe. Steranes and triterpanes produced by pyrolysis of a series of vitrinites were investigated and correlated with maturity variations. Finally, the biomarkers produced from asphaltenes were compared with those produced from the extract and extracted rock in order to further investigate the theory that asphaltenes are a liquid kerogen. The results of these experiments showed that the biomarkers released by pyrolysis of source rocks have a potential use for source and maturity determinations. The method is advantageous in that it can be said with some certainty that the biomarkers are indigenous to the rock and not present in the rock as a possible result of migration.     

Portable magnetometer theodolite with fluxgate sensor for earth's magnetic field component measurements

A new portable magnetometer theodolite with fluxgate sensor has been developed for measuring the components of the earth's magnetic field. With this instrument, used as a null detector, it is possible to make absolute measurements of declination (D) and inclination (I). The compensation of the main magnetic field allows direct intensity measurements (H, X, Y, Z components); in this case the calibration is made by reference to a proton magnetometer.The observation procedure is particularly easy and quick. The accuracy is better than 5 sec of arc forD andI and better than 1 nT for direct intensity measurements.