The geochemistry of lead in rivers,estuaries and the continental shelf of the Southeastern United States

Transport by southeastern rivers has insignificant influence on the lead concentration of southeastern shelf waters. If the rate of mobilization and transport of lead by these rivers is representative of uncontaminated fluvial transport during the Pleistocene, only about 5% of the prehistoric output of lead to the North Atlantic can be accounted for by river input.Lead concentrations in southeastern shelf waters are similar to those of North Atlantic Water from the upper 1000 m, which is probably similar to the intrusion source water for the shelf. Atmospheric inputs to the shelf of the same magnitude as observed for the Western North Atlantic are difficult to reconcile given the residence time of shelf waters and their lead concentration unless the rate of loss of lead to shelf sediments is about the same as the atmospheric flux.     

Crustal evolution of the early earth: The role of major impacts

Impact cratering was an important — even dominant — process affecting the crustal evolution of the small terrestrial planets. The fundamental highlands/maria dichotomy of the Moon's surface can be traced to a late heavy bombardment by basin-forming, asteroid-sized bodies which produced not only a topographic division in the lunar crust but also localized the later eruptions of mare basalts. Major impact basins with diameters in excess of 200 km are recognized throughout the inner solar system from Mars to Mercury. Similar craters must have formed on the Earth prior to 4 Ga ago, and the minimum number of such basin-forming impacts can be calculated by scaling from the observed (minimum) number preserved on the Moon. When allowance is made for differences in impact velocity, gravitational cross-section and the effects of gravity on crater diameter, it is found that at least 50% of a presumed global sialic crust would have been converted into impact basins by 4 Ga ago. Among the effects resulting from the impact of an asteroidal object on the early crust were: (a) establishment of a topographic dichotmy of 3–4 km (after isostatic adjustment), (b) pressure-release partial melting of the upper mantle and rapid flooding of the basin floor by basalt, and (c) enhancement of thermal gradients in the sub-basin lithosphere and upper asthenosphere. Comparative planetary data such as impact scaling can be used as important constraints on models of the early terrestrial crust. For example, the topography resulting from impact bombardment produced discrete oceans and dry land by 4 Ga ago, making unreasonable models of a globe-encircling ocean on the Earth after that time.     

Partitioning of Ca and Al between forsterite and silicate melt in dynamic systems with implications for the origin of Ca,Al‐rich forsterites in primitive meteorites

Abstract— We report the results of dynamic crystallization experiments that were specifically designed to study the dependence of Ca and Al partitioning between forsterite and melt in rapidly cooling Caand Al‐rich melts. The partitioning of Ca between olivine and silicate melt is found to be independent of the cooling rate within the range of 1.5 to 1000°C/hr and at CaO contents of up to 25 wt%. Within analytical uncertainty, our data plot on the equilibrium partitioning curve obtained by Libourel (1999). The partitioning behavior of Al at high cooling rates is more complex. Aluminum is much more heterogenously distributed in the olivine and the co‐existing melt than Ca. But, no systematic trend of Al partition coefficient with cooling rate is observed. We apply the results of the experiments to the formation of meteoritic forsterites with relatively high contents of Ca and Al. Although these forsterites are found frequently inside chondrules, the Ca contents of their host chondrules are far too low to crystallize these high Ca‐forsterites. This is also true for very rapid cooling of chondrule melts. The parental melt of these forsterites requires CaO contents above 20 wt%.     

Representation of Uncertainty and Integration of PGIS-based Grazing Intensity Maps Using Evidential Belief Functions

In a project to classify livestock grazing intensity using participatory geographic information systems (PGIS), we encountered the problem of how to synthesize PGIS-based maps of livestock grazing intensity that were prepared separately by local experts. We investigated the utility of evidential belief functions (EBFs) and Dempster's rule of combination to represent classification uncertainty and integrate the PGIS-based grazing intensity maps. These maps were used as individual sets of evidence in the application of EBFs to evaluate the proposition that " This area or pixel belongs to the high, medium, or low grazing intensity class because the local expert(s) says (say) so ". The class-area-weighted averages of EBFs based on each of the PGIS-based maps show that the lowest degree of classification uncertainty is associated with maps in which "vegetation species" was used as the mapping criterion. This criterion, together with local landscape attributes of livestock use may be considered as an appropriate standard measure for grazing intensity. The maps of integrated EBFs of grazing intensity show that classification uncertainty is high when the local experts apply at least two mapping criteria together. This study demonstrates the usefulness of EBFs to represent classification uncertainty and the possibility to use the EBF values in identifying and using criteria for PGIS-based mapping of livestock grazing intensity.     

Solar wind induction in Mercury: Constraints on the formation of a magnetosphere

The discovery of Mercury's magnetosphere by Mariner 10 was surprising since the conventional view of regenerative planetary dynamos had been that the spin requirement would likely have been in excess of the observed spin rate of Mercury. Also internal fluid motions were not expected to be sufficiently large. This paper explores the alternative model of the formation of Mercury's magnetosphere via electromagnetic induction forced by the solar wind. It is shown, however, that the constraints are so severe as to limit severely the applicability of such a model. Although induction is easily observed on the Moon, the modification of the magnetic boundary condition associated with a plasma magnetosphere on Mercury rules out its formation via induction except for interplanetary driving fields which are decreasing in amplitude. That model is explored but retains the difficulty that induced magnetospheres tend to be of small radial and temporal extent compared to that inferred by Ness et al. for Mercury.     

Origin of the Earth's ocean basins

The Earth's original ocean basins are proposed to be mare-type basins produced 4 billion y.a. by the flux of asteroid-sized objects responsible for the lunar mare basins. Scaling upward from the observed number of lunar basins for the greater capture cross-section and impact velocity of the Earth indicates that at least 50% of an original global crust would have been converted to basin topography. These basins were flooded by basaltic liquids in times short compared to the isostatic adjustment time for the basin. The modern crustal dichotomy (60% oceanic, 40% continental crust) was established early in the history of the Earth, making possible the later onset of plate tectonic processes. These later processes have subsequently reworked, in several cycles, principally the oceanic parts of the Earth's crust, changing the configuration of the continents in the process. Ocean basins (and oceans themselves) may be rare occurences on planets in other star systems.     

Holocene sedimentation of a wave-dominated barrierisland shoreline: Cape Lookout, North Carolina

The sedimentary record of 130 km of microtidal (0.9 m tidal range) high wave energy (1.5 m average wave height) barrier island shoreline of the Cape Lookout cuspate foreland has been evaluated through examination of 3136 m of subsurface samples from closely spaced drill holes. Holocene sedimentation and coastal evolution has been a function of five major depositional processes: (1) eustatic sea-level rise and barrier-shoreline transgression; (2) lateral tidal inlet migration and reworking of barrier island deposits; (3) shoreface sedimentation and local barrier progradation; (4) storm washover deposition with infilling of shallow lagoons; and (5) flood-tidal delta sedimentation in back-barrier environments.

Twenty-five radiocarbon dates of subsurface peat and shell material from the Cape Lookout area are the basis for a late Holocene sea-level curve. From 9000 to 4000 B.P. eustatic sea level rose rapidly, resulting in landward migration of both barrier limbs of the cuspate foreland. A decline in the rate of sea-level rise since 4000 B.P. resulted in relative shoreline stabilization and deposition of contrasting coastal sedimentary sequences. The higher energy, storm-dominated northeast barrier limb (Core and Portsmouth Banks) has migrated landward producing a transgressive sequence of coarse-grained, horizontally bedded washover sands overlying burrowed to laminated back-barrier and lagoonal silty sands. Locally, ephemeral tidal inlets have reworked the transgressive barrier sequence depositing fining-upward spit platform and channel-fill sequences of cross-bedded, pebble gravel to fine sand and shell. Shoreface sedimentation along a portion of the lower energy, northwest barrier limb (Bogue Banks) has resulted in shoreline progradation and deposition of a coarsening-up sequence of burrowed to cross-bedded and laminated, fine-grained shoreface and foreshore sands. In contrast, the adjacent barrier island (Shackleford Banks) consists almost totally of inlet-fill sediments deposited by lateral tidal inlet migration. Holocene sediments in the shallow lagoons behind the barriers are 5–8 m thick fining-up sequences of interbedded burrowed, rooted and laminated flood-tidal delta, salt marsh, and washover sands, silts and clays.

While barrier island sequences are generally 10 m in thickness, inlet-fill sequences may be as much as 25 m thick and comprise an average of 35% of the Holocene sedimentary deposits. Tidal inlet-fill, back-barrier (including flood-tidal delta) and shoreface deposits are the most highly preservable facies in the wave-dominated barrier-shoreline setting. In the Cape Lookout cuspate foreland, these three facies account for over 80% of the sedimentary deposits preserved beneath the barriers. Foreshore, spit platform and overwash facies account for the remaining 20%.     

An experimental analysis of spatial competition in a dense infaunal community: The importance of relative effects

A densely populated soft-sediment community was experimentally analysed for interspecific competition for space in laboratory experiments. No interspecific competitive interactions leading to a decrease in survivorship could be documented over a five-week period. The four most abundant species all coexisted in laboratory microcosms. The two tube-buiding species, the tanaid Leptochelia dubia and the polychaete Rhynchospio arenincola, could not exclude the mobile bivalve Transennella tantilla or the burrowing amphipod Paraphoxus spinosus. None of the species increases its emigration frequency when other species are present. Paraphoxus is found to be a browsing predator on Phynchospio but inflicts no detectable mortality. The coexistence of these species is permitted by virtue of the fact that none of the species can alter the soft-sediment habitat sufficiently to make the habitat unsuitable for the other species.     

Cadmium release caused by the die-back of the saltmarsh cord grass Spartina anglica in Poole Harbour (UK)

As in many other areas, the perennial cord grass Spartina anglica C.E. Hubbard has been extremely successful at colonising the English and Irish south coasts, but it is dying back for reasons that are not completely understood. The present study considers the relationship between die-back and metal concentrations in estuarine sediment. No obvious impact of the metal contamination on the S. anglica growth/die-back could be detected in the study zone, Poole Harbour, although the die-back did seem to have substantially influenced the metal concentrations in the sediments of the estuary. Based on core profiles, the remaining patches of S. anglica still retain elevated concentrations and the overall cadmium concentrations in the sediments have risen since 1925. However, considerable quantities of the cadmium stored in the sediment by S. anglica appear to have been washed out rapidly in the die-back zones. Should serious erosion of the saltmarsh occur, triggered for example by sea-level rise, then sudden and high levels of cadmium release may cause harmful effects to marine biota.