Spatially distributed hydrotope‐based modelling of evapotranspiration and runoff in mountainous basins

River basins in mountainous regions are characterized by strong variations in topography, vegetation, soils, climatic conditions and snow cover conditions, and all are strongly related to altitude. The high spatial variation needs to be considered when modelling hydrological processes in such catchments. A complex hydrological model, with a great potential to account for spatial variability, was developed and applied for the hourly simulation of evapotranspiration, soil moisture, water balance and the runoff components for the period 1993 and 1994 in 12 subcatchments of the alpine/pre‐alpine basin of the River Thur (area 1703 km²). The basin is located in the north‐east of the Swiss part of the Rhine Basin and has an elevation range from 350 to 2500 m a.s.l. A considerable part of the Thur Basin is high mountain area, some of it above the tree‐line and a great part of the basin is snow covered during the winter season. In the distributed hydrological model, the 12 sub‐basins of the Thur catchment were spatially subdivided into sub‐areas (hydrologically similar response units—HRUs or hydrotopes) using a GIS. Within the HRUs a hydrologically similar behaviour was assumed. Spatial interpolations of the meteorological input variables wereemployed for each altitudinal zone. The structure of the model components for snow accumulation and melt, interception, soil water storage and uptake by evapotranspiration, runoff generation and flow routing are briefly outlined. The results of the simulated potential evapotranspiration reflect the dominant role of altitudinal change in radiation and albedo of exposure, followed by the influence of slope. The actual evapotranspiration shows, in comparison with the potential evapotranspiration, a greater variability in the lower and medium altitudinal zones and a smaller variability in the upper elevation zones, which was associated with limitations of available moisture in soil and surface depression storages as well as with the evaporative demand of the local vegetation. The higher altitudinal dependency and variability of runoff results from the strong increase in precipitation and the decrease in evaporation with increased altitude. An increasing influence of snow cover on runoff as well as evapotranspiration with altitude is obvious. The computed actual evapotranspiration and runoff were evaluated against the observed values of a weighting lysimeter and against runoff hydrographs. Copyright © 1999 John Wiley & Sons, Ltd.     

New paleomagnetic results from the Aegean extensional province

Various Oligocene formations from NE Greece (ignimbrites from the Medousa area, rhyolites from Zagradenia, granodiorites from Elatia) show discordant paleomagnetic signatures, in each case indicating small cw (clockwise) rotation and also inclination flattening. Marls from Pithion were partly remagnetized in a present-day field. Samples that contain ancient magnetization components also indicate small cw rotation and inclination flattening. However, the magnetization of andesites from Peplos reflects a considerably larger rotation, likely owing to local tectonics. In the context of previous work in the area, these results are used to propose a subdivision of NE Greece into four structural zones of distinctive rotational behaviour (from east to west): sites in zone 1, east of the Kavala-Xanthi-Komotini fault (KXK), show various cw and ccw (counterclockwise) rotation angles owing to complex kinematics resulting from the interaction of the KXK and the north-Anatolian fault zone. However, zone 2, between the KXK and the Strymon valley, is structurally homogeneous ( 10° cw rotation). The paleomagnetic signature of the Vertiskos massif (zone 3) implies a larger (> 30°) cw rotation, whereas sites in the Vardar basin (zone 4) contain a paleomagnetic signature similar to that of zone 2. This suggests a motion of the Vertiscos massif, a meta-ophiolitic nappe, relative to underlying strata. Indeed, zones 2 and 4 may be parts of the same structural unit which underlies this nappe.     

Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden

This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite). Received: 28 October 1996 · Accepted: 24 February 1997     

Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer     

Calibration of paired watersheds: Utility of moving sums in presence of externalities

Historically, paired watershed studies have been used to quantify the hydrological effects of land use and management practices by concurrently monitoring 2 similar watersheds during calibration (pretreatment) and post‐treatment periods. This study characterizes seasonal water table and flow response to rainfall during the calibration period and tests a change detection technique of moving sums of recursive residuals (MOSUM) to select calibration periods for each control–treatment watershed pair when the regression coefficients for daily water table elevation were most stable to minimize regression model uncertainty. The control and treatment watersheds were 1 watershed of 3–4‐year‐old intensely managed loblolly pine (Pinus taeda L.) with natural understory, 1 watershed of 3–4‐year‐old loblolly pine intercropped with switchgrass (Panicum virgatum), 1 watershed of 14–15‐year‐old thinned loblolly pine with natural understory (control), and 1 watershed of switchgrass only. The study period spanned from 2009 to 2012. Silvicultural operational practices during this period acted as external factors, potentially shifting hydrologic calibration relationships between control and treatment watersheds. MOSUM results indicated significant changes in regression parameters due to silvicultural operations and were used to identify stable relationships for water table elevation. None of the calibration relationships developed using this method were significantly different from the classical calibration relationship based on published historical data. We attribute that to the similarity of historical and 2010–2012 leaf area index on control and treatment watersheds as moderated by the emergent vegetation. Although the MOSUM approach does not eliminate the need for true calibration data or replace the classic paired watershed approach, our results show that it may be an effective alternative approach when true data are unavailable, as it minimizes the impacts of external disturbances other than the treatment of interest.     

MELIMEX,an experimental heavy metal pollution study: Particle size distributions in limno-corrals

The particle size distributions in three limno-corrals, located in Baldeggersee, Switzerland, have been determined by means of a Zeiss Micro-Videomat image analyzer as a function of depth and time. The distributions were measured biweekly over a period of 1 year at depths of 0 m, 2.5 m, 5 m, 7.5 m and 10 m (=above bottom). Two of the limno-corrals were charged with heavy metals, whereas the third was uncharged and served as a reference. The shape of the distributions as well as the particle concentrations in the uncharged container did not differ from the ones in the charged limno-corrals. The distributions were found to be self-preserving and independent on heavy metal load, time, depth and particle concentrations. As an average, the dependence of the distributions on the particle diameter was found to be ?1.5 to ?2.5.     

First record of Karydomys (Rodentia, Mammalia) from the German part of the North Alpine Foreland Basin

Karydomys, a rare genus of cricetid rodents from the Middle Miocene of central Europe, had previously been reported only from the Swiss part of the North Alpine Foreland basin; documented evidence from the German part was lacking. This paper describes several new specimens of Karydomys from the German localities Höll and Laimering 3. A correlation of both localities to the Bavarian local biostratigraphic scale OSM F is proposed. Taxonomically, the fossils are most probably linked to K. wigharti from Hambach 6C (north-west Germany), and thus assigned to K. cf. wigharti. In spite of the scarcity of Karydomys fossils in the Upper Freshwatermolasse, the taxon is an important biostratigraphical marker because of its short stratigraphical range.     

Partitioning of Na between olivine and melt: An experimental study with application to the formation of meteoritic Na2O-rich chondrule glass and refractory forsterite grains

We report experimentally determined 1 atm olivine/melt D_Na partitioning data for low f_O2, a variety of melt compositions and a temperature range of 1325-1522 °C. We demonstrated that high-current electron microprobe analyses (EPMA, I = 500 nA, 600 s on the peak) allow quantitative determination of Na₂O in olivine down to ∼10 μg/g. The mean olivine/melt D_Na from 12 experimental runs is 0.0031 ± 0.0007 (1σ). This is the recommended value for low pressures and a wide range of natural compositions.This result is applied to the problem of the origin of alkalis in chondrules and the formation of chondritic refractory forsterite grains. The data on Semarkona (LL3.0) chondrules show that Na₂O is primordial and was present during olivine crystallization. For refractory forsterite grains from Murchison (CM2), we demonstrate that high CaO contents are not a result of equilibration with Na₂O-rich melts, but require high activities of CaO during their formation.