F-OH exchange equilibria between mica-amphibole mineral pairs

Fluoride-hydroxyl exchange equilibria between phlogopite-pargasite and phlogopite-tremolite mineral pairs were experimentally determined at 1,173K, 500 bars and 1,073–1,173 K, 500 bars respectively. The distribution of fluorine between phlogopite and pargasite was found to favor phlogopite slightly, G _ex ^. (1,173 K)=–1.71 kJ anion^–1, while in the case of phlogopite-tremolite, fluorine was preferentially incorporated in the mica, G _ex ^. (1,073)=– 5.67 kJ anion^–1 and G _ex ^. (1,173K)=–5.84 kJ anion^–1. These results have yielded new values of entropy and Gibbs energy of formation for fluortremolite, S _f =–2,293.4±16.0JK^–1 mol^–1 and G _f = –11,779.3±25.0 kJ mol^–1, respectively. In addition, F-OH mineral exchange equilibria support a recent molten oxide calorimetric value for the Gibbs energy of fluorphlogopite, G _f =–6,014.0±7.0 kJ mol^–1, which is approximately 40 kJ mol^–1 more exothermic than the tabulated value.This work performed in part at Sandia National Laboratories supported by the U.S. Department of Energy, DOE, under contract number DE-AC04-76DP00789     

Organochlorine residues in whales landed at Durban,South Africa

The levels of DDT and its metabolites found in the blubber of 29 minke, 6 fin and 1 sei whale landed at the Durban whaling station in 1974 were on average much lower than those found in baleen whales from the North Atlantic, but of the same order as those measured from the Antarctic and North Pacific. In 12 sperm whales examined at Durban the levels of DDT and its metabolites in the blubber were substantially lower than in any other locality so far examined, including the Antarctic, but this may partly reflect the comparative youth of the animals sampled. Low levels of Dieldrin were found in some minke whales only. No PCB could be detected in any of the whales examined.     

Stream-sediment geochemical prospecting for uranium in the paleozoic of the Belgian ardennes

During the years 1979 and 1980, a preliminary program of uranium exploration in the Paleozoic of the Belgian Ardennes was carried out under the sponsorship of the Commission of European Communities. The Laboratory of Mineralogy of the Polytechnic Faculty of Mons was charged with the radiometric section of the program, the Geochemistry Laboratory of the Free University of Brussels with the hydrogeochemical exploration, and the Geochemistry Laboratory of the University of Louvain with the stream sediment exploration. The Geological Survey of Belgium had the responsibility for coordinating the three programs, the statistical and computer treatment of the data, and the compilation of the different maps.Orientation studies at the Geochemistry Laboratory of the University of Louvain showed that a positive geochemical response for uranium could be obtained with bank sampling, which consists of collecting colluvium and alluvium on both sides of the rivers. This necessitates a large sampling density of about one sample per km² (10 205 samples from an area of 11 000 km²).The frequency distribution of the values of uranium follows the lognormal law with a geometric mean of 1.06 ppm and a threshold of 2.36 ppm (P= 0.954). The anomalies (> 3 ppm) fall into three main areas each in a different geological setting: (1) at the periphery of the Cambro-Silurian Massif of Stavelot; (2) within the transition beds between the Visean and Namurian; and (3) in the lower Devonian of the central Ardennes.The first two areas coincide with zones of known radiometric anomalies and of the occurrence of uraniferous minerals.In the third zone, follow-up work has led to the discovery of a uraniferous mineral assemblage consisting of a weathered mass of iron oxide, leucoxene and phosphates.Statistical analyses of the results indicate no significant relationship between U and either organic carbon or Mn, a negative correlation between U and carbonate and pH, and a good positive correlation between U and Cu, V and Fe. The last correlation may indicate an association of U, V, and Cu with iron oxides formed during meteoric alteration.     

Subliquidus glass-glass immiscibility along the albite-diopside join

A calorimetric study has shown that glasses along the albite-diopside join in the system albiteanorthite-diopside have positive enthalpies of mixing. Thermodynamic calculations based on these data describe a nearly symmetric, metastable, subliquidus irascibility gap along the join with a critical temperature at 910 K. The existence of the miscibility gap was tested experimentally by annealing an Ab₅₀Di₅₀ glass at 748 K and 823 K. Annealed glasses were examined by optical microscopy and by scanning and transmission electron microscopy. The glasses showed morphological and chemical features consistent with unmixing of two glass phases. The apparent mechanism of phase separation involves initial spinodal decomposition followed by coarsening to produce 0.1 μm–0.3 μm spherical glass phases.     

Ted Harrison 1930–2007

Associate of the RAS, pioneer in ionospheric incoherent scatter theory and observation, practical manager and leader, not least of EISCAT.     

Structure and evolution of the backstop in the eastern Nankai Trough area (Japan): Implications for the soon-to-come Tokai earthquake

Abstract We present data showing that the intra-oceanic shortening now occurring south of the eastern Nankai Trough that has produced the Zenisu Ridge has also been responsible for the formation of a previous ridge now buried below the continental margin. This ridge, that we refer to as Paleo-Zenisu, is presently adjacent to the backstop and its location coincides with the outer limit of the seismogenic decollement. The subduction of the paleo-Zenisu ridge below the wedge has led to its complete reorganization and has given its identity to the Great Tokai earthquake rupture zone. The formation of paleo-Zenisu and its consequent subduction has induced the tilting of the backstop toward the northwest since ca 2 Ma. This model suggests that the backstop and possibly the wedge are dextrally sheared because they are extruded southwestward in relation to the collision of the Izu-Bonin Ridge with Japan. We use the finite motion from Zenisu to paleo-Zenisu to derive both the subduction vectors along the Nankai Trough and the shortening vectors within Zenisu-Izu. The amount of shortening absorbed within Zenisu-Izu increases toward the northeast. The corresponding subduction vectors of the Zenisu platelet below the wedge decrease accordingly to the northeast from 50 to less than 20 mm/year and the Zenisu body rotates clockwise with a pole near 36° North, 139° East. This might explain the apparent longer repetition time of great earthquakes in the Tokai area. On the other hand, the 25-35 mm/year obtained for the rate of shortening along the Zenisu thrust indicates a high seismic potential there.     

Practical method for drawing a VGP path

A statistical method is proposed for the smoothing of polar wander paths and for giving their confidence limits by the mean of successive ellipses. The method is fully parametrical and is based on the relations between the inertia matrix and the parameters of the Fisher distribution, from which a bivariate form is deduced. An elementary tensorial calculation gives the parameters of the confidence ellipse around a vectorial weighted mean, for any unimodal set of vectors. This model can also be used for other statistical tests, wherever the rotational symmetry hypothesis is not consistent (i.e. the fold test).