Total nitrogen content of deep sea basalts

Various models have been suggested concerning the origin and evolution of the earth's atmosphere. An estimate of the nitrogen content of the mantle could further constrain atmospheric models. Total nitrogen content was determined by thermal neutron activation analysis via ¹⁴N(n,p)¹⁴C. The ¹⁴C was converted to carbon dioxide and counted in miniature low level proportional counters. The total nitrogen content of U.S.G.S. standards BCR-1 and G-2 as determined by different laboratories is variable, probably due to atmospheric adsorption by the finely ground samples. Total nitrogen content was determined in deep sea basalt glasses from three regions: East Pacific Rise ($\text{15 ± 4, 18 ± 4}$, and $\text{7 ±}\text{ppm}\text{2 N}$), Mid-Atlantic Rift (FAMOUS Region:$\text{22 ± 5, 18 ± 3}$, and $\text{10 ± 2}\text{ppm}\text{N}$) and the Juan de Fuca Ridge ($\text{17 ± 4}\text{ppm}\text{N}$). Matrix material from the same samples as the glasses was available from the East Pacific Rise ($\text{37 ± 6, 26 ± 4}$, and $\text{34 ± 6}\text{ppm}\text{N}$) and the Mid-Atlantic Rift ($\text{39 ± 4}\text{ppm}\text{N}$) which are about 50 to 100% greater than the associated glasses. The increased matrix abundance may be due to incorporation of chemically bound nitrogen from sea water rather than dissolved molecular nitrogen. The nitrogen content of the FAMOUS samples are inconsistent with the model of Langmuir et al. (1977) for petrogenesis based on trace element data. Factors which can affect the observed nitrogen content in the basalts and the interpretation in terms of the mantle nitrogen abundance are discussed (e.g. partial melting and degassing of the basalts). A lower limit of about 2 ppm N in the mantle can be estimated.     

Spectra of the earthquake sequence February-March, 1981, in south-central Sweden

On February 13, 1981 a relatively strong earthquake occurred in the Lake Vänern region in south-central Sweden. The shock had a magnitude ofM_L = 3.3 and was followed within three weeks by three aftershocks, with magnitudes 0.5 ≤ M_L ≤ 1.0. The focal mechanism solution of the main shock indicates reverse faulting with a strike in the N-S or NE-SW direction and a nearly horizontal compressional stress. The aftershocks were too small to yield data for a full mechanism solution, but first motions of P-waves, recorded at two stations, are consistent for the aftershocks. Dynamic source parameters, derived from Pg- and Sg-wave spectra, show similar stress drops for the main shock (2 bar) and the aftershocks (1 bar), while the differences in seismic moment (1.5·10²⁰ resp. 4·10¹⁸dyne cm), fault length (0.7 resp. 0.2 km) and relative displacement (0.15 resp. 0.03 cm) are significant.     

A nested rediscretization method to improve pathline resolution by eliminating weak sinks representing wells

This paper discusses a method for overcoming the problem of weak sinks representing wells that result from spatial discretization effects when using MODPATH, the particle-tracking postprocessor for the ground water flow model MODFLOW. Weak sink cells are model cells that represent a well that does not discharge at a sufficiently large rate to capture all of the flow entering the cell; therefore, flowpaths within these cells cannot be uniquely defined because it is impossible to know whether a given water particle discharges to the well or passes through the cell. Creating a submodel of the well cell by using the nested rediscretization method can eliminate this ambiguity by converting the weak sink cell into a strong sink cell. The method is designed to be run manually for each well and for steady-state conditions. Other advantages, disadvantages, technical considerations, and limitations of the method are presented. Software created for the method consists of five Fortran programs that are operated using a set of instructions. A practical application of the method is presented by using an example wellhead-protection problem that demonstrates that nested rediscretization can provide more accurate particle-tracking results than those obtained by using a coarsely discretized model alone.     

Factors Controlling Sulfide Geochemistry in Sub-tropical Estuarine and Bay Sediments

The primary factors that control the concentration of total reduced (inorganic) sulfide in coastal sediments are believed to be the availability of reactive iron, dissolved sulfate and metabolizable organic carbon. We selected nine sites in shallow (<3 m), close to sub-tropical, estuaries and bays along the central Texas coast that represented a range in sediment grain size (a proxy for reactive iron), salinity (a proxy for dissolved sulfate), and total organic carbon (a proxy for metabolizable organic carbon). Based on these parameters a prediction was made of which factor was likely to control total reduced sulfide at each site and what the relative total reduced sulfide concentration was likely to be. To test the prediction, the sediments were analyzed for total reduced sulfide, acid volatile sulfide, and citrate dithionate-extractable, HCl-extractable and total Fe in the solid phase. Using solid-state gold–mercury amalgam microelectrodes and voltammetry, we determined pore water depth profiles of Fe(II) and ΣH₂S and presence or absence of FeS_(aq). At five of the nine sites the calculated degree of sufildization of citrate dithionite-reactive-iron was close to or greater than 1 indicating that rapidly reactive iron was probably the limiting factor for iron sulfide mineral formation. At one site (salinity = 0.9) dissolved Fe(II) was high, ΣH₂S was undetectable and the total reduced sulfide concentration was low indicating sulfate limitation. At the last three sites a low degree of sulfidization and modest total reduced (inorganic) sulfide concentrations appeared to be the result of a limited supply of metabolizable organic carbon. Fe(II)–S(-II) clusters (FeS_(aq)) were undetectable in 10 out of 12 bay sediment profiles where ΣH₂S was close to or below detection limits, but was observed in all other porewater profiles. Acid volatile sulfide, but not total reduced sulfide, was well correlated with total organic carbon and ranged from being undetectable in some cores to representing a major portion of total reduced sulfide in other cores. Although predicted controls on total reduced sulfide were good for very low salinity water or sandy sediments, they were only right about half the time for the other sediments. The likely reasons for the wrong predictions are the poor correlation of total organic carbon with grain size and differing fractions of metabolizable organic carbon in different sedimentary environments. Differences in sediment accumulation rates may also play a role, but these are difficult to determine in this region where hurricanes often resuspend and move sediments. This study demonstrates the need to examine more complex and often difficult to determine parameters in anoxic “normal marine” sediments if we are to understand what controls the concentration and distribution of sulfides.     

Application of GIS Processing Techniques for Producing Mineral Prospectivity Maps—A Case Study: Mesothermal Au in the Swayze Greenstone Belt,Ontario, Canada

A Geographic Information System (GIS) is used to prepare and process digital geoscience data in a variety of ways for producing gold prospectivity maps of the Swayze greenstone belt, Ontario, Canada. Data used to produce these maps include geologic, geochemical, geophysical, and remotely sensed (Landsat). A number of modeling methods are used and are grouped into data-driven (weights of evidence, logistic regression) and knowledge-driven (index and Boolean overlay) methods. The weights of evidence (WofE) technique compares the spatial association of known gold prospects with various indicators (evidence maps) of gold mineralization, to derive a set of weights used to produce the final gold prospectivity map. Logistic regression derives statistical information from evidence maps over each known gold prospect and the coefficients derived from regression analysis are used to weight each evidence map. The gold prospectivity map produced from the index overlay process uses a weighting scheme that is derived from input by the geologist, whereas the Boolean method uses equally weighted binary evidence maps.The resultant gold prospectivity maps are somewhat different in this study as the data comprising the evidence maps were processed purposely differently for each modeling method. Several areas of high gold potential, some of which are coincident with known gold prospects, are evident on the gold prospectivity maps produced using all modeling methods. The majority of these occur in mafic rocks within high strain zones, which is typical of many Archean greenstone belts.     

Hailstorm Risk Assessment in Rural New South Wales

The risk of hail damage at a particular location depends on the frequency and severity (intensity) of hailfall. Three data sets were used to determine the relative risk of hail damage in the various weather forecasting districts of the state of New South Wales, Australia. Two of the data sets were observational data and the third was a set of crop insurance data. The crop insurance data was the least spatially-biased data available for rural areas. Combined data revealed that hailstorms were most frequent in the tablelands and most severe in the north of the state where there is summer-dominant rainfall.     

Triggered earthquakes and deep well activities

Earthquakes can be triggered by any significant perturbation of the hydrologic regime. In areas where potentially active faults are already close to failure, the increased pore pressure resulting from fluid injection, or, alternatively, the massive extraction of fluid or gas, can induce sufficient stress and/or strain changes that, with time, can lead to sudden catastrophic failure in a major earthquake. Injection-induced earthquakes typically result from the reduction in frictional strength along preexisting, nearby faults caused by the increased formation fluid pressure. Earthquakes associated with production appear to respond to more complex mechanisms of subsidence, crustal unloading, and poroelastic changes in response to applied strains induced by the massive withdrawal of subsurface material. As each of these different types of triggered events can occur up to several years after well activities have begun (or even several years after all well activities have stopped), this suggests that the actual triggering process may be a very complex combination of effects, particularly if both fluid extraction and injection have taken place locally. To date, more than thirty cases of earthquakes triggered by well activities can be documented throughout the United States and Canada. Based on these case histories, it is evident that, owing to preexisting stress conditions in the upper crust, certain areas tend to have higher probabilities of exhibiting such induced seismicity.