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91.
Sumaira Khan Tasneem G. Kazi Muhammad B. Arain Nida F. Kolachi Jameel A. Baig Hassan I. Afridi Abdul Q. Shah 《洁净——土壤、空气、水》2013,41(8):808-815
Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH3COOH has good correlation with aluminum content in corresponding water samples of each ecosystem. 相似文献
92.
Mohamed M. Abu-Zeid Ashraf R. Baghdady Hassan A. El-Etr 《Journal of Arid Environments》2001,48(4):475
Sand dunes and interdune sediments around Al Ain city have markedly high carbonate contents which increase towards Jabal Hafit mountain and the Arabian Gulf coast. The dunes are composed predominantly of well-sorted fine sands, consisting of unstrained quartz and carbonate grains together with minor proportions of chert and feldspars. Scanning electron microscope (SEM) examination reveals that quartz grains display various mechanically- and chemically-formed surface textures. The heavy minerals are dominated by opaques and pyroxenes with minor tourmaline, garnet, rutile, epidote, monazite, zircon, hornblende and staurolite.Interdune sediments consist of fine and very fine, poorly- to extremely poorly-sorted sands together with small concentrations of gravel, silt and clay. The light sand fractions compositionally resemble those of dunes but contain, in addition, gypsum, anhydrite, halite and celestite. Percentages of pyroxenes are higher whereas those of zircon, tourmaline and rutile are lower than in dunes. X-ray diffractometry reveals that the clay fractions consist solely of palygorskite. Generally, interdune sediments are much less mature texturally and mineralogically than dune sands; the maturity of both types of sediments decreases toward the NE of the study area.Sand dunes in the various districts of the greater Al Ain area are genetically related. Also, there is a partial genetic relationship between the dunes and interdune sediments; both are mainly multicyclic. Their major parts were brought mainly by the dominant north-west (El Shamal) winds from older dune fields in other localities in U.A.E., Qatar and El-Rub El-Khali. Local contributions to the dune fields from Jabal Hafit mountain, the Oman Mountains and the calcareous coast of the Arabian Gulf were, in cases, significant. Also, authigenesis by groundwater under highly evaporitic conditions played a major role in the formation of interdune sediments through the genesis of the clay and some nonclay minerals. 相似文献
93.
Amirhossein Gheitanchi Mashini Mona Fard Yazdani Pargol Ghavam Mostafavi Mohammad Hassan Shahhosseiny 《Marine Ecology》2017,38(2)
The genus Symbiodinium plays an essential role in the resistance and survival of reef‐building corals during temperature anomalies. Coral colonies inhabiting the Persian Gulf (PG) experience extended periods of different stresses. Kish Island is located in the harsh environment of the Northern PG with previously reported bleaching episodes. Samples of six coral species from Northwestern Kish Island were analysed by internal transcribed spacer 2 of ribosomal DNA to identify in hospite Symbiodinium populations. The results showed that lineage D of Symbiodinium was the most prevalent clade among different coral colonies, while clade C was only detected in symbiosis with a single coral species. However, the detected Symbiodinium subclades belonged to two host generalists. The predominance of the stress tolerant Symbiodinium trenchii and subclade C3 could suggest an acclimatization strategy to cope with the hostile environment of the PG. 相似文献
94.
Fatemeh Pourjomeh Mohammad Reza Shokri Hamid Rezai Hassan Rajabi‐Maham Elham Maghsoudlou 《Marine Ecology》2017,38(6)
Processes underlying the temporal and spatial variations observed in the distribution of jellyfish and non‐gelatinous zooplankton in the Gulf of Oman are not well understood. This information gap is clearly a major issue in controlling the harmful blooms of jellyfish and non‐gelatinous zooplankton. Samples of jellyfish and non‐gelatinous zooplankton were collected from six stations in Chabahar Bay and three stations in Pozm Bay within four seasons. At each station, environmental variables were also recorded from bottom and surface water. A total of 83 individuals of medusae representing four species of Scyphozoa (i.e., Cyanea nozakii, Chrysaora sp., Pelagia noctiluca, Catostylus tagi) and species of Hydrozoa (i.e., Diphyes sp., Rhacostoma sp., Aequorea spp.) were observed in the study area. A total of 70,727.25 individuals/m?3 of non‐gelatinous zooplankton dominated by copepods and cladocerans were collected in nine stations within the four seasons. The results of a RELATE analysis yielded no significant association between species composition for jellyfish and non‐gelatinous zooplankton. Among environmental variables, water transparency, nitrite concentration, water depth and temperature were better associated with the total variation in jellyfish species composition than with that of non‐gelatinous zooplankton. Dissolved oxygen, pH, and phosphate concentration were significant environmental variables associated with the variation in the spatial and temporal distribution patterns of non‐gelatinous zooplankton assemblages. Although some jellyfish species (i.e., Rhacostoma sp., Pelagia noctiluca, Catostylus tagi) occur independently of non‐gelatinous zooplankton assemblages, other jellyfish (i.e., Chrysaora sp., Aequorea spp., Cyanea nozakii, Diphyes sp.) are strongly correlated with non‐gelatinous zooplankton assemblages. 相似文献
95.
Gravel road surfaces can be a major source of fine sediment to streams, yet their contribution to channel reach sediment balances remains poorly documented. To quantify the input of road surface material and to compare this input with natural sediment sources at the reach scale, suspended sediment dynamics was examined and a 16‐month sediment balance was developed for a ~35 channel‐width (approx. 425 m) reach of the Honna River, a medium‐size, road‐affected stream located in coastal British Columbia. Of the 105 ± 33 t of suspended material passing through the reach, 18 ± 6% was attributed to the road surface. The high availability of sediment on the road surface appears to limit hysteresis in road run‐off. During rainstorms that increase streamflow, road surface material composed 0.5–15% of sediment inputs during relatively dry conditions from April to the end of September and 5–70% through wetter conditions from October to the end of March, but our data do not show evidence of major sediment accumulation on the riverbed in the reach. A comparison of modelled sediment production on the road surface with observed yields from drainage channels suggests that (1) during low intensity rainfall, ditches and drainage channels may trap sediment from road run‐off, which is subsequently released during events of greater intensity, and/or (2) production models do not effectively describe processes, such as deposition or erosion of sediment in ditches, which control sediment transport and delivery. Our findings further emphasize the risk of unpaved roads in polluting river systems and highlight the continued need for careful road design and location away from sensitive aquatic environments. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
96.
Basem Zoheir Richard Goldfarb Astrid Holzheid Hassan Helmy Ahmed El Sheikh 《地学前缘(英文版)》2020,11(1):325-345
The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures. 相似文献
97.
The Tafresh granitoids are located at the central part of the Urumieh-Dokhtar Magmatic Arc(UDMA) in Iran. These rocks, mainly consisting of diorite and granodiorite, were emplaced during the Early Miocene. They are composed of varying proportions of plagioclase + K-feldspar + hornblende ± quartz ± biotite. Discrimination diagrams and chemical indices of amphibole phases reveal a calc-alkaline affinity and fall clearly in the crust-mantle mixed source field. The estimated pressure, derived from Al in amphibole barometry, is approximately 3 Kb. The granitoids are I-type, metaluminous and belong to the calc-alkaline series. They are all enriched in light rare earth elements and large ion lithophile elements, depleted in high field strength elements and display geochemical features typical of subduction-related calc-alkaline arc magmas. Most crystal size distribution(CSD) line patterns from the granitoids show a non-straight trend which points to the effect of physical processes during petrogenesis.The presence of numerous mafic enclaves, sieve texture and oscillatory zoning along with the CSD results show that magma mixing in the magma chamber had an important role in the petrogenesis of Tafresh granitoids. Moreover, the CSD analysis suggests that the plagioclase crystals were crystallized in a time span of less than 1000 years, which is indicative of shallow depth magma crystallization. 相似文献
98.
Galih Yudha Kuswandaru Meor H. Amir Hassan Liviu C. Matenco Nur I. Taib Khairul A. Mustapha 《Geological Journal》2019,54(6):3421-3437
Turbiditic flysch units of the Rajang Group form a large crescentic belt of deformed strata in central Borneo. Unfortunately, our understanding of its bed type characteristics and depositional setting is very poor. Here, we present a detailed bed type analysis of the Palaeocene to middle Eocene Kapit and Pelagus members of the Belaga Formation, based on detailed investigations of recent road‐cut exposures around Sibu, Sarawak, Malaysia. Five bed types are identified from the studied sections, representing deposition from turbidity currents, debris flows, and flows that show turbulent and laminar characteristics. The Belaga Formation deposits are divided into four bed type associations based on bed type assemblages, bed geometry, degree of bed amalgamation, vertical grain size, and bed thickness trends, for example, lobe axis, lobe off‐axis, lobe fringe, and slump. Hybrid event beds (HEBs) are not restricted only to the lobe fringe but are also a common element of the lobe axis sub‐environment in the Belaga Formation system. Their common occurrence in a proximal location in the lobes is probably due to enhanced seafloor erosion and rapid deceleration due to loss of confinement at the channel lobe transition further up‐dip. Evidence such as bidirectional ripple cross‐lamination in thin‐bedded turbidites and variable palaeocurrent orientations suggest a complex depositional topography, which also suppressed flow turbulence and promoted deposition of hybrid event beds in proximal locations through deflection and deceleration of incoming flows by confining counter slopes. Similar bed type assemblages within the slump and lobe deposits indicate a local origin for the slumps. Localized failures can form on low gradient slopes developed in tectonically active basins with complex topography. 相似文献
99.
Houda El Kerni Hasnaa Chennaoui Aoudjehane David Baratoux Mohammed Aoudjehane Andr Charrire Hassan Ibouh Pierre Rochette Yoann Quesnel Minoru Uehara Thomas Kenkmann Gerwin Wulf Michael Poelchau Van Binh Nguyen Maria Aboulahris Samira Makhoukhi Georges Aumaître Didier Bourls Karim Keddadouche 《Meteoritics & planetary science》2019,54(10):2483-2509
Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km2) and 1:15,000 (2.25 km2) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (36Cl) constrain the local erosion rates between 220 ± 22 m Ma?1 and 430 ± 43 m Ma?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data. 相似文献
100.
An astronomical observatory is the core component of any astronomical research facility that connects astronomers with their lab: the Cosmos. The research quality of an astronomical facility is rooted in the precision of data, collected by its observatory. For optimal performance, an observatory is sited while considering certain astronomical, environmental, geological and social parameters. This study aims to identify the potential sites in Pakistan for locating an optical-astronomical observatory using the Multicriteria Decision Analysis(MCDA) technique. The study uses the Analytic Hierarchy Process(AHP) for deriving the influence weights of nine evaluation criteria: Photometric Night Fraction; Night-time Sky Brightness;Sky Transparency; Aerosol Concentration; Altitude; Terrain Slope; Accessibility; Seismic Vulnerability;and Landuse/Land Cover. On the basis of experts' opinions and previous studies, the evaluation criteria have been ordered in two possible preference sequences for identifying their influence weights with respect to each other for taking part in MCDA. Consequently, the process of MCDA identified certain areas with respect to each preference sequence, whereas some areas were found to be suitable according to both preference sequences. The study synchronizes the required eclectic data into an evaluation matrix that augments the process of astronomical site selection. In the future, this study will be useful for astronomical societies and for furthering astronomical research in the country. 相似文献