Partitioning of heavy metals on soil samples from column tests

In this study, column tests were used to determine the retention capability of three types of estuarine alluvia collected adjacent to landfill sites in South Wales. Selective sequential extraction (SSE) was used to study the retention mechanisms of heavy metals in the soil columns obtained from leaching experiments. Acid digestion was later used to check the validity of the SSE results. Breakthrough curves show good retention of heavy metal ions (Pb, Cu, and Zn) by all soils, where almost 99% of heavy metals were retained with the C_e/C_o values in the order of 10⁻³. The retention strength of these soils was observed to be constant up to five pore volumes (PV). This corresponds with the pH of the effluents and pore water of soil slices, which also show good buffering capacity against very acidic leachate up to 5PV. The heavy metal extraction profiles from SSE show very similar trends with the retention profiles from the leaching experiments, where heavy metals were retained mainly at the top part where the leachate entered the column. SSE indicates qualitatively that heavy metals precipitated with carbonates and amorphous materials (oxides/hydroxides) are higher than heavy metal retention via exchangeable mechanisms. The mass balance calculation gives range of deviation of 1–16% of the total soil extraction. The distribution of the heavy metals with various soil constituents are ranked in the following order: Carbonates>Amorphous oxides hydroxides>Organic matter>Exchangeable phases.     

Environmental management in Antarctica Instruments and institutions

Instruments and institutions for environmental management in Antarctica have evolved from beginnings in the Antarctic Treaty, with subsequent introduction of the Convention for the Conservation of Antarctic Seals, the Convention on the Conservation of Antarctic Marine Living Resources, and recommendations made at Treaty meetings. The Protocol on Environmental Protection to the Antarctic Treaty will improve existing provisions for environmental management in Antarctica. When it enters into force the Protocol will apply to all activities in the Treaty area: it provides rules for environmental impact assessment, conservation of fauna and flora, disposal of wastes, prevention of marine pollution and specially protected and managed areas. The Protocol's Committee for Environmental Protection will facilitate discussion and advice on environmental management. Management of information is a vital part of ensuring measures are effective. The Protocol should be ratified quickly to improve the basis for environmental protection, but the test will be whether and how it is implemented in practice.     

Estimation of exploration potential of a metallogenic unit by parametric modeling of the distribution of mineral occurrences when exploration is incomplete. Case study: Walker Lake quadrangle of Nevada and California

Analysis of the distribution of ore-bodies in space can be useful generally in the estimation of mineral resources or the management of exploration. This study is directed to analysis of the undiscovered potential of well known areas of mining district size, referred to as metallogenic units (MUs). The analysis employs an effort-adjusted and truncated probability model for number of occurrences within a subdivision (quadrat) of a MU and Monte Carlo sampling to generate an approximation to the probability distribution for number of occurrences and number of mines within an MU when it is totally explored. Exploration potential for Monitor, Bodie, Aurora, and Camp Douglas MUs (Walker Lake quadrangle of Nevada and California) are estimated to be 9, 4, 7, and 4 mines, respectively.     

Volumetric characteristics of lava flows from interferometric radar and multispectral satellite data: the 1995 Fernandina and 1998 Cerro Azul eruptions in the western Galápagos

We have used a suite of remotely sensed data, numerical lava flow modeling, and field observations to determine quantitative characteristics of the 1995 Fernandina and 1998 Cerro Azul eruptions in the western Galápagos Islands. Flank lava flow areas, volumes, instantaneous effusion rates, and average effusion rates were all determined for these two eruptions, for which only limited syn-eruptive field observations are available. Using data from SPOT, TOPSAR, ERS-1, and ERS-2, we determined that the 1995 Fernandina flow covers a subaerial area of 6.5×10⁶ m² and has a subaerial dense rock equivalent (DRE) volume of 42×10⁶ m³. Field observations, ATSR satellite data, and the FLOWGO numerical model allow us to determine that the effusion rate declined exponentially from a high of ~60–200 m³ s^-1 during the first few hours to <5 m³ s^-1 prior to ceasing after 73 days, with a mean effusion rate of 4–16 m³ s^-1. Integrating the ATSR-derived, exponentially declining effusion rate over the eruption duration produces a total (subaerial + submarine) DRE volume of between 27 and 100×10⁶ m³, the range in values being due to differing assumptions about heat loss characteristics; only values in the higher part of this range are consistent with the independently derived subaerial volume. Using SPOT, TOPSAR, ERS-1, and ERS-2 data, we determine that the 1998 Cerro Azul flow is 16 km long, covers 16 km², and has a DRE volume of 54×10⁶ m³. FLOWGO produces at-vent velocity and effusion rate values of 11 m s^-1 and ~600 m³ s^-1, respectively. The velocity value agrees well with the 12 m s^-1 estimated in the field. The mean effusion rate (total DRE volume/duration) was 7–47 m³ s^-1. Dike dimensions, fissure lengths, and pressure gradients along the conduit based on magma chamber depth estimates of 3–5 km produce mean effusion rates for the two eruptions that range over nearly four orders of magnitude, the range being due to uncertainty in the magma viscosity, dike dimensions, and pressure gradient between magma chamber and vent. Although somewhat consistent with mean effusion rates from other techniques, their wide range makes them less useful. The exponentially declining effusion rates during both eruptions are consistent with release of elastic strain being the driving mechanism of the eruptions. Our results provide independent input parameters for previously published theoretical relationships between magma chamber pressurization and eruption rates that constrain chamber volumes and increases in volume prior to eruption, as well as time constants of exponential decay during the eruption. The results and theoretical relationships combine to indicate that at both volcanoes probably 25–30% of the volumetric increase in the magma chamber erupted as lava onto the surface. In both eruptions the lava flow volumes are less than 1% of the magma chamber volume.     

Diamond formation and source carbonation: mineral associations in diamonds from Namibia

Mineral inclusions in diamonds from Namibia document a range of mantle sources, including eclogitic, websteritic and peridotitic parageneses. Based on unusual textural features a group of inclusions showing websteritic, peridotitic and transitional chemical features is assigned to an 'undetermined suite' (12% of the studied diamonds). The mutual characteristic of this group is the occurrence of lamellar intergrowths of clinopyroxene and orthopyroxene. In addition, the 'undetermined suite' is associated with a number of uncommon phases: in one diamond MgCO₃ is enclosed by clinopyroxene. Other minerals that form touching inclusions with the pyroxene lamellae are (1) a SiO₂ phase observed in three diamonds, together with CaCO₃ in one of them, (2) phlogopite and a Cr-rich 'titanate' (probably lindsleyite). The inclusions document a metamorphic path of decreasing pressures and temperatures after entrapment in diamond. First, homogeneous low-Ca clinopyroxenes were entrapped at high temperatures. They subsequently exsolved orthopyroxene and probably also SiO₂ (coesite) on cooling along a P,T trajectory that did not allow garnet to be exsolved as well. Phlogopite, carbonates and LIMA phases are the result of overprint of a peridotitic source rock by a carbon-rich agent. The resulting unusual, olivine-free mineral association and the host diamonds are interpreted as products of extensive carbonation of the peridotite.     

The Near-Earth Asteroid Size-Frequency Distribution: A Snapshot of the Lunar Impactor Size-Frequency Distribution

It is shown that the size-frequency distribution (SFD) of a time-averaged projectile population derived from the lunar crater SFD of Neukum and Ivanov (in Hazards Due to Comets and Asteroids (T. Gehrels, Ed.), 1994, pp. 359-416, Univ. of Arizona Press, Tucson) provides a convincing fit to the SFD of the current near-Earth asteroid (NEA) population, as deduced from the results of asteroid search programs. Our results suggest that the shape of the SFD of the impactor flux has remained in a steady state since the late heavy bombardment, so that the current NEA population can be viewed as a snapshot of the flux of impactors on the Moon. The number of bodies in the projectile population with diameters of 1 km or more is 700±130, which is in good agreement with recent estimates of the total number of NEAs in this size range. Our results imply that the contribution to the projectile flux from comets is small for diameters below 10 km.     

The dynamics of a channel-fed lava flow on Pico Partido volcano, Lanzarote

A short length of channel on Pico Partido volcano, Lanzarote, provides us the opportunity to examine the dynamics of lava flowing in a channel that extends over a sudden break in slope. The 1–2-m-wide, 0.5–2-m-deep channel was built during the 1730–1736 eruptions on Lanzarote and exhibits a sinuous, well-formed channel over a steep (11° slope) 100-m-long proximal section. Over-flow units comprising smooth pahoehoe sheet flow, as well as evidence on the inner channel walls for multiple (at least 11) flow levels, attest to unsteady flow in the channel. In addition, superelevation is apparent at each of the six bends along the proximal channel section. Superelevation results from banking of the lava as it moves around the bend thus causing preferential construction of the outer bank. As a result, the channel profile at each bend is asymmetric with an outer bank that is higher than the inner bank. Analysis of superelevation indicates flow velocities of ~8 m s^–1. Our analysis of the superelevation features is based on an inertia-gravity balance, which we show is appropriate, even though the down-channel flow is in laminar flow. We use a viscosity-gravity balance model, together with the velocities calculated from superelevation, to obtain viscosities in the range 25–60 Pa s (assuming that the lava behaved as a Newtonian liquid). Estimated volume fluxes are in the range 7–12 m³ s^–1. An apparent down-flow increase in derived volume flux may have resulted from variable supply or bulking up of the flow due to vesiculation. Where the channel moves over a sharp break in slope and onto slopes of ~6°, the channel becomes less well defined and widens considerably. At the break of slope, an elongate ridge extends across the channel. We speculate that this ridge was formed as a result of a reduction in velocity immediately below the break of slope to allow deposition of entrained material or accretion of lava to the channel bed as a result of a change in flow regime or depth.     

Synergy of multiple geophysical approaches to unravel explosive eruption conduit and source dynamics - A case study from Stromboli

An effective approach to understanding the dynamics of explosive volcanic eruptions and the conduit systems that drive them is through synergy of multiple data sets. Three data sets that lend themselves to ease of integration are seismic, infrasonic and thermal. Although approaches involving these data have been used to record volcanological phenomena since 1862, 1955 and 1965, respectively, their integrated use has only developed since 1999. When combined, these three data sets allow constraint of shallow system geometry and the dynamics of the explosive events that occur within that system. Using Stromboli volcano (Italy) as a case study, we review the complete range of geochemical and geophysical studies that can be applied. In doing so, we aim to show how integration of these diverse studies allows insights into a plumbing system and the dynamics of the eruptive activity that the system feeds. When combined at Stromboli, these data provide constraint of multiple system parameters including chamber depths, gas and magma fluxes, shallow system magma residence times, explosion source depths, and the rise/ejection velocities of ascending gas slugs and ejecta. In turn, these results allow various conduit and eruption dynamic models to be applied and tested.The persistent and repeated mildly explosive events that characterize Stromboli have been modeled in terms of the coalescence of gas within the magma to form large gas slugs that ascend the remaining portion of the conduit to burst at the free surface. Our integrated seismic, infrasonic and thermal data sets indicate that gas coalescence occurs at a depth of ∼260 m, with a typical event frequency of ∼9/h. Infrasonic and thermal data show the explosion source to be located 20-220 m below the vent. Thermal data give emission velocities for the ejected fragments of 8-20 m/s, which converts to gas jet velocities of 23-39 m/s. Tracking these parameters in space and time shows that, although eruptions at Stromboli can be grouped into two characteristic types (simple and complex-each of which characterizes a particular crater, NE and SW, respectively), events within each type show significant short-term variability. The system does, however, appear robust, maintaining its characteristic strombolian eruption style after significant effusive phases and more energetic explosive events.