Across the Arctic front west of Spitsbergen: high-resolution CTD sections from 1998-2000

The structure of the oceanic Arctic front west of Spitsbergen is investigated using data from high-resolution CTD sections from September 1998-2000. Below the fresher surface layer, the front appears as a temperature-salinity front situated near the shelf break. No clear corresponding front in density is found. Our analysis suggests that barotropic front instability is a main factor in provoking subsurface cross-front exchange. The subsurface heat loss in the West Spitsbergen Current due to this exchange is estimated to be of the same order of magnitude as the heat loss to the atmosphere in the surface layer.     

Tree Species Composition in European Pristine Forests: Comparison of Stand Data to Model Predictions

The degree of general applicability across Europe currently achieved with several forest succession models is assessed, data needs and steps for further model development are identified and the role physiology based models can play in this process is evaluated. To this end, six forest succession models (DISCFORM, ForClim, FORSKA-M, GUESS, PICUS v1.2, SIERRA) are applied to simulate stand structure and species composition at 5 European pristine forest sites in different climatic regions. The models are initialized with site-specific soil information and driven with climate data from nearby weather stations. Predicted species composition and stand structure are compared to inventory data. Similarity and dissimilarity in the model results under current climatic conditions as well as the predicted responses to six climate change scenarios are discussed. All models produce good results in the prediction of the right tree functional types. In about half the cases, the dominating species are predicted correctly under the current climate. Where deviations occur, they often represent a shift of the species spectrum towards more drought tolerant species. Results for climate change scenarios indicate temperature driven changes in the alpine elevational vegetation belts at humid sites and a high sensitivity of forest composition and biomass of boreal and temperate deciduous forests to changes in precipitation as mediated by summer drought. Restricted generality of the models is found insofar as models originally developed for alpine conditions clearly perform better at alpine sites than at boreal sites, and vice versa. We conclude that both the models and the input data need to be improved before the models can be used for a robust evaluation of forest dynamics under climate change scenarios across Europe. Recommendations for model improvements, further model testing and the use of physiology based succession models are made.     

Coastal eutrophication and the Danish national aquatic monitoring and assessment program

Nutrient over-enrichment and cultural eutrophication are significant problems in the Danish marine environment. Symptoms of eutrophication include periods of hypoxia and anoxia in bottom waters, death of benthic-dwelling organisms during anoxia, long-term reductions in the depth distribution of macrophyte communities, changes in the species composition of macrophyte communities, and increases in reports of harmful algal blooms. In 1987 the Action Plan on the Aquatic Environment was adopted to combat nutrient pollution of the aquatic environment with the overall goal of reducing nitrogen loads by 50% and point source phosphorus loads by 80%. The Danish Aquatic Nation-wide Monitoring Program was begun in 1988 in order to describe the status of point sources (industry, sewage treatment plants, stormwater outfalls, scattered dwellings, and fish farms), ground water, springs, agricultural watersheds, streams, lakes, atmospheric deposition, and the marine environment. Another important aspect of the program was to document the effects on the aquatic environment of the measures and investments taken for nutrient reduction as outlined in the Action Plan. The monitoring program should determine if reductions in nutrients are achieved by the measures taken and should help decision makers choose appropriate additional measures to fulfill the objectives. Coordination with international programs and commissions is an important component of the monitoring program to meet internationally agreed upon reductions in nutrient inputs. The future and direction of the Danish National Aquatic Monitoring and Assessment Program will be to a large extent shaped by both the Water Framework Directive and Habitat Directive adopted by the European Union.     

Hoanib River flood deposits of Namib Desert interdunes asanalogues for thin permeability barrier mudstone layers inaeolianite reservoirs

ABSTRACT The ephemeral braided Hoanib River of NW Namibia flows for a few days a year, and only high discharges enable the river to pass through interdunal depressions within the northern Namib Desert dune field to the Atlantic. The dune field comprises mainly large transverse dunes resulting from predominant SSW winds. River flood deposits between aeolian dunes are analogous to mudstone layers conformably interbedded with ancient aeolianite dune foresets. Deep floods pond laterally to considerable depths (metres to >10 m) in adjacent interdunes, depositing mud layers (1–50 cm) to considerable heights on avalanche and stoss faces of bounding dunes. Fairly passive flooding only disturbs aeolian stratification minimally. Floodwater clay infiltrates and settles as an impermeable seal, with a flood pond on top, perched, above regional groundwater. Flood ponds evaporate slowly for long periods (>3 years). Early emergence desiccates higher parts of a mud layer. Subsequent floods can refill a predecessor pond, benefiting from the existing impervious seal. Potential preservation of such mud layers is lower on the stoss face, but high on the avalanche face after burial by subsequent dune reactivation and migration. The leeward (right) Hoanib bank, a dune stoss face, is river and wind eroded to exhume fossil interdune pond mud layers of an earlier Hoanib channel. The highly inclined layers are interbedded with dune avalanche foresets and represent the edges of two successive fossil ponds exposed in plan. Ancient flood pond mudstones occur in the Permian–Triassic hydrocarbon reservoir, the Sherwood Sandstone Group of the Cheshire Basin (Kinnerton Formation) and Irish Sea Basin and were previously used erroneously to argue against the aeolian origin of cross‐bed sets. Hoanib studies show that primary river interaction with a dune field might preserve only localized erosional omission surfaces in ancient aeolianites, with little sandy barform preservation, prone to aeolian reworking. Around the main fluvial channel locus, however, flood pond mudstone layers should form a predictable halo, within which fluid permeability will decrease.     

Remote sensing and petroleum seepage: a review and case study

When reservoirs leak, varying quantities of oil and gas migrate to the surface as macroseeps, which are visible, and microseeps, which are invisible. This review article describes the mechanisms of seepage and the resulting surface manifestations in relation to optical high-resolution remote sensing data. Oil pools and tar deposits (macroseeps) often can be detected directly by remote sensing. Microseeps are more difficult to study using remote sensing, but they give rise to vegetation stress, and cause geochemical alterations in soil and rocks, which can be studied indirectly using hyperspectral sensors. An integrated methodology is presented to combine various geoscience and remote sensing datasets for seepage detection. A combination of red-edge modelling algorithms and spectral matching tools is identified that provides a validated technique for onshore microseepage detection. These remote sensing tools are not only important for petroleum exploration, but also have environmental implications because seeps emit greenhouse gases. A statistical data integration approach was developed based on Bayesian assumptions, which can be used to integrate hyperspectral remote sensing data, other satellite remote sensing data, and ancillary field geological and geochemical datasets, for modelling microseepage. In a case study from the Ventura basin (Santa Barbara) in Southern California, Probe-1 data from the 1998 Geosat Group Shoot are integrated with field and subsurface geological and geochemical data to predict possible sites of hydrocarbon microseepage.     

A technique for modeling transport/conversion processes applied to smectite-to-illite conversion in HLW buffers

This paper describes an application of a technique developed for modeling chemical processes in buffer materials that are controlled by a reaction rate and by the transport of one component, which is essential for the process in question to occur. The application described here is the illitization of smectite by fixation of potassium ions in cation exchange positions, and with diffusion of dissolved potassium being the transport process. The technique is verified by comparison with analytical solutions. An overview, based on small models, is given which outlines under what constellations of assumptions the time scale for conversion of the buffer is controlled by reaction rate parameters and under which conditions transport controls this time scale. Examples are given of calculations performed for deposition holes, with potassium being supplied from the surroundings to the upper parts of the highly compacted bentonite buffer. It is concluded that restrictions in nearfield transport capacity have a very significant effect on the conversion time scale. Towards the end of the heating period about 98% of the smectite is found to remain, even for reaction rates and buffer transport conditions that would have left only 10% of the smectite unconverted without nearfield transport restrictions. It is also concluded that the modeling technique can be applied to other, similar, transport/conversion processes.     

Propagating rift tectonics of a Caledonian marginal basin: Multi-stage seafloor spreading history of the Solund-Stavfjord ophiolite in western Norway

The Late Ordovician Solund-Stavfjord ophiolite in western Norway represents a remnant of the Iapetus oceanic lithosphere that developed in a Caledonian marginal basin. The ophiolite contains three structural domains that display distinctively different crustal architecture that reflects the mode and nature of magmatic and tectonic processes operated during the multi-stage seafloor spreading evolution of this marginal basin. Domain I includes, from top to bottom, an extensive extrusive sequence, a transition zone consisting of dike swarms with screens of pillow breccias, a sheeted dike complex, and plutonic rocks composed mainly of isotropic gabbro and microgabbro. Extrusive rocks include pillow lavas, pillow breccias, and massive sheet flows and are locally sheared and mineralized, containing epidosites, sulfide-sulfate deposits, Fe-oxides, and anhydrite veins, reminiscent of hydrothermal alteration zones on the seafloor along modern mid-ocean ridges. A fossil lava lake in the northern part of the ophiolite consists of a >65-m-thick volcanic sequence composed of a number of separate massive lava units interlayered with pillow lavas and pillow breccia horizons. The NE-trending sheeted dike complex contains multiple intrusions of metabasaltic dikes with one- and two-sided chilled margins and displays a network of both dike-parallel normal and dike-perpendicular oblique-slip faults of oceanic origin. The dike-gabbro boundary is mutually intrusive and represents the root zone of the sheeted dike complex. The internal architecture and rock types of Domain I are analogous to those of intermediate-spreading oceanic crust at modern mid-ocean ridge environments. The ophiolitic units in Domain II include mainly sheeted dikes and plutonic rocks with a general NW structural grain and are commonly faulted against each other, although primary intrusive relations between the sheeted dikes and the gabbros are locally well preserved. The exposures of this domain occur only in the northern and southern parts of the ophiolite complex and are separated by the ENE-trending Domain III, in which isotropic to pegmatitic gabbros and dike swarms are plastically deformed along ENE-striking sinistral shear zones. These shear zones, which locally include fault slivers of serpentinite intrusions, are crosscut by N20°E-striking undeformed basaltic dike swarms that contain xenoliths of gabbroic material. The NW-trending sheeted dike complex in the northern part of Domain II curves into an ENE orientation approaching Domain III in the south. The anomalous nature of deformed crust in Domain III is interpreted to have developed within an oceanic fracture zone or transform fault boundary.REE chemistry of representative extrusive and dike rocks from all three domains indicates N- to E-MORB affinities of their magmas with high Th/Ta ratios that are characteristic of subduction zone environments. The magmatic evolution of Domain I encompasses closed-system fractional crystallization of high-Mg basaltic magmas in small ephemeral chambers, which gradually interconnected to form large chambers in which mixing of primary magmas with more evolved and fractionated magma caused resetting of magma compositions through time. The compositional range from high-Mg basalts to ferrobasalts within Domain I is reminiscent of modern propagating rift basalts. We interpret the NE-trending Domain I as a remnant of an intermediate-spread rift system that propagated northeastwards (in present coordinate system) into a pre-existing oceanic crust, which was developed along the NW-trending doomed rift (Domain II) in the marginal basin. The N20°E dikes laterally intruding into the anomalous oceanic crust in Domain III represent the tip of the rift propagator. The inferred propagating rift tectonics of the Solund-Stavfjord ophiolite is similar to the evolutionary history of the modern Lau back-arc basin in the SW Pacific and suggests a complex magmatic evolution of the Caledonian marginal basin via multi-stage seafloor spreading tectonics.     

Quantifying volume transports during SKAGEX with the Norwegian Ecological Model system

A coupled 3-dimensional physical, chemical and biological model system, NORWECOM (the NORWegian ECOlogical Model system), is validated and used to identify and quantify the short-term variability of the different water masses being transported into and out of Skagerrak. The model system is a nesting between a coarse grid model set up for an extended North Sea, and a fine grid defined in the Skagerrak/Kattegat area.Originating from the extensive SKAGEX (SKAGerrak EXperiment) database, several interesting events have been identified and become the focus of the modeling. Through interactive use of the SKAGEX data set and NORWECOM, it is possible to gain a new insight into a very complex hydrodynamic system, an insight that is hard to achieve based on measurements only.     

Late Cretaceous exhumation history of an extensional extruding wedge (Graz Paleozoic Nappe Complex, Austria)

Late Cretaceous structures within the eastern Graz Paleozoic Nappe Complex define an extruding wedge with north-eastward directed thrusting in eastern portions and strike-slip shear along the margins. Stacking structures are overprinted by south-westward directed extension with low-grade metamorphic rocks in the hangingwall and high-grade basement rocks in the footwall. Pressure–temperature and structural data are obtained from successively opening quartz veins that record various stages of progressive deformation and metamorphism. Fluid inclusion data and related structures show that during extension isothermal decompression from ca. 550°C and 8 kbar down to ca. 450°C and 2 kbar was related to exhumation of rocks from deep crustal levels. The data point to a high geothermal gradient and explain condensed paleo-isotherms due to ductile normal faulting in the eastern areas of the Graz Paleozoic Nappe Complex. The investigated Late Cretaceous structural elements suggest that the Graz Paleozoic Nappe Complex decoupled from the surrounding basement units and operated as a large-scale extension–extrusion corridor that evolved prior to Miocene extrusion tectonics in the Eastern Alps.