Boron incorporation into mullite

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria     

Chandra measurements of the X-ray core and cluster of 3C 220.1

We report results of an 18-ks exposure with the ACIS instrument on Chandra of the powerful z =0.62 radio galaxy 3C 220.1. The X-ray emission separates into cluster gas of emission-weighted kT ∼5 keV , 0.7–12 keV luminosity (to a radius of 45 arcsec) of 5.6×10⁴⁴ erg s⁻¹ and unresolved emission (coincident with the radio core). While the extended X-ray emission is clearly thermal in nature, a straightforward cooling-flow model, even in conjunction with a point-source component, is a poor fit to the radial profile of the X-ray emission. This is despite the fact that the measured properties of the gas suggest a massive cooling flow of ∼130 M_⊙ yr⁻¹, and the data show weak evidence for a temperature gradient. The central unresolved X-ray emission has a power-law spectral energy index α ∼0.7 and 0.7–12 keV luminosity of 10⁴⁵ erg s⁻¹, and any intrinsic absorption is relatively small. The two-point spectrum of the core emission between radio and X-ray energies has α _rx=0.75 . Since this is a flatter spectrum than seen in other sources where the X-ray emission is presumed to be radio-related, regions close to the active galactic nucleus (AGN) in this source may dominate the central X-ray output, as is believed to be the case for lobe-dominated quasars. Simple unification models would be challenged if this were found to be the case for a large fraction of high-power radio galaxies.     

Turbulent flows over mountainous terrain modelled by the Reynolds equations

A numerical model based upon fundamental principles, a standard (k, ) turbulence closure and a finite element integration technique, is applied to separated flows over hills. Predictions are compared to experimental data from a wind tunnel. Although few-equation turbulence closures have been shown to have obvious deficiencies with respect to comparable flows, the model predicts remarkably accurately, without coefficient adjustments of any kind. Even the turbulent intensity is predicted quite realistically.     

Approaches to analyse and model changes in impacts: reply to discussions of “How to improve attribution of changes in drought and flood impacts”*

ABSTRACT

We thank the authors, Brunella Bonaccorso and Karsten Arnbjerg-Nielsen for their constructive contributions to the discussion about the attribution of changes in drought and flood impacts. We appreciate that they support our opinion, but in particular their additional new ideas on how to better understand changes in impacts. It is great that they challenge us to think a step further on how to foster the collection of long time series of data and how to use these to model and project changes. Here, we elaborate on the possibility to collect time series of data on hazard, exposure, vulnerability and impacts and how these could be used to improve e.g. socio-hydrological models for the development of future risk scenarios.     

Physical weathering of building stones induced by freeze–thaw action: a laboratory long-term study

Damages to natural building stones induced by the action of frost are considered to be of great importance. Commonly, the frost resistance of building stones is checked by standardised freeze–thaw tests before using. Corresponding tests normally involve 30–50 freeze–thaw action cycles. In order to verify the significance of such measurements, we performed long-term tests on four selected rocks over 1,400 freeze–thaw action cycles. Additionally, numerous petrophysical parameters were analysed to compare the behaviour of rocks in the weathering tests according to the current explanatory models of stress formation by growing ice crystals in the pore space. The long-term tests yield more information about the real frost sensibility of the rocks. A clear deterioration cannot be determined in most cases until 50 weathering cycles have been completed. In the freeze–thaw tests, the samples are also stressed by changing temperature and moisture, indicating that different decay mechanisms can interfere with each other. Thus, thermohygric and moisture expansion are important damage processes.     

A canonical theory for short GPS baselines. Part IV: precision versus reliability

This contribution is the last of four parts and deals with the link between baseline precision and ambiguity reliability. It is shown analytically how and to what extent the baseline-ambiguity correlation is related to the gain in baseline precision, to the volume of the ambiguity search space, and to the impact of potential integer ambiguity biases. Also, an ambiguity DOP measure is introduced together with its closed-form formulae for the three different single-baseline models. Received: 16 July 1996 / Accepted: 14 November 1996     

Period–luminosity relations for red supergiant variables – I.The calibration

We present CCD photometry of red supergiant long-period variables (LPVs) in the Per OB1 association, the Large Magellanic Cloud (LMC) and M33. The photometry was obtained in the Kron–Cousins R and I bandpasses and in a narrow bandpass ( λ ₀=8250 Å, FWHM=300 Å) chosen to avoid TiO bands in the spectral energy distribution of the LPVs. Because the strength of the TiO bands varies greatly with temperature, which varies with the phase of an LPV, avoiding TiO reduces the amplitude of the photometric variations seen in LPVs. The result is a lower dispersion and a well defined period–luminosity (PL) relation.
For the LMC sample we find an rms dispersion of 0.27 mag in the narrow-band PL relation and slightly larger dispersions for the LPVs in Per OB1 and M33. This dispersion is comparable to that of the Cepheid PL relation at similar wavelengths. Adopting a distance modulus of 18.5±0.1 mag for the LMC, we obtain distance moduli of 11.68±0.15 mag for Per OB1 and 24.85±0.13 mag for M33. These distances agree well with those based on main sequence fitting for Per OB1 and the Cepheid distance for M33. Since LPVs are ∼ 5 times more common than Cepheids and have a well defined PL relation, LPVs provide a promising method for estimating Galactic and extra galactic distances.     

Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.