Spatial variability and temporal dynamics of surface water pCO2, ��O2/Ar and dimethylsulfide in the Ross Sea, Antarctica

We report results from two surveys of pCO₂, biological O₂ saturation (??O₂/Ar) and dimethylsulfide (DMS) in surface waters of the Ross Sea polynya. Measurements were made during early spring (November 2006-December 2006) and mid-summer (December 2005-January 2006) using ship-board membrane inlet mass spectrometry (MIMS) for high spatial resolution (i.e. sub-km) analysis. During the early spring survey, the polynya was in the initial stages of development and exhibited a rapid increase in open water area and phytoplankton biomass over the course of our ∼3 week occupation. We observed a rapid transition from a net heterotrophic ice-covered system (supersaturated pCO₂ and undersaturated O₂) to a high productivity regime associated with a Phaeocystis-dominated phytoplankton bloom. The timing of the early spring phytoplankton bloom was closely tied to increasing sea surface temperature across the polynya, as well as reduced wind speeds and ice cover, leading to enhanced vertical stratification. There was a strong correlation between pCO₂, ??O₂/Ar, DMS and chlorophyll a (Chl a) during the spring phytoplankton bloom, indicating a strong biological imprint on gas distributions. Box model calculations suggest that pCO₂ drawdown was largely attributable to net community production, while gas exchange and shoaling mixed layers also exerted a strong control on the re-equilibration of mixed layer ??₂ with the overlying atmosphere. DMS concentrations were closely coupled to Phaeocystis biomass across the early spring polynya, with maximum concentrations exceeding 100 nM.During the summer cruise, we sampled a large net autotrophic polynya, shortly after the seasonal peak in phytoplankton productivity. Both diatoms and Phaeocystis were abundant in the phytoplankton assemblages during this time. Minimum pCO₂ was less than 100 ppm, while ??O₂/Ar exceeded 30% in some regions. Mean DMS concentrations were ∼2-fold lower than during the spring, although the range of concentrations was similar between the two surveys. There was a significant correlation between pCO₂, ??O₂/Ar and Chl a across the summer polynya, but the strength of these correlations and the slope of O₂ vs. CO₂ relationship were significantly lower than during the early spring. Summertime DMS concentrations were not significantly correlated to phytoplankton biomass (Chl a), pCO₂ or ??O₂/Ar. In contrast to the early spring time, there were no clear temporal trends in summertime gas concentrations. Rather, small-scale spatial variability, likely resulting from mixing and localized sea-ice melt, was clearly evident in surface gas distributions across the polynya. Analysis of length-scale dependent variability demonstrated that much of the spatial variance in surface water gases occurred at scales of <20 km, suggesting that high resolution analysis is needed to fully capture biogeochemical heterogeneity in this system.     

偕胺肟基聚丙烯腈/蒙脱土纳米复合材料海水铀的吸附规律研究

采用偕胺肟化聚丙烯腈/蒙脱土(APAN/MMT)复合纳米吸附材料对海水中的铀进行吸附,考察了吸附条件对APAN/MMT吸附铀量的影响,并对APAN/MMT吸附铀的动力学和热力学进行了探讨.结果表明:铀初始浓度、溶液温度较高、采用磁力搅拌吸附方式有利于吸附速率的提高,溶液pH对吸附性能有一定的影响,在pH为5时,平衡吸附...     

Nutrient and chlorophyll a anomaly in red-tide periods of 2003-2008 in Sishili Bay, China

Sishili Bay is the most important aquiculture and tourism area for the city of Yantai, China; however, red tides occurred frequently and have caused huge economic losses in this bay in recent years. To gain a better understanding of the local ecological environments in the bay, we conducted this research between 2003 and 2008 to analyze variations in nutrients and chlorophyll (chl-a) during high frequency red tide period (May to September). The results show that the chl-a concentration increased from 2.70 in 2003 to 7.26 mg/m3 in 2008, while the concentration of total inorganic nitrogen (TIN) and silicate (SiO3-Si) increased lineally from 5.18 and 1.45 μmol/L in 2003 to 18.57 and 9.52 μmol/L in 2008, respectively, and the annual phosphate (PO4-P) varied between 0.15 and 0.46 μmol/L. Special attention was given to a red tide in August 2007 occurred when water temperature was high and nutrient concentrations increased sharply because of a heavy rainfall. Overall, the results show the P limitation in Sishili Bay, and reveal that red tides were caused by eutrophication from terrestrial inputs and local warm weather, particularly during rainy periods. Therefore, to control red tide, greater efforts should be made to reduce sewage discharges into Sishili Bay, particularly during rainfall seasons.     

基于ArcMap插件的土地利用规划编制方法研究

近几年来,GIS在土地利用规划领域得到了广泛的应用.但是受到规划的复杂性等因索的影响,GIS也表现出了缺乏针对性等缺陷.本文根据规划编制的具体要求开发了一个土地利用规划编制插件.此插件可以无缝地集成到ArcMap中.在土地利用规划编制过程中使用此插件可以提高工作的效率和精度.此插件提供了一系列数据处理工具和数据库管理工...     

一次东北冷涡的天气学分析及基于HYSPLIT4模式的水汽通道特征

摘 要：利用连续一年旌德县负氧离子监测数据,分别以兔儿山公园、路西村茶园代表城市公园、高山茶园这两种生态环境,对城市公园和高山茶园负氧离子浓度特征以及气象要素对负氧离子浓度影响进行比较分析。结果表明：①高山茶园负氧离子浓度显著高于城市公园;②负氧离子浓度夏季最高,冬季最低,春秋季次之,6月负氧离子浓度达全年最高;③负氧离子浓度日变化整体呈“一峰一谷”变化趋势,峰值出现在上午,谷值出现在正午前后,夜间至上午负氧离子浓度较高,城市公园负氧离子浓度日较差较高山茶园偏小;④负氧离子浓度日变化与气温、风速呈显著负相关;⑤负氧离子浓度雨天最高,晴天次之,阴天和多云相对较低,暴雨天气条件下大气负氧离子浓度显著提高。     

Tsunami-induced scour at coastal roadways: a laboratory study

Coastal roads are lifelines for bringing emergency personnel and equipment into affected areas after tsunamis, thus careful thought should be given to how to make roadways safer from tsunamis. Scouring at roadways is the primary damage caused by tsunamis; however, tsunami-induced scouring and beach erosion are less understood compared to tsunami runup and tsunami inundation. A set of laboratory experiments are reported in this study on tsunami-induced scour at a road model situated on a sandy beach. Our experiments showed that the distance between the shoreline and a roadway, which varies with tides, was a key factor affecting the scour depth at the road. Having the coastal road at about half of the inundation distance is not the most ideal location. The depth of road embedment did not affect the scour depth in our experiments. It was also found that for typical tsunamis, the scour depth is unlikely to reach its equilibrium stage. The information reported in this study is useful for local authorities to assess potential tsunami damage of roads and to have a better plan for tsunami disaster relief.     

Zircon U–Pb Dating and Geochemistry of the Linong Granitoid and Its Relationship to Cu Mineralization in the Yangla Copper Deposit,Yunnan, China

The Yangla copper deposit (Cu reserves: 1.2 Mt) in the Jinshajiang–Lancangjiang–Nujiang region in China is spatially associated with the Linong granitoid. Zircon U–Pb dating shows the granitoid formed at 234.1 ± 1.2 to 235.6 ± 1.2 Ma, and the KT2 ore body of the deposit yields a molybdenite Re–Os model age of 230.9 ± 3.2 Ma. The ages of mineralization and crystallization of the granitoid are identical within the measurement uncertainties, suggesting the Yangla deposit is genitically related to the Indosinian Linong granitoid.     

Climate and environmental changes over the past 150 years inferred from the sediments of Chaiwopu Lake, central Tianshan Mountains, northwest China

We used a 55-cm sediment core from shallow Chaiwopu Lake in the central Tianshan Mountains of Xinjiang, northwest China, to investigate climate and environmental changes in this arid region over the past ~150 years. The core was dated using ¹³⁷Cs. We compared temporal changes in several sediment variables with recent meteorological and tree-ring records. Organic matter had a positive correlation with the Palmer Drought Severity Index in the central Tianshan Mountains, and the δ¹³C of organic matter had a positive correlation with regional temperature. We applied constrained incremental sum-of-squares cluster analysis to element concentrations in the core and identified three distinct zones: (1) 55–46 cm, ~1860–1910, (2) 46–26 cm, ~1910–1952, and (3) 26–0 cm, 1952–present. Between 1880 and 1910 AD, following the Little Ice Age (LIA), the sediment environment was relatively stable, climate was cold and dry, and the lake water displayed high salinity, in contrast to conditions during the LIA. During the LIA, westerlies carried more water vapor into Central Asia when the North Atlantic Oscillation was in a negative phase, and encountered the enhanced Siberia High, which probably led to increased precipitation. In the period 1910–1950 AD, the lake was shallow and the regional climate was unstable, with high temperatures and humidity. In the last ~15–20 years, human activities caused an increase in sediment magnetic susceptibility, and heavy metal and total phosphorus concentrations in the sediment were substantially enriched. Mean annual temperature displays a warming trend over the past 50 years, and the lowest temperature was observed in the 1950s. There has been an increase in annual total precipitation since the 1990s. The combined influences of climate and human activity on the lake environment during this period were faithfully recorded in sediments of Chaiwopu Lake. This study provides a scientific basis for environmental management and protection.     

Modeling impacts of sediment delivery ratio and land management on adsorbed non-point source nitrogen and phosphorus load in a mountainous basin of the Three Gorges reservoir area, China

Agricultural nonpoint source (NPS) pollution at the Three Gorges reservoir area in China has been increasingly recognized as a threat to aquatic environment in recent years due to the serious eutrophication problem. Adsorbed NPS pollution is one of the major forms of NPS pollution in mountainous regions, the essential of the adsorbed NPS pollution is soil loss. Thus, simple, highly sensitive and continuous methods are required to simulate and quantify sediments yield at watershed scales. It is imperative to construct an integrated model to estimate the sediment yield and adsorbed NPS pollution load. According to the characteristics of climate, hydrology, topography, geology, geomorphology and land use types in Three Gorges reservoir area, a GIS-based dynamic-integrated-distributed model of annual adsorbed NPS load was presented in view of impacts of the rainfall intensity, sediment delivery ratio (SDR) and land management, where the temporally dynamic-continuous model of annual sediment yield was established by modifying the revised Universal Soil Loss Equation (RUSLE), and the spatially integrated-distributed model of annual adsorbed NPS load was then developed via the correlation between sediment yield and adsorbed NPS load. Furthermore, a case study of the Jialing River basin in China was applied to validate the integrated model, the dynamic-distributed coupling among GIS technology, sediment yield model, and adsorbed NPS load model was achieved successfully. The simulation results demonstrate the following: (1) runoff and sediment are influenced greatly by rainfall intensity, SDR and vegetation cover; rainfall and land management show high sensitivities to the integrated model; the average annual adsorbed TN and TP pollution loads from 2006 to 2010 decreased by 76 and 74 % compared with the previous treatment (1990), respectively. (2) Spatio-temporal variations of adsorbed NPS nitrogen and phosphorus load are mainly related to different land use types and the background level of nutriments in topsoil; different land use types have different contribution rates; the largest contribution rates of adsorbed total nitrogen (TN, 58.9 %) and total phosphorus (TP, 53 %) loads are both from the dryland cropland. (3) The identification of critical source areas can help to implement the prevention and control measures aiming at the reduction of water environmental pollution. These results will provide useful and valuable information for decision makers and planners to take sustainable land use management and soil conservation measures for the control of sediment pollution in the Three Gorges reservoir area. The application of this model in the catchment shows that the integrated model may be used as a major tool to assess sediment yield risks and adsorbed NPS pollution load at mountainous watersheds.