Imaging crustal discontinuities and the downgoing slab beneath western Crete

The migration of teleseismic receiver functions yields high-resolution images of the crustal structure of western Crete. Data were collected during two field campaigns in 1996 and 1997 by networks of six and 47 short-period three-component seismic stations, respectively. A total of 1288 seismograms from 97 teleseismic events were restituted to true ground displacement within a period range from 0.5 to 7 s. The application of a noise-adaptive deconvolution filter and a new polarization analysis technique helped to overcome problems with local coda and noise conditions. The computation and migration of receiver functions results in images of local crustal structures with unprecedented spatial resolution for this region. The crust under Crete consists of a continental top layer of 15–20 km thickness above a 20–30 km thick subducted fossil accretionary wedge with a characteristic en echelon fault sequence. The downgoing oceanic Moho lies at a depth of 40–60 km and shows a topography or undulation with an amplitude of several kilometres. As a consequence of slab depth and distribution of local seismicity, the Mediterranean Ridge is interpreted as the recent accretionary wedge.     

Pink manganian phengite in a high P/T meta-conglomerate from northern Syros (Cyclades, Greece)

A new occurrence of Mn-rich rocks was discovered within the high-pressure/low-temperature metamorphic rocks on the Palos peninsula of Syros (Greece). Near the summit of Mount Príonas, a meta-conglomerate consists of calcite (~63 wt%), pink manganian phengite, blue–purple manganian aegirine–jadeite, microcline, albite and quartz. In addition, it contains abundant braunite-rich aggregates (up to ~1.5 cm in diameter) that include hollandite [(Ba_0.98–1.02K_<0.01Na_<0.02Ca_<0.03) (Mn _1.02–1.52 ³⁺ Fe _0.38–0.88 ³⁺ Ti_0.29–0.92Mn _5.11–5.76 ⁴⁺ )O₁₆], barite and manganian hematite. Due to metamorphic recrystallization and deformation, the contacts between clasts and matrix are blurred and most clasts have lost their identity. In back-scattered electron images, many aegirine–jadeite grains appear patchy and show variable jadeite contents (Jd_10–67). These pyroxenes occur in contact with either quartz or albite. Manganian phengite (3.41–3.49 Si per 11 oxygen anions) is of the 3T type and contains 1.4–2.2 wt% of Mn₂O₃. At the known P–T conditions of high-pressure metamorphism on Syros (~1.4 GPa/ 470 °C), the mineral sub-assemblage braunite + quartz + calcite (former aragonite) suggests high oxygen fugacities relative to the HM buffer (+7 ≤ ?f_O2 ≤ + 17) and relatively high CO₂ fugacities. The exact origin of the conglomerate is not known, but it is assumed that the Fe–Mn-rich and the calcite-rich particles originated from different sources. Braunite has rather low contents of Cu (~0.19 wt%) and the concentrations of Co, Ni and Zn are less than 0.09 wt%. Hollandite shows even lower concentrations of these elements. Furthermore, the bulk-rock compositions of two samples are characterized by low contents of Cu, Co and Ni, suggesting a hydrothermal origin of the manganese ore. Most likely, these Fe–Mn–Si oxyhydroxide deposits consisted of ferrihydrite, todorokite, birnessite, amorphous silica (opal-A) and nontronite. Al/(Al + Fe + Mn) ratios of 0.355 and 0.600 suggest the presence of an aluminosilicate detrital component.     

UV irradiation of natural organic matter (NOM): impact on organic carbon and bacteria

UV-induced transformation of dissolved organic matter (DOC) is often accompanied by reduction of molecular weight and aromaticity and an increase of low-molecular weight (LMW) matter that can be utilized as a substrate by heterotrophic bacteria. Moreover, the generation of reactive transients and mineralization of DOC occurs. For a better understanding of the modification that starts after irradiation and to distinguish between possible chemical and biological modifications, we selected different natural organic matter (NOM) from Norway and Germany. The aqueous solutions were treated by UV irradiation and divided into two aliquot samples. NaN₃ anti-bacterial treatment was applied to one sample, and high-pressure size-exclusion chromatography (HPSEC) analysis was used for both. In all samples, we found typical modifications of NOM after UV irradiation. Incubation (>7?days) of UV-irradiated NOM samples resulted in lower levels of LMW matter and increased aromaticity. Parallel to these changes of carbon fractions, an increase in bacterial cell numbers was observed. Addition of NaN₃ to NOM, however, inhibited the reduction of LMW matter, indicating that microbial activity accounted for the observed changes in NOM. Analysis of the bacterial community composition by denaturing gradient gel electrophoresis (DGGE) of the amplified 16S rRNA genes revealed that bacterial communities of non-irradiated and UV-irradiated NOM were different and that UV selected for specific members of ??-proteobacteria, ??-proteobacteria, and Bacteriodetes. Our results imply that after UV-irradiation of NOM, specific bacterial members are well adapted to low pH, high LMW DOC concentrations, and oxidative stress, and therefore thrive well on UV-irradiated humic matter.     

Deep Time Reconstructions of Internal Earth Structure with the Adjoint Method

正The adjoint method is a powerful tool to obtain gradient information in a computational model relative to unknown model parameters,allowing one to solve inverse problems where analytical solutions are not available or the cost to determine prohibitive.In geodynamics its most prominent application relates to the restoration problem of mantle convection(i.e.,to reconstruct past mantle flow states with dynamic earth models back in time by finding optimal flow histories relative to     

True polar wander in mantle convection models with multiple, mobile continents

The geologic record supports numerous instances during which continents apparently moved at speeds significantly faster than any of today's tectonic plates. While the time dependence of convective driving forces likely explains some such observations, rapid motions of large continents in particular are often attributed to true polar wander (TPW). In order to gauge the potential for connections between continents, mantle temperature anomalies, and polar motion, we present the first calculations of TPW derived from models that couple mantle convection with multiple, mobile continents. We find that the aggregation and dispersal of supercontinents can lead to two types of TPW, driven either by a well developed hot upwelling axis that creates a stable maximum moment of inertia, or by the homogenization of mantle thermal structure following continent dispersal that leads to destabilization of the principal axis and possible large magnitude polar wander. These supercontinent-modulated thermal heterogeneities drive model TPW events as large as 90° at rates of up to 2.5° Ma^− 1. Such magnitudes and speeds are greater than those attained in similar models lacking continents, but comparable to those for episodes inferred from paleomagnetic data for some large continents in the past.     

TOPEX/Poseidon and Jason Equatorial Sea Surface Slope Anomaly in the Atlantic in 2002: Comparison with Wind and Current Measurements at 23W

A time series of velocity profile in the upper 150 m of the equatorial Atlantic was gathered at 23W in 2002 within the PIRATA program. It constitutes the first time series of near surface current measurements simultaneous with altimetric data in the equatorial Atlantic. The surface slope anomaly along the equator is computed from satellite altimetry, and, as a proxy for the pressure gradient along the equator, compared with the wind and near surface current data. In a first step, a time series of the surface slope anomaly along the equator in the Atlantic is computed from the 10-year-long TOPEX/Poseidon sea level anomalies. A sensitivity study establishes the robustness of the calculation. Apart from a 15 cm bias, the equatorial sea surface slope anomalies estimated either from TOPEX/Poseidon or from Jason over the 6-month overlap (Feb.-Aug. 2002) do not reveal drastic differences. We produce two sea surface slope anomaly composite time series for 2002 (one with T/P data, the other with Jason data during the commissioning phase) and compare them to the wind and velocity data at 23W. As expected, the near surface velocity and depth of the upper limit of the equatorial undercurrent (EUC) are extremely well correlated with the surface pressure gradient anomaly. 10-year-long time series of altimetry-derived zonal sea surface slope anomaly and ECMWF ERA40 wind stress are also well correlated. They exhibit similar spectral content and similar anomalous years. This is a first step towards a full analysis of the EUC dynamics using altimetry, PIRATA data (near surface current and subsurface thermohaline structure) and model. These initial comparisons reinforce the utility of Jason measurements for continuing the 10-year and highly accurate TOPEX/Poseidon time series for study of equatorial signals.     

Marine ice-rafted debris records constrain maximum extent of Saalian and Weichselian ice-sheets along the northern Eurasian margin

Ice-rafted debris (IRD) (>2 mm), input in eight sediment cores along the Eurasian continental margin (Arctic Ocean), have been studied over the last two glacial/interglacial cycles. Together with the revised chronologies and new micropaleontological data of two cores from the northern Barents Sea (PS2138) and northeastern Kara Sea (PS2741) spanning Marine Isotope Stages (MIS) 6 to 1, the IRD data give new insights into the glacial history of northern Eurasian ice-sheets over the last 150 ka. The chronologies of the cores are based on stable isotope records, AMS ¹⁴C datings, paleomagnetic and biostratigraphic data.Extensive episodes of northern Barents Sea ice-sheet growth, probably to the shelf edge, occurred during the late Weichselian (MIS 2) and the Saalian (MIS 6). Major IRD discharge at the MIS 4/3-transition hints to another severe glaciation, probably onto the outer shelf, during MIS 4. IRD-based instabilities of the marine-based ice margin along the northern Barents Sea between MIS 4 and 2 are similar in timing with North Atlantic Heinrich events and Nordic Seas IRD events, suggesting similar atmospheric cooling over a broad region or linkage of ice-sheet fluctuations through small sea-level events.In the relatively low-precipitation areas of eastern Eurasia, IRD peak values during Termination II and MIS 4/3-transition suggest a Kara Sea ice-sheet advance onto the outer shelf, probably to the shelf edge, during glacial MIS 6 and 4. This suggests that during the initial cooling following the interglacials MIS 5, and possibly MIS 7, the combined effect of sustained inflow of Atlantic water into the Arctic Ocean and penetration of moisture-bearing cyclones into easterly direction supported major ice build-up during Saalian (MIS 6) and Mid-Weichselian (MIS 4) glaciation. IRD peak values in MIS 5 indicate at least two advances of the Severnaya Semlya ice-sheet to the coast line during the Early Weichselian. In contrast, a distinct Kara Sea ice advance during the Late Weichselian (MIS 2) is not documented by the IRD records along the northeastern Kara Sea margin.