Non-monotonic Responses of Phytoplankton Biomass Accumulation to Hydrologic Variability: A Comparison of Two Coastal Plain North Carolina Estuaries

Freshwater inputs often play a more direct role in estuarine phytoplankton biomass (chlorophyll a) accumulation than nitrogen (N) inputs, since discharge simultaneously controls both phytoplankton residence time and N loading. Understanding this link is critical, given potential changes in climate and human activities that may affect discharge and watershed N supply. Chlorophyll a (chla) relationships with hydrologic variability were examined in 3-year time series from two neighboring, shallow (<5?m), microtidal estuaries (New and Neuse River estuaries, NC, USA) influenced by the same climatic conditions and events. Under conditions ranging from drought to floods, N concentration and salinity showed direct positive and negative responses, respectively, to discharge for both estuaries. The response of chla to discharge was more complex, but was elucidated through conversion of discharge to freshwater flushing time, an estimate of transport time scale. Non-linear fits of chla to flushing time revealed non-monotonic, unimodal relationships that reflected the changing balance between intrinsic growth and losses through time and along the axis of each estuary. Maximum biomass occurred at approximately 10-day flushing times for both systems. Residual analysis of the fitted data revealed positive relationships between chla and temperature, suggesting enhanced growth rates at higher temperatures. N loading and system-wide, volume-weighted chla were positively correlated, and biomass yields per N load were greater than other marine systems. When combined with information on loss processes, these results on the hydrologic control of phytoplankton biomass will help formulate mechanistic models necessary to predict ecosystem responses to future climate and anthropogenic changes.     

Bau und Entwicklung des Harznordrandes bei Bad Harzburg

Zusammenfassung Konglomeratische Oberkreidesandsteine im Raum Bad Harzburg wurden auf ihren Geröll- und Leitmineralgehalt hin untersucht. Aus der Leitmineralverteilung ergibt sich die stratigraphische Stellung der Emscher- und Senonvorkommen zueinander; aus der Geröllführung geht hervor, daß der Brockengranit bereits im Oberemscher im Erosionsniveau lag und die Aufrichtungszone mesozoischer Gesteine am Harznordrand auch im Schimmerwaldgebiet bis zum Quadratensenon übertage vorhanden war, obwohl sie heute hier nicht mehr zu finden ist. Ursache dieser Erscheinung ist ein Schollenabbruch aus dem Dach des Ilsenburggranits, der an der Wende Granulaten-Quadratensenon erfolgte und zu einer lokalen Überfahrung der Aufrichtungszone geführt hat. Die geologische Neuaufnahme des Paläozoikums nördlich des Ilsenburggranites stellt die heutigen Lagerungsverhältnisse dieses Gebietes klar; sie werden bei der Rekonstruktion der ursprünglichen Lagerung und des Bewegungsvorganges zugrunde gelegt, dessen Ergebnis die teilweise Überdeckung des Vorlandes ist. Ein ähnlicher Vorgang liegt auch am benachbarten Okervorsprung der Harznordrandlinie vor.Unter Berücksichtigung der Ergebnisse neuer Tiefbohrungen im Subherzyn wird eine Auffassung von Ablauf und Ursachen tektonischer Vorgänge in diesem Raum entwickelt, die der herrschenden Meinung in zahlreichen Punkten widerspricht:Eine echte Faltung des Subherzyns im Mesozoikum, die bisher vermutete starke Nordbewegung der Harzscholle und eine ausschließliche Bindung tektonischer Vorgänge in diesem Gebiet an orogene Phasen wird abgelehnt.Auslösender Vorgang aller tektonischen Erscheinungen im Subherzyn ist eine vertikale Differentialbewegung der Harz- und Vorlandscholle, die sich seit Ausgang des Paläozoikums gleichsinnig, aber mit örtlich und zeitlich wechselnder Intensität, abspielt.     

Methodology for construction, calibration and validation of a national hydrological model for Denmark

An integrated groundwater/surface water hydrological model with a 1 km² grid has been constructed for Denmark covering 43,000 km². The model is composed of a relatively simple root zone component for estimating the net precipitation, a comprehensive three-dimensional groundwater component for estimating recharge to and hydraulic heads in different geological layers, and a river component for streamflow routing and calculating stream–aquifer interaction. The model was constructed on the basis of the MIKE SHE code and by utilising comprehensive national databases on geology, soil, topography, river systems, climate and hydrology. The present paper describes the modelling process for the 7330 km² island of Sjælland with emphasis on the problems experienced in combining the classical paradigms of groundwater modelling, such as inverse modelling of steady-state conditions, and catchment modelling, focussing on dynamic conditions and discharge simulation. Three model versions with different assumptions on input data and parameter values were required until the performance of the final, according to pre-defined accuracy criteria, model was evaluated as being satisfactory. The paper highlights the methodological issues related to establishment of performance criteria, parameterisation and assessment of parameter values from field data, calibration and validation test schemes. Most of the parameter values were assessed directly from field data, while about 10 ‘free’ parameters were subject to calibration using a combination of inverse steady-state groundwater modelling and manual trial-and-error dynamic groundwater/surface water modelling. Emphasising the importance of tests against independent data, the validation schemes included combinations of split-sample tests (another period) and proxy-basin tests (another area).     

安徽巢湖地区下三叠统综合层序

印度阶一奥伦尼克阶界线的全球层型候选剖面之一位于安徽巢湖地区;巢湖地区的下三叠统也是国际上同期地层中生物地层序列最有代表性、多重地层学手段应用齐备、研究效果最好的地层序列之一。根据巢湖地区3条代表性下三叠统剖面的岩石地层、生物地层和碳同位素地层的最新研究成果归纳出本区早三叠世综合地层序列,作为区域地层对比研究的标准．巢湖的下三叠统明确包含8个牙形石带和6个菊石带。它们具有区域甚至全球对比意义;巢湖地区早三叠世碳同位素δ^13Ccarb的演变呈现2个显著的漂移周期,这种有特色的碳同位素漂移,不仅具有地层学价值,而且可能对于三叠纪初的生物复苏和生态系演变具有指导意义．在综合地层序列基础上,将3条剖面的古地磁学研究成果链接,形成了巢湖地区完整的早三叠世磁性地层序列,包括5个主要的正向极性带和5个反向极性带,这也是目前在本区乃至华南获得的最完整的早三叠世磁极性序列之一．这些为该区域乃至全球相关地层研究树立了一个基本格架。     

Deriving Constraints on Small-Scale Variograms due to Variograms of Large-Scale Data

The application of kriging-based geostatistical algorithms to integrate large-scale seismic data calls for direct and cross variograms of the seismic variable and primary variable (e.g., porosity) at the modeling scale, which is typically much smaller than the seismic data resolution. In order to ensure positive definiteness of the cokriging matrix, a licit small-scale coregionalization model has to be built. Since there are no small-scale secondary data, an analytical method is presented to infer small-scale seismic variograms. The method is applied to estimate the 3-D porosity distribution of a West Texas oil field given seismic data and porosity data at 62 wells.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Electrical conductivity of orthopyroxene and plagioclase in the lower crust

The electrical conductivities of lower crustal orthopyroxene and plagioclase, as well as their dependence on water content, were measured at 6–12 kbar and 300–1,000°C on both natural and pre-annealed samples prepared from fresh mafic xenolith granulites. The complex impedance was determined in an end-loaded piston cylinder apparatus by a Solarton-1260 Impedance/Gain Phase analyzer in the frequency range of 0.1–10⁶ Hz. The spectra usually show an arc over the whole frequency range at low temperature and an arc plus a tail in the high and low frequency range, respectively, at high temperature. The arc is due to conduction in the sample interior, while the tails are probably due to electrode effects. Different conduction mechanisms have been identified under dry and hydrous conditions. For the dry orthopyroxene, the activation enthalpy is ~105 kJ/mol, and the conduction is likely due to small polarons, e.g., electrons hopping between Fe²⁺ and Fe³⁺. For the dry plagioclase, the activation enthalpy is ~161 kJ/mol, and the conduction may be related to the mobility of Na⁺. For the hydrous samples, the activation enthalpy is ~81 kJ/mol for orthopyroxene and ~77 kJ/mol for plagioclase, and the electrical conductivity is markedly enhanced, probably due to proton conduction. For each mineral, the conductivity increases with increasing water content, with an exponent of ~1, and the activation enthalpies are nearly independent of water content. Combining these data with our previous work on the conductivity of lower crustal clinopyroxene, the bulk conductivity of lower crustal granulites is modeled, which is usually >~10⁻⁴ S/m in the range of 600–1,000°C. We suggest that the high electrical conductivity in most regions of the lower crust, especially where it consists mostly of granulites, can be explained by the main constitutive minerals, particularly if they contain some water. Contributions from other highly conducting materials such as hydrous fluids, melts, or graphite films are not strictly necessary to explain the observed conductivities.     

Modeled seasonality of glacial abrupt climate events

Greenland ice cores, as well as many other paleo-archives from the northern hemisphere, recorded a series of 25 warm interstadial events, the so-called Dansgaard-Oeschger (D-O) events, during the last glacial period. We use the three-dimensional coupled global ocean–atmosphere–sea ice model ECBILT-CLIO and force it with freshwater input into the North Atlantic to simulate abrupt glacial climate events, which we use as analogues for D-O events. We focus our analysis on the Northern Hemisphere. The simulated events show large differences in the regional and seasonal distribution of the temperature and precipitation changes. While the temperature changes in high northern latitudes and in the North Atlantic region are dominated by winter changes, the largest temperature increases in most other land regions are seen in spring. Smallest changes over land are found during the summer months. Our model simulations also demonstrate that the temperature and precipitation change patterns for different intensifications of the Atlantic meridional overturning circulation are not linear. The extent of the transitions varies, and local non-linearities influence the amplitude of the annual mean response as well as the response in different seasons. Implications for the interpretation of paleo-records are discussed.     

Stratigraphy and sedimentation rates of Upper Cretaceous deep-water systems of the Rhenodanubian Group (Eastern Alps, Germany)

In the Bavarian Alps (Germany), west of the Isar River, the abyssal deposits of the Lower Barremian to Upper Campanian Rhenodanubian Group consist of siliciclastic and calcareous turbidites alternating with hemipelagic non-calcareous mudstones. The up to 1500-m-thick succession, deposited in the Penninic Basin to the south of the European Plate, is characterized by a low mean sedimentation rate (c. 25 mm kyr⁻¹) over 60 million years. Palaeocurrents and turbidite facies distribution patterns suggest that sedimentation occurred on a weakly inclined abyssal plain. The highest sedimentation rates (up to 240 mm kyr⁻¹) were associated with the calcareous mud turbidites of the newly defined Röthenbach Subgroup, which includes the Piesenkopf, Kalkgraben and Hällritz formations (Middle Coniacian to Middle Campanian). These calcareous turbidites prograded from the west, and interfinger towards the east with red hemipelagic claystone. A high sea level presumably favoured pelagic carbonate production and accumulation on the shelves and on internal platforms in the western part of the basin, whereas siliciclastic shelves with steep slope angles have bordered the eastern part of the basin, where a dearth of turbidite sedimentation and increased Cretaceous oceanic red beds deposition occurred. In contrast to the eustatically-induced Middle Coniacian to Lower Campanian Cretaceous oceanic red beds (calcareous nannoplankton zones CC14 to CC18), red hemipelagites of Early Cenomanian age (upper part of calcareous nannoplankton zone CC9) and early Late Campanian age (upper part of zone CC21 and zone CC22) are interpreted as the result of regional tectonic activity.     

The interannual variability of East Asian Winter Monsoon and its relation to the summer monsoon

1.IntroductionOvertheEastAsiaregion,themostprominentsurfacefeatureofthewintermonsoonisstrongnortheasterliesalongtheeastflankoftheSiberianhighandthecoastofEastAsia.At500hPathereisabroadtroughcenteredaboutatthelongitudesofJapan.Thedominantfea-tureat2O0hPaistheEastAsianjetwithitsmaximumlocatedatjustsoutheastofJapan.Thisktisassociatedwithintensebaroclinicity,largeverticalwindshearandstrongadvectionofcoldair(StaffmembersofAcademiaSinica,l957,LauandChang,1987;BoyleandChen,1987;Chenetal.,1991…