Fatty acid transfer in the food web of a coastal Mediterranean lagoon: Evidence for high arachidonic acid retention in fish

The transfer of fatty acids (FAs) in the food web of a Mediterranean lagoon was studied using FA compositional patterns across several trophic levels. The structure of the food web was inferred from C and N stable isotopes values and an isotope mixing model was used in order to estimate the relative contribution of the different potential food sources to the biomass of consumers. Bidimensional plots of FA composition of food web components against their δ¹⁵N values indicated a general trend of increasing proportions of highly unsaturated fatty acids (HUFAs) with increasing trophic levels while the proportions of saturated fatty acids (SAFAs) and 18-carbon polyunsaturated fatty acids (PUFAs) decreased. Using the relative contributions of food sources to consumers and their FA compositions, a model was built in order to estimate the PUFA composition of consumer mixed diets which was compared to consumer PUFA profiles. The latter allowed the identification of the PUFAs which were mostly enriched/retained in consumer lipids. There was a surprisingly high retention of arachidonic acid (ARA), a trend which challenges the idea of low ARA needs in marine fish and suggests the important physiological role of this essential FA for fish in estuarine environments.     

The crustal evolution of South America from a zircon Hf‐isotope perspective

Hf‐isotope data of >1100 detrital zircon grains from the Palaeozoic, south‐central Andean Gondwana margin record the complete crustal evolution of South America, which was the predominant source. The oldest grains, with crustal residence ages of 3.8–4.0 Ga, are consistent with complete recycling of existing continental crust around 4 Ga. We confirm three major Archaean, Palaeoproterozoic (Transamazonian) and late Mesoproterozoic to early Neoproterozoic crust‐addition phases as well as six igneous phases during Proterozoic to Palaeozoic time involving mixing of juvenile and crustally reworked material. A late Mesoproterozoic to early Neoproterozoic, Grenville‐age igneous belt can be postulated along the palaeo‐margin of South America. This belt was the basement for later magmatic arcs and accreted allochthonous microcontinents as recorded by similar crustal residence ages. Crustal reworking likely dominated over juvenile addition during the Palaeozoic era, and Proterozoic and Archaean zircon was mainly crustally reworked from the eroding, thickened Ordovician Famatinian arc.     

On the causes of pressure oscillations in low‐permeable and low‐compressible porous media

Nonphysical pressure oscillations are observed in finite element calculations of Biot's poroelastic equations in low‐permeable media. These pressure oscillations may be understood as a failure of compatibility between the finite element spaces, rather than elastic locking. We present evidence to support this view by comparing and contrasting the pressure oscillations in low‐permeable porous media with those in low‐compressible porous media. As a consequence, it is possible to use established families of stable mixed elements as candidates for choosing finite element spaces for Biot's equations. Copyright © 2011 John Wiley & Sons, Ltd.     

Preliminary evaluation of the runoff processes in a remote montane cloud forest basin using Mixing Model Analysis and Mean Transit Time

In this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km²) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub‐páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C‐horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow. Copyright © 2011 John Wiley & Sons, Ltd.     

Quaternary denudation of southern Fennoscandia – evidence from the marine realm

Throughout the last 1.1 million years repeated glaciations have modified the southern Fennoscandian landscape and the neighbouring continental shelf into their present form. The glacigenic erosion products derived from the Fennoscandian landmasses were transported to the northern North Sea and the SE Nordic Seas continental margin. The prominent sub‐marine Norwegian Channel trough, along the south coast of Norway, was the main transport route for the erosion products between 1.1 and 0.0 Ma. Most of these erosion products were deposited in the North Sea Fan, which reaches a maximum thickness of 1500 m and has nearly 40 000 km³ of sediments. About 90% of the North Sea Fan sediments have been deposited during the last 500 000 years, in a time period when fast‐moving ice streams occupied the Norwegian Channel during each glacial stage. Back‐stripping the sediment volumes in the northern North Sea and SE Nordic Seas sink areas, including the North Sea Fan, to their assumed Fennoscandian source area gives an average vertical erosion of 164 m for the 1.1–0.0 Ma time period. The average 1.1–0.0 Ma erosion rate in the Fennoscandian source area is estimated to be 0.15 mm a^?1. We suggest, however, that large variations in erosion rates have existed through time and that the most intense Fennoscandian landscape denudation occurred during the time period of repeated shelf edge ice advances, namely from Marine Isotope Stage 12 (c. 0.5 Ma) onwards.     

The potential of point clouds for the analysis of rock kinematics in large slope instabilities: examples from the Swiss Alps: Brinzauls,Pizzo Cengalo and Spitze Stei

Landslides - Lidar measurements and UAV photogrammetry provide high-resolution point clouds well suited for the investigation of slope deformations. Today, however, the information contained in...     

Impact of the unpredictable changes in agricultural groundwater use on long-term sustainable exploitation: the case study of Bouhefna-Haffouz aquifer system,central Tunisia

Long-term exploitation schemes in many regions are often based solely on hydrodynamic factors, while the agricultural use of groundwater undergoes significant changes over time. The Bouhefna-Haffouz aquifer system in central Tunisia is one of those cases where an aquifer exploitation scheme was well designed hydrodynamically to address the political needs at the time. Fifty years later, a numerical groundwater model has been conducted to assess the sustainability of the scheme. Results show that the scheme aimed to lower the groundwater level to reduce overflow to Merguellil Wadi and maintain it at a level that benefits agricultural profitability. This caused loss of the Merguellil baseflow, forcing farmers to switch from traditional irrigation canals to deep wells and motor pumps, thereby disrupting the hydrological budget even further. The numerical model indicates that the flow to the wadi reached zero in 1978, the average flow by vertical leakage decreased from 8 hm³ in 1970 to 2 hm³ in 2020, and the horizontal percolation between the regional aquifer units increased from 1 hm³ in 1970 to 6 hm³ in 2020. Although the groundwater exploitation scheme was not previously considered a factor in local hydrological changes, the results of this study demonstrate the significant impact of societal behavior following the scheme’s implementation on the hydrological budget of Merguellil Wadi.

     

Governance of bioenergy with carbon capture and storage (BECCS): accounting,rewarding, and the Paris agreement

Studies show that the ‘well below 2°C’ target from the Paris Agreement will be hard to meet without large negative emissions from mid-century onwards, which means removing CO₂ from the atmosphere and storing the carbon dioxide in biomass, soil, suitable geological formations, deep ocean sediments, or chemically bound to certain minerals. Biomass energy combined with Carbon Capture and Storage (BECCS) is the negative emission technology (NET) given most attention in a number of integrated assessment model studies and in the latest IPCC reports. However, less attention has been given to governance aspects of NETs. This study aims to identify pragmatic ways forward for BECCS, through synthesizing the literature relevant to accounting and rewarding BECCS, and its relation to the Paris Agreement. BECCS is divided into its two elements: biomass and CCS. Calculating net negative emissions requires accounting for sustainability and resource use related to biomass energy production, processing and use, and interactions with the global carbon cycle. Accounting for the CCS element of BECCS foremost relates to the carbon dioxide capture rate and safe underground storage. Rewarding BECCS as a NET depends on the efficiency of biomass production, transport and processing for energy use, global carbon cycle feedbacks, and safe storage of carbon dioxide, which together determine net carbon dioxide removal from the atmosphere. Sustainable biomass production is essential, especially with regard to trade-offs with competing land use. Negative emissions have an added value compared to avoided emissions, which should be reflected in the price of negative emission ‘credits’, but must be discounted due to global carbon cycle feedbacks. BECCS development will depend on linkages to carbon trading mechanisms and biomass trading.

Key policy insights

• A standardized framework for sustainable biomass should be adopted.

• Countries should agree on a standardized framework for accounting and rewarding BECCS and other negative emission technologies.

• Early government support is indispensable to enable BECCS development, scale-up and business engagement.

• BECCS projects should be designed to maximize learning across various applications and across other NETs.

• BECCS development should be aligned with modalities of the Paris Agreement and market mechanisms.

     

Global Calibration of SARAL/AltiKa Using Multi-Mission Sea Surface Height Crossovers

SARAL/AltiKa completed its first year in orbit in March 2014. The 1 Hz GDR-T data of the first 10 cycles of the mission are used to perform a comprehensive quality assessment by means of a global multi-mission crossover analysis. Within this approach, SARAL sea surface heights are compared with data from other current missions, mainly Jason-2 and Cryosat-2, to reveal its accuracy and consistency with the other altimeter systems. Alongside with global mean range bias and instrumental drifts, investigations on geographically correlated errors as well as on the realization of the systems origin are performed. The study proves the high quality and reliability of SARAL. The mission shows only a small range bias of about ?5 cm with respect to Jason-2 and neither significant time-tag bias nor instrumental drifts. With 1.3 cm the scatter of radial errors is in the same order of magnitude as for Cryosat-2 and Jason-1 GM and will probably further improve using an enhanced sea state bias (SSB) model. However, the wet tropospheric corrections from SARAL radiometer still show some systematic effects influencing the range bias as well as geographically correlated error patterns and the z-component of the origin. Improved inflight calibration will be necessary to overcome these effects.