Risk perception in small island developing states: a case study in the Commonwealth of Dominica

Natural Hazards - Small island developing states (SIDS) face high vulnerability to natural hazards; thus, understanding risk perception in SIDS is an essential step toward reducing vulnerability. A...     

Large‐scale climatic influences on precipitation and discharge for a British river basin

This article aims to identify the large‐scale climate variables that yield significant statistical relationships with precipitation and discharge for a British river basin (Dyfi). Ranked correlation analysis was performed between gridded ERA‐40 atmospheric data and Dyfi precipitation and discharge for individual months. Precipitation and discharge demonstrate significant negative correlation with mean sea level pressure (MSLP). Strongest MSLP correlation areas move from north of Britain in winter to central Britain in summer; this shift is associated with a displacement of geopotential (Z) and zonal wind (U). Movement of significant correlation regions (not captured by the North Atlantic Oscillation Index) highlights the dynamic nature of precipitation and river flow generating weather systems throughout the year. Existence of strong significant correlation shows potential for exploiting large‐scale climate variables in forecasting precipitation and river flow in Britain. Copyright © 2010 John Wiley & Sons, Ltd.     

The western end of the Eoalpine High‐Pressure Belt (Texel unit,South Tyrol / Italy)

Eclogites in the Texel Unit (Eastern Alps; South Tyrol, Italy) represent the westernmost outcrops of the E–W striking Eoalpine High‐Pressure Belt (EHB). East of the Tauern Window, the EHB forms part of a Cretaceous intracontinental south‐dipping subduction/collision zone; however, the same nappe stack displays a northwest dip at its western end. This prominent change in dip direction gave rise to discussions on the general setting of the Eoalpine collision. Based on our own observations and literature data, we present a new tectonic model for the western end of the EHB. Due to the special situation of this area at the tip of the Southalpine indenter, originally south(east) dipping structures became overturned, and former thrusts appear as normal faults (e.g. Schneeberg fault zone) while former normal faults presently display thrust geometries (e.g. Jaufen fault). Thus, we explain the current configuration with a coherent Eoalpine subduction direction.     

Assessing global Sentinel-2 coverage dynamics and data availability for operational Earth observation (EO) applications using the EO-Compass

ABSTRACT

Sentinel-2 scenes are increasingly being used in operational Earth observation (EO) applications at regional, continental and global scales, in near-real time applications, and with multi-temporal approaches. On a broader scale, they are therefore one of the most important facilitators of the Digital Earth. However, the data quality and availability are not spatially and temporally homogeneous due to effects related to cloudiness, the position on the Earth or the acquisition plan. The spatio-temporal inhomogeneity of the underlying data may therefore affect any big remote sensing analysis and is important to consider. This study presents an assessment of the metadata for all accessible Sentinel-2 Level-1C scenes acquired in 2017, enabling the spatio-temporal coverage and availability to be quantified, including scene availability and cloudiness. Spatial exploratory analysis of the global, multi-temporal metadata also reveals that higher acquisition frequencies do not necessarily yield more cloud-free scenes and exposes metadata quality issues, e.g. systematically incorrect cloud cover estimation in high, non-vegetated altitudes. The continuously updated datasets and analysis results are accessible as a Web application called EO-Compass. It contributes to a better understanding and selection of Sentinel-2 scenes, and improves the planning and interpretation of remote sensing analyses.     

Regional climate and atmospheric circulation controls on the discharge of two British rivers, 1974–97

Summary ¶The dependence of the discharge (Q) of two contrasting UK rivers (Itchen, Ewe) on concurrent and lagged regional climate (RC) and atmospheric circulation (AC) variations was assessed over the period 1974–97. RC variables used were temperature and precipitation; the AC indicators used were 850hPa water vapour flux anomalies (VF) at five western European stations, and the Arctic (AOI) and North Atlantic Oscillation (NAOI) indices. Correlation analyses were performed to assess Q-RC and Q-AC relationships before two sets of multiple linear regression models were developed to specify monthly Q values from RC and AC. Q-RC associations were generally stronger and more seasonally consistent than Q-AC relationships, with the flow of the Itchen (southern England) and Ewe (northern Scotland) being most sensitive to temperature (TEMP) and precipitation (PPT) respectively. In most months, discharge values of both rivers were positively associated to zonal and vector VF anomalies over the British Isles and northern France, but inversely related to vector VF over Iceland. The AOI and NAOI were significantly related to the Ewes flow only; relationships were strongest in the winter half-year. Monthly AC regression models explained 14.8–81.0% (25.0–90.9%) of the discharge variability of the Itchen (Ewe). Strong AC forcing of the Itchens discharge is confined to the winter (DJF), since the Itchens direct meteorological signal is attenuated by groundwater dynamics in other seasons. Analysis of anomalous flow periods (e.g. 1988–92 and 1995–7) revealed that discharge does not always respond in the same manner to a given RC/AC forcing, as the relationships themselves vary inter-annually as well as between the two rivers.     

Development of spatial regression models for predicting summer river temperatures from landscape characteristics: Implications for land and fisheries management

There is increasing demand for models that can accurately predict river temperature at the large spatial scales appropriate to river management. This paper combined summer water temperature data from a strategically designed, quality controlled network of 25 sites, with recently developed flexible spatial regression models, to understand and predict river temperature across a 3,000 km² river catchment. Minimum, mean and maximum temperatures were modelled as a function of nine potential landscape covariates that represented proxies for heat and water exchange processes. Generalised additive models were used to allow for flexible responses. Spatial structure in the river network data (local spatial variation) was accounted for by including river network smoothers. Minimum and mean temperatures decreased with increasing elevation, riparian woodland and channel gradient. Maximum temperatures increased with channel width. There was greater between‐river and between‐reach variability in all temperature metrics in lower‐order rivers indicating that increased monitoring effort should be focussed at these smaller scales. The combination of strategic network design and recently developed spatial statistical approaches employed in this study have not been used in previous studies of river temperature. The resulting catchment scale temperature models provide a valuable quantitative tool for understanding and predicting river temperature variability at the catchment scales relevant to land use planning and fisheries management and provide a template for future studies.     

New insights into the heterogeneity of the Tagish Lake meteorite: Soluble organic compositions of variously altered specimens

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ¹³C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.     

Potassium isotopic compositions of enstatite meteorites

Enstatite chondrites and aubrites are meteorites that show the closest similarities to the Earth in many isotope systems that undergo mass‐independent and mass‐dependent isotopic fractionations. Due to the analytical challenges to obtain high‐precision K isotopic compositions in the past, potential differences in K isotopic compositions between enstatite meteorites and the Earth remained uncertain. We report the first high‐precision K isotopic compositions of eight enstatite chondrites and four aubrites and find that there is a significant variation of K isotopic compositions among enstatite meteorites (from ?2.34‰ to ?0.18‰). However, K isotopic compositions of nearly all enstatite meteorites scatter around the bulk silicate earth (BSE) value. The average K isotopic composition of the eight enstatite chondrites (?0.47 ± 0.57‰) is indistinguishable from the BSE value (?0.48 ± 0.03‰), thus further corroborating the isotopic similarity between Earth's building blocks and enstatite meteorite precursors. We found no correlation of K isotopic compositions with the chemical groups, petrological types, shock degrees, and terrestrial weathering conditions; however, the variation of K isotopes among enstatite meteorite can be attributed to the parent‐body processing. Our sample of the main‐group aubrite MIL 13004 is exceptional and has an extremely light K isotopic composition (δ⁴¹K = ?2.34 ± 0.12‰). We attribute this unique K isotopic feature to the presence of abundant djerfisherite inclusions in our sample because this K‐bearing sulfide mineral is predicted to be enriched in ³⁹K during equilibrium exchange with silicates.     

The effect of pH and ionic strength on proton adsorption by the thermophilic bacterium Anoxybacillus flavithermus

Numerous studies have utilized surface complexation theory to model proton adsorption behaviour onto mesophilic bacteria. However, few experiments, to date, have investigated the effects of pH and ionic strength on proton interactions with thermophilic bacteria. In this study, we characterize proton adsorption by the thermophile Anoxybacillus flavithermus by performing acid-base titrations and electrophoretic mobility measurements in NaNO₃ (0.001-0.1 M). Equilibrium thermodynamics (Donnan model) were applied to describe the specific chemical reactions that occur at the water-bacteria interface. Acid-base titrations were used to determine deprotonation constants and site concentrations for the important cell wall functional groups, while electrophoretic mobility data were used to further constrain the model. We observe that with increasing pH and ionic strength, the buffering capacity increases and the electrophoretic mobility decreases. We develop a single surface complexation model to describe proton interactions with the cells, both as a function of pH and ionic strength. Based on the model, the acid-base properties of the cell wall of A. flavithermus can best be characterized by invoking three distinct types of cell wall functional groups, with pK_a values of 4.94, 6.85, and 7.85, and site concentrations of 5.33, 1.79, and 1.42 × 10⁻⁴ moles per gram of dry bacteria, respectively. A. flavithermus imparts less buffering capacity than pure mesophilic bacteria studied to date because the thermophile possesses a lower total site density (8.54 × 10⁻⁴ moles per dry gram bacteria).