The western end of the Eoalpine High‐Pressure Belt (Texel unit,South Tyrol / Italy)

Eclogites in the Texel Unit (Eastern Alps; South Tyrol, Italy) represent the westernmost outcrops of the E–W striking Eoalpine High‐Pressure Belt (EHB). East of the Tauern Window, the EHB forms part of a Cretaceous intracontinental south‐dipping subduction/collision zone; however, the same nappe stack displays a northwest dip at its western end. This prominent change in dip direction gave rise to discussions on the general setting of the Eoalpine collision. Based on our own observations and literature data, we present a new tectonic model for the western end of the EHB. Due to the special situation of this area at the tip of the Southalpine indenter, originally south(east) dipping structures became overturned, and former thrusts appear as normal faults (e.g. Schneeberg fault zone) while former normal faults presently display thrust geometries (e.g. Jaufen fault). Thus, we explain the current configuration with a coherent Eoalpine subduction direction.     

Development of spatial regression models for predicting summer river temperatures from landscape characteristics: Implications for land and fisheries management

There is increasing demand for models that can accurately predict river temperature at the large spatial scales appropriate to river management. This paper combined summer water temperature data from a strategically designed, quality controlled network of 25 sites, with recently developed flexible spatial regression models, to understand and predict river temperature across a 3,000 km² river catchment. Minimum, mean and maximum temperatures were modelled as a function of nine potential landscape covariates that represented proxies for heat and water exchange processes. Generalised additive models were used to allow for flexible responses. Spatial structure in the river network data (local spatial variation) was accounted for by including river network smoothers. Minimum and mean temperatures decreased with increasing elevation, riparian woodland and channel gradient. Maximum temperatures increased with channel width. There was greater between‐river and between‐reach variability in all temperature metrics in lower‐order rivers indicating that increased monitoring effort should be focussed at these smaller scales. The combination of strategic network design and recently developed spatial statistical approaches employed in this study have not been used in previous studies of river temperature. The resulting catchment scale temperature models provide a valuable quantitative tool for understanding and predicting river temperature variability at the catchment scales relevant to land use planning and fisheries management and provide a template for future studies.     

Spatial variability of precipitation regimes over Turkey

Abstract

This study aims to predict the daily precipitation from meteorological data from Turkey using the wavelet—neural network method, which combines two methods: discrete wavelet transform (DWT) and artificial neural networks (ANN). The wavelet—ANN model provides a good fit with the observed data, in particular for zero precipitation in the summer months, and for the peaks in the testing period. The results indicate that wavelet—ANN model estimations are significantly superior to those obtained by either a conventional ANN model or a multi linear regression model. In particular, the improvement provided by the new approach in estimating the peak values had a noticeably high positive effect on the performance evaluation criteria. Inclusion of the summed sub-series in the ANN input layer brings a new perspective to the discussions related to the physics involved in the ANN structure.     

Synthetic ANaB(Na x Li1 − x Mg1)CMg5Si8O22(OH)2 (with x = 0.6, 0.2 and 0) P21/m amphiboles at high pressure: a synchrotron infrared study

The high-pressure behavior of three synthetic amphiboles crystallized with space group P2₁/m at room conditions in the system Li₂O–Na₂O–MgO–SiO₂–H₂O has been studied by in situ synchrotron infrared absorption spectroscopy. The amphiboles have compositions ^ANa ^B(Na _x Li_1 − x Mg₁) ^CMg₅ Si₈ O₂₂(OH)₂ with x = 0.6, 0.2 and 0.0, respectively. The high-P experiments up to 32 GPa were carried out on the U2A beamline at Brookhaven National Laboratory (NY, USA) using a diamond anvil cell under non-hydrostatic or quasi-hydrostatic conditions. The two most intense absorption bands in the OH-stretching infrared spectra can be assigned to two non-equivalent O–H dipoles in the P2₁/m structure, bonded to the same local environment ^M1M3Mg₃–OH–^ANa, and pointing toward two differently kinked tetrahedral rings. In all samples these bands progressively merge to give a unique symmetrical absorption with increasing pressure, suggesting a change in symmetry from P2₁/m to C2/m. The pressure at which the transition occurs appears to be linearly correlated to the aggregate B-site dimension. The infrared spectra collected for amphibole ^B(Na_0.2Li_0.8Mg₁) in the frequency range 50 to 1,400 cm⁻¹ also show a series of changes with increasing pressure. The data reported here support the inference of Iezzi et al. (Am Miner 91:479–482, 2006a) regarding a new high-pressure amphibole polymorph.     

Floods in the Southern Alps of New Zealand: the importance of atmospheric rivers

Extremely high precipitation occurs in the Southern Alps of New Zealand, associated with both orographic enhancement and synoptic‐scale weather processes. In this study, we test the hypothesis that atmospheric rivers (ARs) are a key driver of floods in the Southern Alps of New Zealand. Vertically integrated water vapour and horizontal water vapour transport, and atmospheric circulation, are investigated concurrently with major floods on the Waitaki River (a major South Island river). Analysis of the largest eight winter maximum floods between 1979 and 2012 indicates that all are associated with ARs. Geopotential height fields reveal that these ARs are located in slow eastward moving extratropical cyclones, with high pressure to the northeast of New Zealand. The confirmation of ARs as a contributor to Waitaki flooding indicates the need for their further exploration to better understand South Island hydrometeorological extremes. Copyright © 2016 John Wiley & Sons, Ltd.     

On the migration of precursors of strong earthquakes

It is found that perturbations presumedly associated with swarms, the B patterns and the BG pattern precursors of strong earthquakes in New Zealand, California and Apennines, propagate in the crust of the Earth with a velocity of the order of cm¹. The hypothesis that a single travelling elastic perturbation causes a set of precursors of the same strong earthquake is discussed and it is concluded that each precursor is associated with a different perturbation.     

Hydrological influences on hyporheic water quality: implications for salmon egg survival

The spatial and temporal variability of groundwater–surface‐water (GW–SW) interactions was investigated in an intensively utilized salmon spawning riffle. Hydrochemical tracers, were used along with high‐resolution hydraulic head and temperature data to assess hyporheic dynamics. Surface and subsurface hydrochemistry were monitored at three locations where salmon spawning had been observed in previous years. Temperature and hydraulic head were monitored in three nests of three piezometers located to characterize the head, the run and the tail‐out of the riffle feature. Hydrochemical gradients between surface and subsurface water indicated increasing GW influence with depth into the hyporheic zone. Surface water was characterized by high dissolved oxygen (DO) concentrations, low alkalinity and conductivity. Hyporheic water was generally characterized by high levels of alkalinity and conductivity indicative of longer residence times, and low DO, indicative of reducing conditions. Hydrochemical and temperature gradients varied spatially over the riffle in response to changes in local GW–SW interactions at the depths investigated. Groundwater inputs dominated the head and tail of the riffle. The influence of SW increased in the area of accelerating flow and decreasing water depth through the run of the riffle. Temporal GW–SW interactions also varied in response to changing hydrological conditions. Gross changes in hyporheic hydrochemistry were observed at the weekly scale in response to changing flow conditions and surface water inputs to the hyporheic zone. During low flows, caused by freezing or dry weather, hyporheic hydrochemistry was dominated by GW inputs. During higher flows hyporheic hydrochemistry indicated that SW contributions increased. In addition, high‐resolution hydraulic head data indicated that rapid changes in GW–SW interactions occurred during hydrological events. The spatial, and possibly the temporal, variability of GW–SW interactions had a marked effect on the survival of salmon ova. It is concluded that hyporheic dynamics and their effect on stream ecology should be given increased consideration by fisheries and water resource managers. Copyright © 2004 John Wiley & Sons, Ltd.     

The remarkable Re–Os chronometer in molybdenite: how and why it works

The Re–Os (rhenium–osmium) chronometer applied to molybdenite (MoS₂) is now demonstrated to be remarkably robust, surviving intense deformation and high‐grade thermal metamorphism. Successful dating of molybdenite is dependent on proper preparation of the mineral separate and analysis of a critical quantity of molybdenite, unique to each sample, such that recognized spatial decoupling of ¹⁸⁷Re parent and ¹⁸⁷Os daughter within individual molybdenite crystals is overcome. Highly precise, accurate and reproducible age results are derived through isotope dilution and negative thermal ion mass spectrometry (ID‐NTIMS). Spatial decoupling of parent–daughter precludes use of the laser ablation ICP‐MS microanalytical technique for Re–Os dating of molybdenite. The use of a reference or control sample is necessary to establish laboratory credibility and for interlaboratory comparisons. The Rb–Sr, K–Ar and ⁴⁰Ar/³⁹Ar chronometers are susceptible to chemical and thermal disturbance, particularly in terranes that have experienced subsequent episodes of hydrothermal/magmatic activity, and therefore should not be used as a basis for establishing accuracy in Re–Os dating of molybdenite, as has been done in the past. Re–Os ages for molybdenite are almost always in agreement with observed geological relationships and, when available, with zircon and titanite U–Pb ages. For terranes experiencing multiple episodes of metamorphism and deformation, molybdenite is not complicated by overgrowths as is common for some minerals used in U–Pb dating (e.g. zircon, monazite, xenotime), nor are Re and Os mobilized beyond the margins of individual crystals during solid‐state recrystallization. Moreover, inheritance of older molybdenite cores, incorporation of common Os, and radiogenic Os loss are exceedingly rare, whereas inheritance, common Pb and Pb loss are common complications in U–Pb dating techniques. Therefore, molybdenite ages may serve as point‐in‐time markers for age comparisons.