Eutrophication assessment of the Baltic Sea Protected Areas by available data and GIS technologies

Concerning increased degradation of marine ecosystems, there is a great political and institutional demand for an array of different tools to restore a good environmental status. Thereby, eutrophication is acknowledged as one of the major human induced stressors which has to be monitored and reduced. The present study concentrates on an assessment of the eutrophication status of the Baltic Sea Protected Areas by use of available data and GIS technologies. Two geodata layers were used for analysis: (1) a map on the eutrophication status of the Baltic Sea generated by the Helsinki Commission applying the HELCOM Eutrophication Assessment Tool (HEAT), and (2) modelled data on atmospheric nitrogen deposition made available by the European Monitoring and Evaluation Programme (EMEP). The results yielded comprehensive and conclusive data indicating that most of the BSPAs may be classified as being 'affected by eutrophication' and underlining the need to decrease the overall emissions of nutrients.     

Changes in the biota and sediments of glacial Lake Koźmin, Poland, during the late Saalian (Illinoian)

Upper Saalian (Illinoian) glaciolacustrine deposits in central Poland, preserved in a tectonic graben, were exposed in an opencast lignite mine and investigated using sedimentological and micro-paleontological methods. The extraglacial lake sediments provide the first records of late Saalian cladoceran communities in central Europe, recovered from glaciolacustrine deposits. Sedimentation was dominated by a supply of clastics that fluctuated with the seasons, forming rhythmites. In addition to seasonal cyclicity, sedimentary and environmental conditions changed every several years to decades, with periods of increased inflow to the lake delivering sandy material, and periods of almost stagnant water dominated by suspension settling. The sediments contain Cladocera assemblages that indicate the lake was initially deep, oligotrophic, and filled with moderately cold water. Changes in Cladocera community composition and abundance were perhaps responses to climate seasonality. Zones without Cladocera were associated with seasons of higher inflow and sediment supply, and directly or indirectly, with tectonic activity in the graben. Earthquakes, documented by the presence of seismites, caused not only deformation of unconsolidated lake-bottom sediments, but possibly also changes in habitat characteristics. Combined sedimentological and biological data were used to infer the lake’s history and show that deposits of glaciolacustrine lakes can be used as indicators of past ecological and climate changes.     

Ice table depth variability near small rocks at the Phoenix landing site, Mars: A pre-landing assessment

We combine thermal simulations of ground ice stability near small rocks with extrapolations of the abundance of rocks at the Phoenix landing site based on HiRISE rock counts to estimate the degree of ice table depth variability within the 3.8 m² workspace that can be excavated during the mission. Detailed predictions of this kind are important both to test current ground-ice theory and to optimize soil investigations after landing. We find that Phoenix will very likely have access to at least one rock in the diameter range 5 cm to 1 m. Our simulations, which assume the ice to be in diffusive equilibrium with atmospheric water vapor, indicate that all rocks in this size range are associated with an annulus of deep ice-free soil. Ice table depth variability of 1-5 cm is very likely at the landing site due to the presence of small rocks. Further, there are scenarios in which Phoenix might exploit the presence of individual large rocks and/or the arrangement of small rocks to sample soils at depths >10 cm below the average depth predicted from orbit (∼4 cm). Scale analysis to constrain uncertainties in simulation results indicates that estimates of maximum depths may be somewhat conservative and that ice table depressions associated with individual rocks could be deeper and laterally more extended than indicated by formal predictions by mm to cm.     

Vesta and the HED meteorites: Mid‐infrared modeling of minerals and their abundances

Abstract— We demonstrate that the use of an established spectral deconvolution algorithm with mid‐infrared spectral libraries of mineral separates of varying grain sizes is capable of identifying the known mineral compositions and abundances of a selection of howardite, eucrite, and diogenite (HED) meteorite samples. In addition, we apply the same technique to mid‐infrared spectral emissivity measurements of Vesta that have been obtained from Cornell's Mid‐Infrared Asteroid Spectroscopy (MIDAS) Survey and the Infrared Space Observatory (ISO). Each Vesta measurement was made over a different range of longitudes. Our spectral deconvolution results to the Vesta spectra corroborate that Vesta's surface is howardite or eucrite‐like in composition and heterogeneous across its surface. The spectral fits produced by the linear deconvolution algorithm yields good results for the HED samples of known composition, thus giving us a high degree of confidence that our results for Vesta are valid.     

Analysis of three years of boundary layer observations over the Gulf of Mexico and its shores

Boundary layer observations were made over the Gulf of Mexico over a 3-year period in order to develop and test methods for estimating surface fluxes and boundary layer wind fields. In addition to routinely available buoy and CMAN surface data, six 915 MHz radar wind profilers (RWPs) and RASS profilers were mounted on oil platforms and on the shore. Estimates of surface momentum, sensible heat, and latent heat fluxes have been made from the surface observations using the COARE software. Simulations by the National Weather Service's Eta meteorological model are compared with the observations of surface fluxes and wind profiles. The boundary layer is found to be unstable over 90% of the time, and latent heat fluxes are about five to ten times larger than sensible heat fluxes, as usually found over tropical oceans. Eta model simulations of surface fluxes are within about ±50% of COARE estimates of the fluxes based on surface observations. Most of the time, COARE-derived fluxes at 11 sites are within a factor of two of each other at any given hour. In multi-day case studies, COARE calculations are found to agree with Eta model simulations of these fluxes and parameters within a factor of two most of the time. Eta model simulations of wind speeds in the boundary layer tend to exceed the RWP observations by 1–2 m s⁻¹ near shore and by 2–6 m s⁻¹ at distances of 100–200 km offshore.     

Along-wind dispersion of puffs released in a built-up urban area

The SF₆ gas tracer observations for puffs released near the ground during the Joint Urban 2003 (JU2003) urban dispersion experiment in Oklahoma City have been analysed. The JU2003 observations, at distances of about 100–1,100 m from the source, show that, at small times, when the puff is still within the built-up downtown domain, the standard deviation of the concentration time series, σ_t, is influenced by the initial puff spread due to buildings near the source and by hold-up in the wakes of large buildings at the sampler locations. This effect is parameterised by assuming an initial σ_to of about 42 s, leading to a comprehensive similarity formula: σ_t = 42 + 0.1t. The second term, 0.1t, is consistent with an earlier similarity relation, σ_t = 0.1t, derived from puff observations in many experiments over rural terrain. The along-wind dispersion coefficient, σ_x, is assumed to equal σ_t u, in which u is the puff speed calculated as the distance from the source to the sampler, x, divided by the time after the release that the maximum concentration is observed at the sampler. σ_x can be expressed as σ_x = σ_xo + 0.14x, with the initial σ_xo of 45 m. This initial σ_xo agrees with the suggestion of an initial plume spread of about 40 m, made by McElroy and Pooler from analysis of the 1960s’ St. Louis urban dispersion experiment. The puff speeds, u, are initially only about 20% of the observed wind speed, averaged over about 80 street-level and rooftop anemometers in the city, but approach the mean observed wind speed as the puffs grow vertically. The scatter in the σ_t data is about ± a factor of two or three at any given travel time. The maximum σ_t is about 250 s, and the maximum duration of the puff over the sampler, Dt, sometimes called the retention time, is about 1,100 s or 18 min for these puffs and distances.     

Comparison of Monte Carlo simulation methods for the calculation of the nucleation barrier of argon

We compare two molecular Monte Carlo simulation methods, the discrete summation method and the growth/decay method, which calculate the vapor-liquid nucleation free energy barrier by simulating isolated clusters of fixed size without the surrounding vapor. The methods are applied to calculations of nucleation barriers of Lennard–Jones argon at 60 K and 80 K. Both of these methods are computationally efficient, as only isolated clusters without the surrounding vapor are simulated, and the methods can be applied with any given cluster definition. They give equivalent results to other methods where the vapor phase is also included. The discrete summation method is based on the calculation of the difference in free energies between two systems containing an n-cluster and an (n − 1)-cluster plus one non-interacting (free) molecule. We show that the configurational space is not equivalent in the two systems. Hence, there has to be an additional term in the free energy calculation that accounts for several kT in magnitude. In contrast to previous studies we also show that it is not correct to prevent the overlap of the non-interacting molecule and another molecule by a zero or an arbitrarily small repulsive potential, but with a small excluded space around the free molecule.     

Radial Velocities of Six Early Type Evolved Stars

Many early-type main sequence stars are known spectroscopic binaries, while early type spectroscopic binaries with evolved components are rather rare and well-determined masses are available only in some cases. For this reason a program to study stars with suspected variable velocity among early-type evolved stars has been initiated some time ago. In the present paper 54 coudé spectra for a sub-group formed of six early-type stars, namely HD 7902, HD 28446, HD 42087, HD 187983, HD 195592 and HD 208501 have been measured and the results of these plates have been presented.     

Bromine as an indicator of oil migration in northern Iraqi oil fields

The Br content of oil varies systematically along the paths of oil migration in northern Iraqi oil fields, indicating that this element may be used as an indicator of oil movement. The variation in Br parallels that of V and Ni, and like these two elements it is concentrated in the asphaltene fraction of petroleum.