New equation to decipher the relationship between carbon isotopic composition of methane and maturity of gas source rocks

The identification of the origin and source of natural gas is always a difficult and hot issue.Hereinto,the maturity identification is one of the most important scientific problems.Many empirical equations have been established to decipher the relationship between the maturity of gas source rocks and the carbon isotopic composition of natural gas.However,these equations proposed often fail to identify the maturity of the source rocks correctly,which in turn prevents the identification of genetic types and source rocks of the natural gas because the petroliferous sedimentary basins in China are complex and diverse,with multiple sets of source rocks and different thermal history.In this paper,the oil-associated gas from the Permian lacustrine source rocks and the coal-derived gas from the Jurassic source rocks in Junggar and Turpan-Hami basins have been investigated to decipher the relationship between the maturity(vitrinite reflectance)of gas source rocks and the carbon isotopic composition of methane.The equations established areδ¹³C₁=25lgR_o-42.5 for oil-associated gas,andδ¹³C₁=25lgR_o-37.5 for coal-derived gas.These new equations are suitable for the maturity identification of source rocks in most petroliferous basins,and favorable for the identification of the genetic type and source of natural gas,which is very important to improve the geological theory of natural gas.     

Crystallographic and NMR studies on sterols from green alga Chaetomorpha basiretorsa Setchell

Chemical investigation of the ethanol extract of the marine green alga Chaetomorpha basiretorsa Setchell led to the isolation of a new sterol stigmast-4,28-dien-3α,6β-diol 1 in addition to the five known sterols of β-lawsaritol 2, saringosterol 3, 24-hydroperoxy-24-vinyl - cholesterol 4, β-stigmasterol 5, 29-hydroxystigmasta-5, 24 （28） -dien-3β-ol 6. Compounds were isolated by normal phase silica gel and Sephadex LH - 20 gel colum chromatography, reverse phase HPLC and recrystalization. Their structures were elucidated by spectroscopic methods including MS, IR 1D/2D NMR and X-ray analysis. Cytotoxicity of compounds was screened by using the standard MTF method. All these compounds were isolated from the green alga Chaetomorpha basiretorsa Setchell for the first time and they were inactive （50% inhibitory concentration was greater than 10 μg/cm^3） against KB, Bel -7402, PC - 3M, Ketr 3 and MCF-7 cell lines.     

漠斑牙鲆早期发育阶段的摄食与生长特性

2006年12月至2007年2月,在漳州市东山县华涛水产综合养殖场,采用生态学方法对人工培育的漠斑牙鲆仔、稚、幼鱼的摄食习性与生长特性进行了分析.结果表明,在水温为18.1～23℃时,仔鱼在孵出第6天开口摄食,开口饵料为褶皱臂尾轮虫(Bruchionus plicatilis),以后随着鱼体的生长,开始投喂卤虫无节幼体.对288尾仔、稚、幼鱼观察结果表明,其摄食率达83.0%,消化道饱满系数波动在0.9%～6.6%之间,日摄食指数在6.8%～29.6%;摄食具有明显的昼夜节律,一昼夜中仔鱼出现两个摄食高峰,分别出现在12:00和翌日08:00,稚鱼摄食高峰出现在10:00～14:00,幼鱼摄食高峰出现在12:00,但12:00～20:00均保持较高的摄食水平.仔、稚鱼夜间基本不摄食,幼鱼夜间有少量摄食.摄食量(y)与体重(W)的关系式为y=0.030 7W 0.050 5,全长(LT)与日龄(D)的关系式为LT=2.666 1e0.043 3D,体重(W)与日龄(D)的关系式为W=0.065e0.169 3D,全长(LT)与体重(W)的回归方程为W=0.001 8LT3.689 4.     

The black water around the Changjiang (Yangtze) Estuary in the spring of 2003

The Changjiang (Yangtze) Estuary is located in the East China Sea shelf with shallow water. Affected by the tide mixing and the runoff of the Changjiang River and the Qiantang River, the turbidity is very high. Generally, the water-leaving radiance is high in the turbid water because of the large particle scattering. Based on the in-situ data and ocean color remote sensing data of SeaWiFS, it was found that there was a black water region with the normalized water-leaving radiances less than 0.5 mW/(cm2·μm2·...     

Evaluation of the four potential Cretaceous-Paleogene (K-Pg) boundaries in the Nanxiong Basin based on evidences from volcanic activity and paleoclimatic evolution

Determining the location of the Cretaceous-Paleogene(K-Pg) boundary in terrestrial strata is highly significant for studying the evolution of terrestrial ecosystems at the end of the Cretaceous(especially the extinction of non-avian dinosaurs). At present, research on terrestrial K-Pg boundaries worldwide is concentrated in the middle and high latitudes, such as North America and Northeast China. Although many studies have also been carried out in the Nanxiong Basin, located at low latitudes(which has become the standard for dividing and comparing the continental K-Pg stratigraphy in China), many researchers have proposed four possible boundaries from different perspectives. Therefore, the exact location remains to be determined. In this study, the total mercury(Hg) content, environmental magnetism, geochemistry, and other parameters for the samples collected near the four boundaries were determined and compared with existing records. Results indicated that: 1) The total Hg content significantly increased in the upper part of the Zhenshui Formation and Pingling part of the Shanghu Formation with sharp fluctuations. As per latest dating results of Deccan Traps, the significantly high Hg value was attributed to the Deccan Traps eruption. Boundary 1 was located in the middle of the Hg anomaly interval, which was consistent with the relationship between the global K-Pg boundary and time of volcanic eruption. 2) The reconstructed paleoclimate evolution curve revealed that the red sediments in the basin recorded the late Maastrichtian warming event(66.2 Ma). Regarding the relationship between the four boundaries and this warming event, only boundary 1 was found to be closest to the real K-Pg boundary of the Nanxiong Basin.     

Analysis of the Decadal and Interdecadal Variations of the East Asian Winter Monsoon as Simulated by 20 Coupled Models in IPCC AR4

Using the output data of 20 coupled climate models used in IPCC AR4 and observational data from NCEP, the capability of the models to simulate the boreal winter climatology of the East Asian sea level pressure, 850-hPa wind, and surface air temperature; the decadal variations of the East Asian winter mon- soon (EAWM) intensity and EAWM-related circulation, and the interdecadal variations of EAWM-related circulation are systematically evaluated. The results indicate that 16 models can weakly simulate the declin- ing trend of the EAWM in the 1980s. More than half of the models produce relatively reasonable decadal variations of the EAWM-related circulation and the interdecadal di?erences of EAWM-related circulation between the boreal winters of 1960-1985 and 1986-1998, including the weakened Siberian high, Aleutian low, and East Asian trough, the enhanced Arctic oscillation and North Pacific oscillation, and a deepened polar vortex. It is found that the performance of the multi-selected-model ensemble in reproducing the spatial dis- tribution of the variations is encouraging, although the variational amplitudes are generally smaller than the observations. In addition, it is found that BCCR_BCM2.0, CGCM3.1_T63, CNRM_CM3, CSIRO_MK3.0, GISS-ER, INM_CM3.0, and MRI_CGCM2.3.2 perform well in every aspect     

拉斑玄武质岩浆极端分异之实例—Loch Ba环状岩墙的岩石学与地球化学

苏格兰西北部马尔地区Loch Ba环状岩墙系由条带状流纹溶结凝灰岩组成。该流纹岩含有大量暗色隐晶质包体。根据流纹岩及其暗色包体的结构构造特征、斑晶矿物及组合、含量、化学成分特征和全岩的常量元素变化特征，认为Loch Ba岩墙之深部存在着一强烈分带的岩浆房，岩浆房上部为流纹质岩浆，其下为强烈分带区，由英安质至底部至少是镁铁质安山岩浆组成。岩浆的分异结晶作用、深部岩浆对来自上部岩浆的捕获晶的同化作用及蚀变作用是造成岩石主要元素一系列变化的原因。     

Land use change in Bohai Rim: a spatial-temporal analysis

Land use change is one of the important aspects of global change[1-3]. The Bohai Rim is a hot spot of economic development in China, where land use changes remarkably. Analyzing land use change in this area is significant to the research of global change and regional sustainable land use. Although there has been much work undertaken on regional land use change in China, it was mainly on urban land use change[4-11], and few researches integrated remote sensing and GIS method. Based on data f…     

Karst Collapse Mechanism and Criterion for Its Stability

Karst collapse, caused by natural or artificial abstraction of groundwater, has been a focus of environmentalgeological problems for its ever-increasing hazardousness. The potential erosion theory and vacuum suction erosion theory, which reveal the origin of karst collapse macroscopically, are popularly accepted. However, a mathematic prediction criterion for karst collapse cannot be established only by these two theories. From a new perspective, this paper attempts to explain the microcosmic mechanism of karst collapse on the basis of these two theories. When the shear stress surpasses the shear strength of soil, a certain point or a certain plane in the unconsolidated soil covering karst caves will fail under the mechanical effects of water and air as well as its load-pressure, and with the increase of damaged points, a breaking plane appears and the soil on karst caves is completely damaged; as a result, the karst ground collapses. On the basis of the Mohr-Coulomb failure theory and previous studies,     

Numerical simulation of dynamic process of the Tangshan earthquake

In this paper, the new LDDA (Lagrangian Discontinuous Deformation Analysis) method is used in modeling the dynamic process of the MS=7.8 Tangshan earthquake on July 28, 1976 and obtain directly the dynamic and quasi-static dislocations, shear stress drops, fracture velocities of the Tangshan earthquake fault. The simulation shows that the slip history at each point of the fault is different. The displacement vectors at the concave side of the fault is greater than that of the convex side of the fault. The "over shoot" of the fault slip is greatest at the middle part of the fault and attenuates to its ends. The rupture velocities of the fault from the epicenter towards south-west and towards north-east are 3.08 m/s and 1.18 m/s, respectively, the average one is 2.13 m/s. The maximum dynamic and quasi-static dislocations are 7.1 m and 6.2 m respectively, the average quasi-static one on the fault is 4.5 m. The maximum dynamic and quasi-static shear stress drops are 8.1 MPa and 5.4 MPa, respectively, the average quasi-static shear stress drop is 3.9 MPa.We found that the rupture velocities and shear stress are related to the initial stress states of the fault.