Stable Isotopes and Halogen Geochemistry of the Huayuan Carbonate-hosted Pb-Zn Ore District, South China: Implications for the Salt Source of Ore-forming Fluids

The Huayuan Pb-Zn ore district in China, located in western Hunan Province, is a giant carbonate-hosted Pb-Zn ore district. The source of ore-forming brines in this ore district remains poorly constrained. Whether the highly saline brines are derived from evaporated seawater or dissolved evaporates continues to be intensely debated. Carbonate minerals associated with Pb-Zn mineralization have δ13CV-PDB and δ18OV-SMOW values ranging from ?5.55‰ to +1.35‰ (mean value of ?0.69‰; n = 14) and +16.28‰ to +25.05‰ (mean value of +20.22‰; n = 14), respectively. This indicates that carbonate minerals are dominantly formed from dissolved ore-hosted carbonate rocks. The δ34S values of sulfides range from +20.2‰ to +36.8‰, with an average value of +30.0‰ (n = 27). These results suggest that sulfur is predominantly derived from the thermochemical sulfate reduction of marine sulfate. The crush-leach analyzed solute data of fluid inclusions in sphalerite show the ore-forming fluids have Cl/Br molar ratios range from 118 to 384, and Na/Br molar ratios from 39 to 160 (n = 8). These Cl/Br ratios of hydrothermal fluid are much lower than those of seawater (657 to 564), but are consistent with bittern brines through early halite precipitation. We propose that ore-forming fluids are mainly derived from evaporitic basin brines, which leached base metals from the basement and/or country rocks. The brine then migrated to the basin margins through clastic rocks of basement and then precipitated sul?des by thermochemical sulfate reduction.     

Dynamic Response Analysis and Vibration Control for A Fixed-Bottom Offshore Wind Turbine Subjected to Multiple External Excitations

For the offshore wind turbines installed in earthquake areas, their operation is affected by seismic loads in addition to wind and wave loads. Therefore, it is necessary to study the dynamic responses and vibration control of the wind turbines. In previous studies, the structural responses of offshore wind turbines are usually investigated in the parked case, while the blade rotation effect is usually not considered. The evaluation on the structural responses may be inaccurate under this conditi...     

Petrogenesis and tectonic setting of granite porphyry in Keyouzhongqi area,Inner Mongolia

The authors studied the geochemistry,zircon U-Pb ages,Hf isotope of the granite porphyry and its petrogenesis and tectonic setting in the studied area． The zircon U-Pb dating indicates the formation of the gran- ite porphyry is in Early Cretaceous (125． 1 ±1． 5 Ma)． The granite porphyry has high-SiO2and alkali-rich fea- tures,which belongs to high-K calc-alkaline series rocks (A/CNK = 0． 95%--1． 25%)． The analyses of trace elements show the characteristics of a swallow-shaped ＲEE distribution pattern with enrichment in LＲEEs and most of LILEs and HFSEs,depletion in Ba,Sr,Nb,P and Ti,and especially strong depletion in Eu,which indicates the granite porphyry belongs to the aluminous A-type granite． Their εHf(t)range from 5． 94 to 8． 80 with Hf two-stage model ages (TDM2) of 620 Ma to 803 Ma． Combining with the regional tectonic background, we conclude that the source of the rocks is the new crust materials accreted from depleted mantle in Neoprotero- zoic and is the product of partial melting of middle and lower crustal rocks,which may be suffered from the dual impact of the subduction of the Palaeo-Pacific Ocean and the closure of the Mongol-Okhotsk Ocean．     

星载激光雷达卫星海面风场反演算法研究

The principal purpose of this paper is to extract entire sea surface wind＇s information from spaceborne lidar, and particularly to utilize a appropriate algorithm for removing the interference information due to white caps and subsurface water. Wind speeds are obtained through empirical relationship with sea surface mean square slopes. Wind directions are derived from relationship between wind speeds and wind directions im plied in CMOD5n geophysical models function （GMF）. Whitecaps backscattering signals were distinguished with the help of lidar depolarization ratio measurements and rectified by whitecaps coverage equation. Subsurface water backscattering signals were corrected by means of inverse distance weighted （IDW） from neighborhood non-singular data with optimal subsurface water backscattering calibration parameters. To verify the algorithm reliably, it selected NDBC＇s TAO buoy-laying area as survey region in camparison with buoys＇ wind field data and METOP satellite ASCAT of 25 km single orbit wind field data after temporal-spa tial matching. Validation results showed that the retrieval algorithm works well in terms of root mean square error （RMSE） less than 2m/s and wind direction＇s RMSE less than 21 degree.     

A Velocity Dealiasing Scheme for C-band Weather Radar Systems简

A dealiasing algorithm for radar radial velocity observed by C-band Doppler radars is presented as an extension of an existing S-band dealiasing algorithm. This has operational significance in that many portable and many commercial broadcast radars, as well as approximately one half of the Chinese weather radar network （CINRAD）, are C-band radars. With a wavelength of about 5 cm, the Nyquist interval of C-band radars is just about one half that of S-band radars （wavelength of about 10 cm） and thus has more velocity folding. The proposed algorithm includes seven modules to remove noisy data, find the starting radials, dealias velocities, and apply least squares error checking in both the radial and azimuth directions. The proposed velocity dealiasing method was applied to one widespread rain case and three strong convective cases from radars operating in China. It was found that, on average, 92.95% of the aliased radial velocity data could be correctly de-aliased by the algorithm, resulting in 96.65% of the data being valid.     

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.     

The Influence of Pan Evaporation Conditions on Na Cl crystallization

正1 Introduction Crystallization is one of important unit operations in the chemical production process,which requires not only the crystal product with high purity and yield,but also the available particle size of the crystal products to ensure product quality.Crystallization process is affected by     

Pb Isotopic Geochemistry of the Nuri Cu-W-Mo Deposit and Its Implications in Shannan Area, Southern Tibet

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An Evaluation of Phase Behaviors of the Oil-Gas-Water System in the Displacement of Crude Oil with CO2

CO₂ dissolution into an aqueous phase and water evaporation into a gaseous phase takes place during CO₂ injection into an oil reservoir. This study aims to evaluate the phase behaviors of the oil-gas-water system in the displacement of crude oil by CO₂. The composition of the JL oilfield in the northeast of China is taken as an example. The flash calculation of the oil-gas-water system was performed, based on the method presented by Li and Nghiem. The research re...