透明胞外聚合颗粒物碳输运新途径

目前大家普遍认为,透明胞外聚合颗粒物(Transparent Exopolymer Particles,TEP)因其独特的凝聚效应导致碳通量向海底输出。但是,近几年的研究表明TEP不仅影响了碳沉降途径,其本身能够悬浮甚至向海水表层迁移,导致其在海洋微表层(Surface Micro-layer, SML)积累,最终显著影响海洋表层碳通量。TEP和其他颗粒物聚集形成凝聚物后,其运动趋势则由凝聚物中TEP的含量占比,即最终颗粒物密度所决定。一个新的值得注意的现象是,密度低的TEP通过与其他微粒聚合形成表面活性物质(Surface-active Substances, SAS),会在海洋–大气界面形成薄膜,显著影响海–气CO₂交换通量,甚至对全球气候变化造成影响。     

海面溢油无人机高光谱遥感检测与厚度估算方法

海上溢油是海洋国家所面临的共同问题,但至今仍没有一种可靠实用的海上溢油准确识别和油量遥感监测方法。为此,本文以无人机高光谱遥感为手段,开展了海面溢油检测与厚度估算方法研究。实验中,通过搭建室外大型水槽溢油实验装置,获取了模拟真实海洋环境条件下不同溢油量的遥感和现场光谱数据,在此基础上,分析并提取了海上溢油特征光谱波段,给出了海上溢油高光谱检测模型;针对现场实验条件下水面油膜厚度难以测定的问题,设计了3种利用总体溢油量的油膜厚度估算模型。得到如下主要结论:（1）675 nm和699 nm是海上溢油检测的有效特征波段,但对极薄的油膜没有检测能力;（2）提出了归一化溢油指数模型、反比例模型和吸收基线模型等3种海上溢油油膜厚度估算模型,其中对于薄油膜（厚度≤ 5 μm）和厚油膜（厚度>50 μm）,反比例模型是溢油厚度反演的首选也是唯一选择。对于中厚度油膜,晴朗天气条件下,归一化溢油指数模型是油膜厚度反演的首选,同时反比例模型和溢油吸收基线模型也都有较好的反演能力,而在多云天气条件下,反比例模型效果最佳。     

基于神经网络模型的湛江湾水体有色溶解有机物的遥感估算

有色溶解有机物(Colored Dissolved Organic Matter, CDOM)是水体中重要的水质参数之一,是水色遥感的重要研究对象,如何构建适合特定区域的近海二类水体CDOM反演模型一直是国内外研究难点。本文利用2017年5月26～29日对南海西北部海域湛江湾20个站位采集的水样和测量的光谱资料,分析归一化遥感反射率与CDOM浓度a_g(400)的相关性,发现最大负相关系数出现在586nm处,选择580、585、590、595nm这四个波段处的归一化遥感反射率与a_g(400)建立了多元线性回归模型、BP(Back-Propagation)神经网络模型和RBF(Radial-Basis Function)神经网络模型,并与其他算法模型进行对比分析。结果发现, BP和RBF神经网络模型的平均相对误差和均方根误差均远小于多元线性回归模型和其他算法模型,神经网络模型的预测值与实测值拟合效果要优于多元线性回归模型。研究表明,神经网络模型更适合于湛江湾有色溶解有机物的遥感估算。     

浙江朱家尖岛东沙海滩对热带风暴“娜基莉”的响应及风暴后的恢复

海滩对风暴的响应及风暴后海滩的恢复过程一直以来都是国内外海滩研究的热点。本文通过对浙江舟山市朱家尖岛东沙海滩地形地貌的现场调查,对比分析了热带风暴"娜基莉"影响下东沙海滩剖面的蚀积变化,探讨了海滩在热带风暴发生后的恢复情况。结果表明,在"娜基莉"影响期间,因风暴浪为向岸浪,东沙海滩几乎遭受全线侵蚀,12个剖面单宽侵蚀总量为73.46 m3/m,其中海滩直线段较两个遮蔽段侵蚀显著。由于海滩在风暴前进方向的左侧,且"娜基莉"距东沙较远,使得东沙海滩普遍侵蚀但强度较小。东沙海滩在热带风暴后的恢复过程中,不同部位的地貌调整和冲淤变化不同,下岬角遮蔽段基本趋于稳定,直线段和上岬角遮蔽段在恢复过程中因受海滩季节性调整的影响呈现持续侵蚀。     

底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。     

Authigenic iron oxide formation in the estuarine mixing zone of the Yangtze River

Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.     

中国南海北部珠江口-琼东南盆地钻井岩屑地球化学特征及深水区天然气聚集特征

The Qiongdongnan Basin and Zhujiang River(Pearl River) Mouth Basin, important petroliferous basins in the northern South China Sea, contain abundant oil and gas resource. In this study, on basis of discussing impact of oil-base mud on TOC content and Rock-Eval parameters of cutting shale samples, the authors did comprehensive analysis of source rock quality, thermal evolution and control effect of source rock in gas accumulation of the Qiongdongnan and the Zhujiang River Mouth Basins. The contrast analysis of TOC contents and Rock-Eval parameters before and after extraction for cutting shale samples indicates that except for a weaker impact on Rock-Eval parameter S_2, oil-base mud has certain impact on Rock-Eval S_1, Tmax and TOC contents. When concerning oil-base mud influence on source rock geochemistry parameters, the shales in the Yacheng/Enping,Lingshui/Zhuhai and Sanya/Zhuhai Formations have mainly Type Ⅱ and Ⅲ organic matter with better gas potential and oil potential. The thermal evolution analysis suggests that the depth interval of the oil window is between 3 000 m and 5 000 m. Source rocks in the deepwater area have generated abundant gas mainly due to the late stage of the oil window and the high-supper mature stage. Gas reservoir formation condition analysis made clear that the source rock is the primary factor and fault is a necessary condition for gas accumulation. Spatial coupling of source, fault and reservoir is essential for gas accumulation and the inside of hydrocarbon-generating sag is future potential gas exploration area.     

Heterogeneous Gravity Data Fusion and Gravimetric Quasigeoid Computation in the Coastal Area of China

ABSTRACT

Different types of gravity observations are available over coastal areas. The main challenge for coastal geoid determination is the proper fusion of heterogeneous gravity data including land, shipborne, airborne, and altimetry-derived gravity data. This paper describes the gravity data fusion and the computation of the gravimetric quasigeoid in the coastal area of mainland China. An iterative procedure of the weighted least-squares prediction based on rectangular harmonic functions is used for merging the land, altimetric, shipborne, and airborne gravity data. Applying the analytical continuation method in Molodensky's theoretic frame, the merged gravity data are then used to determine the gravimetric quasigeoid model by using the generalized Stokes' integral in a remove-compute-restore fashion. The gravimetric quasigeoid model is compared with the height anomalies determined at 662 GPS leveling points over the coastal region of mainland China, where both the geodetic height and the normal height are known. The standard deviations of the differences in the coastal provinces range from 1.8 to 4.4 cm. For the entire computation area, the mean and standard deviation of the differences are 27.9 and 3.9 cm, respectively.     

Field study of set-up effect in open-ended PHC pipe piles

Large-scale field tests were conducted to study set-up effect in open-ended prestressed high-strength concrete pipe piles jacked into stratified soil. Four open-ended prestressed high-strength concrete pipe piles with 13 and 18 m in embedment depth were fully instrumented with fiber Bragg grating sensors and installed. Several restrike dynamic tests were performed on each test pile, with the time interval from 21.5 to 284 hours after installation. Static loading tests (SLTs) were later performed on each test pile at 408 hours after installation to substantiate the dynamic tests. Changes with time in pile bearing capacity and in the shaft and toe resistances were studied based on the results of the pile tests. The development of shaft resistance set-up in different layers was studied in particular. It was found that set-up effect in the shaft resistance is significant and the toe resistance increment was minor. The overall set-up factor of total bearing capacity was found to range from 0.09 to 0.53, and the set-up effect of friction pile is much larger than the end bearing pile. More significant set-up in shaft resistance was observed in fill and alluvium layer. The dimensionless set-up factor A for shaft resistance in marine deposits ranges from 0.5 to 1.43, and it contributes the most to the shaft resistance as the shaft resistance in marine deposits is higher.     

Potential Seismic Risk in Taiwan Strait Region

GPS observation indicates that the Fujian coastal region of China mainland, the region of Taiwan Strait and northern Taiwan island all show a generally homogenous horizontal motion with weak deformation. Historical earthquake record over more than 800 years and modern instrumental data reveal that there is potential seismic risk in and around Taiwan Strait region. After the National Seismic Zoning Map of China (2001) the expected seismic risk in northern part of the Taiwan Strait is lower than that in middle and southern part. The suggested northern route of the Taiwan Strait passage project seems to be relatively save seismically.