Organization of amphiphiles, Part VIII: Role of polyoxyethylated alkylphenols in optimizing the beneficiation of hydrophilic mineral

The floatability of silica has been determined by adsorbing various concentrations of a series of polyoxyethylated nonyl and octyl alkyl phenols of varying oxyethylene units (10–40 units) to investigate the role of adsorbed layer. It is seen that the floatability of silica increases with increase in concentration till a maximum of  90% in premicellar region and then decrease to minimum of 40–45% in all cases in spite of the significant differences in adsorption densities. Zeta potential measurement reveals that a thin oxyethylene layer is formed at silica–water interface masking silica surface (Pramila K. Misra, P. Somasundaran, J. Surf. Deterg., Vol. 7, 2004, 373). This layer with oxyethylene units lying on silica surface and alkyl chain dangling to the bulk solution provides the same extent of hydrophobicity. The decrease in flotation recovery has been attributed to increase in the solvent hydrophobicity due to formation of premicellar aggregates and micelles.     

A comparative evaluation of groundwater suitability for irrigation and drinking purposes in two intensively cultivated districts of Punjab, India

Punjab is the most cultivated state in India with the highest consumption of fertilizers. Patiala and Muktsar districts are two agricultural dominated districts of Punjab located in extreme south-east and south-west of the state. This paper highlights temporal variations of the groundwater quality and compares its suitability for irrigation and drinking purpose in these two districts. Water samples were collected in March and September 2003, representing the pre-monsoon and post-monsoon seasons, respectively. Water samples were analysed for almost all major cations, anions, dissolved heavy metals and turbidity. Parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, total hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated on the basis of chemical data. A questionnaire was also used to investigate perception of villagers on taste and odour. Comparison of the concentration of the chemical constituents with WHO (world health organization) drinking water standards of 2004 and various classifications show that present status of groundwater in Patiala is better for irrigation and drinking purposes except for a few locations with a caution that it may deteriorate in near future. In Muktsar, groundwater is not suitable for drinking. Higher total hardness (TH) and total dissolved solids at numerous places indicate the unsuitability of groundwater for drinking and irrigation. Results obtained in this forms baseline data for the utility of groundwater. In terms of monsoon impact, Patiala groundwater shows dilution and flushing but Muktsar samples show excessive leaching of different chemical components into the groundwater leading to the enrichment of different anions and cations indicating pollution from extraneous sources. No clear correlation between the quality parameters studied here and perceived quality in terms of satisfactory taste response were obtained at electrical conductivity values higher than the threshold minimum acceptable value.     

Suitability Analysis of Groundwater Quality for Domestic and Irrigation Usage in Yamuna Nagar District, India: A GIS Approach

The main source to fulfill the enormous needs of water both for domestic and agricultural purposes in the densely cultivated region of Yamuna Nagar district of Haryana (India) is the water under earth. Since enough quantity of good quality water has been readily available, the water quality concerns are often neglected. In the present study analysis of the geochemical characteristics of groundwater to assess its suitability for domestic and irrigation purposes has been done. Fifty-five samples were collected in the months of June (pre-monsoon) and October (post-monsoon) from the bore wells. These samples were analysed for various parameters and were compared with various national and international standards to determine the suitability of water for domestic and irrigation use. The thematic maps for hydrogen ion concentration (pH), total dissolved solids (TDS), total hardness (TH), electric conductivity (EC), sodium adsorption ratio (SAR), percent sodium (Na%) and residual sodium carbonate (RSC) were prepared in GIS environment. These maps were further classified as per given standards to study the spatial variations of quality parameters and their suitability for drinking and irrigation purposes. Investigations revealed that groundwater in general was hard for domestic use. However it was within the safe limits for drinking. Furthermore groundwater quality was well within the desirable to permissible limits for irrigation purpose.     

Chemometric analysis to infer hydro-geochemical processes in a semi-arid region of India

Groundwater exploitation in Punjab has increased in last few decades due to rapid increase in industrialization, population, crop production, and erratic monsoon. In the present study, groundwater samples from 29 locations were collected and analyzed for almost all major anions, cations, and heavy metals. The analyzed parameters formed the attribute database for statistical analysis. The study approach included multivariate statistical analysis of hydro-chemical data to identify hydro-geochemical processes occurring in the study area and its relation to groundwater quality. The principal component analysis produced seven significant factors that explained nearly 77 % of the cumulative variance. Factor 1 explained nearly 22.05 % of dataset with variables loading indicating mineralization of geological component of soil. Trilinear plot and other graphical methods were also used to identify chemical facies of groundwater and geochemical processes occurring in study area. The water type in the study area is of Na/K–Mg–HCO₃ type. It was found that the general hydro-geochemistry of groundwater in the study area dominated is by the processes such as carbonate/silicate weathering, ion-exchange, and dissolution. Thus, statistical methods can prove to be an effective tool understanding hydro-geochemistry of a region along with conventional graphical methods.     

Bianchi type-V anisotropic cosmological models in certain theories of gravitation with perfect fluid distribution

Exact Bianchi type-V cosmological models are presented in Einstein’s theory of gravitation with cosmological constant Λ in case of perfect fluid distribution. Also obtained Bianchi type-V cosmological models in a scalar-tensor theory of gravitation proposed by Saez and Ballester (1986) in case of perfect fluid distribution using and without using negative constant deceleration parameter. Some physical and geometrical properties of the models are also discussed.     

Identification of Suitable Hydrological Models for Streamflow Assessment in the Kangsabati River Basin,India, by Using Different Model Selection Scores

The increasing demand for water in developing countries, like India, requires efficient water management and resource allocation. This is crucial to accurately assess and predict hydrological processes such as streamflow, drought, and flood. However, simulations of these hydrologic processes from various hydrological models differ in their accuracy. By analyzing different characteristics of hydrological models, selection scores can be used to select the best model for the intended purpose based on their inherit strengths (i.e., some models are better for streamflow prediction). In this study, 13 different criteria were used for the model selection scores including temporal and spatial resolutions, and processes involved. Thereafter, based on different scores, we selected two different hydrological models for streamflow prediction in the Kangsabati River Basin (KRB) in eastern India, namely (1) Génie Rural à 4 paramètres Journalier (GR4J), a conceptual model, and (2) Variable Infiltration Capacity (VIC), a semi-distributed model. The models were calibrated against the daily observed streamflow at upper KRB (Reservoir) and lower KRB (Mohanpur) from 2000 to 2006 and validated during the period from 2008 to 2010. Despite the differences in model structure and data used, both models simulated streamflow at a daily time scale with Nash–Sutcliffe coefficient of 0.71–0.82 for the VIC model and 0.63–0.71 for the GR4J. Due to the simpler structure, parsimonious nature, fewer parameters, and reasonable accuracy, the results suggest that a conceptual rainfall—runoff model like GR4J can be used in data-deficient conditions.

     

Near-field and far-field simulation of accelerograms of Sikkim earthquake of September 18, 2011 using modified semi-empirical approach

The semi-empirical approach for modeling of strong ground motion given by Midorikawa (Tectonophysics 218:287?C295, 1993) has been modified in the present paper for component wise simulation of strong ground motion. The modified approach uses seismic moment in place of attenuation relation for scaling of acceleration envelope. Various strong motion properties like directivity effect and dependence of peak ground acceleration with respect to surface projection of source model have been studied in detail in the present work. Recently, Sikkim earthquake of magnitude 6.9 (M _w ) that occurred on September 18, 2011 has been recorded at various near-field and far-field strong motion stations. The modified semi-empirical technique has been used to confirm the location and parameters of rupture responsible for this earthquake. Strong motion record obtained from the iterative modeling of the rupture plane has been compared with available strong motion records from near as well as far-field stations in terms of root mean square error between observed and simulated records. Several possibilities of nucleation point, rupture velocity, and dip of rupture plane have been considered in the present work and records have been simulated at near-field stations. Final selection of model parameters is based on root mean square error of waveform comparison. Final model confirms southward propagating rupture. Simulations at three near-field and twelve far-field stations have been made using final model. Comparison of simulated and observed record has been made in terms of peak ground acceleration and response spectra at 5?% damping. Comparison of simulated and observed record suggests that the method is capable of simulating record which bears realistic appearance in terms of shape and strong motion parameters. Present work shows that this technique gives records which matches in a wide frequency range for Sikkim earthquake and that too from simple and easily accessible parameters of the rupture plane.     

Inertial Alfvén wave induced turbulent spectra in aurora

In the present paper, we investigate the localization of weak inertial Alfvén wave (IAW) in the presence of finite amplitude magnetosonic fluctuations in low β plasmas (β?m _e /m _i ). When IAW is perturbed by these fluctuations, localized structures of IAW magnetic field intensity are formed. We have developed a semi analytical model based on paraxial approximation to study this interaction. Numerical method has also been used to analyse the localized structures and magnetic fluctuation spectrum of IAW. From the obtained results, we find that the magnetic turbulent spectrum upto k _x λ _e ≈3 fits power law spectrum with an index consistent with the Kolmogorov $k_{x}^{ - 5/3}$ law, here λ _e is the electron inertial length. Furthermore, at shorter wavelengths the spectrum steepens to about $k_{x}^{ - 3.8}$ . Energy transfer from larger lengthscales to smaller lengthscales through this mechanism may be responsible for the observed parallel electron heating in auroral region. Results obtained from the simulation are consistent with the observations recorded from various spacecrafts like FAST, Hawkeye and Hoes 2.     

Stability regions of equilibrium points in restricted four-body problem with oblateness effects

In this paper, we extend the basic model of the restricted four-body problem introducing two bigger dominant primaries m ₁ and m ₂ as oblate spheroids when masses of the two primary bodies (m ₂ and m ₃) are equal. The aim of this study is to investigate the use of zero velocity surfaces and the Poincaré surfaces of section to determine the possible allowed boundary regions and the stability orbit of the equilibrium points. According to different values of Jacobi constant C, we can determine boundary region where the particle can move in possible permitted zones. The stability regions of the equilibrium points expanded due to presence of oblateness coefficient and various values of C, whereas for certain range of t (100≤t≤200), orbits form a shape of cote’s spiral. For different values of oblateness parameters A ₁ (0<A ₁<1) and A ₂ (0<A ₂<1), we obtain two collinear and six non-collinear equilibrium points. The non-collinear equilibrium points are stable when the mass parameter μ lies in the interval (0.0190637,0.647603). However, basins of attraction are constructed with the help of Newton Raphson method to demonstrate the convergence as well as divergence region of the equilibrium points. The nature of basins of attraction of the equilibrium points are less effected in presence and absence of oblateness coefficients A ₁ and A ₂ respectively in the proposed model.