The Shape and Volume of the Skaergaard Intrusion, Greenland: Implications for Mass Balance and Bulk Composition

Re-examination of the Skaergaard intrusion in the context ofits regional setting, combined with new data from explorationdrilling, has resulted in a revised structural model for theintrusion. It is modelled as an irregular box, c. 11 km fromnorth to south, up to 8 km from east to west, and 3·4–4km from the lower to the upper contact. The walls of the intrusionare inferred to follow pre-existing and penecontemporaneoussteep faults, and the floor and roof seem largely controlledby bedding planes in the host sediments and lavas, similar toregional sills. The suggested shape and volume are in agreementwith published gravimetric modelling. Crystallization alongall margins of the intrusion concentrated the evolving meltin the upper, central part of the intrusion, best visualizedas an ‘onion-skin’ structure inside the box. Thetotal volume is estimated to c. 280 ± 23 km³, of which13·7% are referred to the Upper Border Series (UBS),16·4% to the Marginal Border Series (MBS) and 69·9%to the Layered Series (LS). In the LS, the Lower Zone (LZ) isestimated to constitute 66·8%, the Middle Zone (MZ) 13·5%and the Upper Zone (UZ) 19·7%. The new volume relationshipsprovide a mass balance estimate of the major and trace elementbulk composition of the intrusion. The parental magma to theSkaergaard intrusion is similar to high-Ti East Greenland tholeiiticplateau basalts with Mg number c. 0.45. The intrusion representsthe solidification of contemporary plateau basalt magma trappedand crystallized under closed-system conditions in a crustalreservoir at the developing East Greenland continental margin. KEY WORDS: bulk composition; emplacement; mass proportions; Skaergaard intrusion; structure     

Formation of Carbon and Hydrogen Species in Magmas at Low Oxygen Fugacity

Studies of iron-bearing silicate melt (ferrobasalt) + iron metallicphase + graphite + hydrogen equilibria show that carbon andhydrogen solubilities in melts are important for the evolutionof the upper mantle. In a series of experiments conducted at3·7 GPa and 1520–1600°C, we have characterizedthe nature (oxidized vs reduced) and quantified the abundancesof C- and H-compounds dissolved in iron-bearing silicate melts.Experiments were carried out in an anvil-with-hole apparatuspermitting the achievement of equal chemical potentials of H₂in the inner Pt capsule and outer furnace assembly. The fO₂for silicate melt–iron equilibrium was 2·32 ±0·04 log units below iron–wüstite (IW). Theferrobasalt used as starting material experienced a reductionof its iron oxides and silicate network. The counterpart wasa liberation of oxygen reacting with the hydrogen entering thecapsule. The amount of H₂O dissolved in the glasses was measuredby ion microprobe and by step-heating and was found to be between1 and 2 wt %. The dissolved carbon content was found to be 1600ppm C by step-heating. The speciation of C and H componentswas determined by IR and Raman spectroscopy. It was establishedthat the main part of the liberated oxygen was used to formOH^– and to a much lesser extent H₂O, and only traces ofH₂, CO₂ and     

Mountain Protection Forests against Natural Hazards and Risks: New French Developments by Integrating Forests in Risk Zoning

Forests can play a very significant role in protection against natural hazards and risks in mountain lands, especially against erosion and rockfalls. This paper first assesses knowledge concerning the capacity of forests to control natural hazards, with emphasis placed on forest location in catchments or slopes. Zoning aspects are then presented; based on the use of GIS, they allow determining priorities for forestry operations (cuts and biological engineering), in view to setting up an 'optimal management' of mountain forest ecosystems. Finally, an explanation is given of how the results of research are used for the management and planning of mountain ecosystems, illustrated by an example of researcher-practitioner transfer in France. Zoning, prevention, display and regular aspects are developed. On the basis of the experience and knowledge presented here, recommendations are proposed to better take into account the role of mountain forests in the control of natural hazards and risks. It is necessary to have an adapted legislative and economic framework, define priority forest intervention zones and determine an adapted sylviculture.     

Exploring the attractions of city centre living: evidence and policy implications in British cities

The British city centre has been the focus of dynamic housing development and repopulation strategies as a key dimension of the government's urban renaissance programme. Through large scale interview surveys in the provincial city centres of Bristol and Swansea, this paper explores the positive and negative features of city centre living, and how these vary amongst a range of social and physical characteristics. The findings suggest that the practical and mundane attractions of city centre living are more important than the more widely publicised lifestyle and cultural attractions of the city centre commonly emphasised in the gentrification literature. Moreover, the research points to differences in attitudes between age groups, with younger adults placing greater value on the range of social and cultural activities in the city centre, whilst older people express high levels of satisfaction with the attractiveness of the environment. A number of policy implications emerge to encourage inclusive marketing strategies within the continued urban renaissance, particularly to challenge the negative perceptions and promote the varied attractions of city centre living to a mix of social groups.     

Seismic image of the deep crust at the eastern margin of the Alps (Austria): indications for crustal extension in a convergent orogen

A 39-km-long deep seismic reflection profile recorded during two field campaigns in 1996 and 2002 provides a first detailed image of the deep crust at the eastern margin of the Eastern Alps (Austria). The ESE–WNW-trending, low-fold seismic line crosses Austroalpine basement units and extends approximately from 20 km west of the Penninic window group of Rechnitz to 60 km SSE of the Alpine thrust front.The explosive-source seismic data reveals a transparent shallow crust down to 5 km depth, a complexly reflective upper crust and a highly reflective lowermost crust. The upper crust is dominated by three prominent west-dipping packages of high-amplitude subparallel reflections. The upper two of these prominent packages commence at the eastern end of the profile at about 5 and 10 km depth and are interpreted as low-angle normal shear zones related to the Miocene exhumation of the Rechnitz metamorphic core complex. In the western portion of the upper crust, east-dipping and less significant reflections prevail. The lowermost package of these reflections is suggested to represent the overall top of the European crystalline basement.Along the western portion of the line, the lower crust is characterised by a 6–8-km-thick band of high-amplitude reflection lamellae, typically observed in extensional provinces. The Moho can be clearly defined at the base of this band, at approximately 32.5 km depth. Due to insufficient signal penetration, outstanding reflections are missing in the central and eastern portion of the lower crust. We speculate that the result of accompanying gravity measurements and lower crustal sporadic reflections can be interpreted as an indication for a shallower Moho in the east, preferable at about 30.5 km depth.The high reflectivity of the lowermost part of the lower crust and prominent reflection packages in the upper crust, the latter interpreted to represent broad extensional mylonite zones, emphasises the latest extensional processes in accordance with eastward extrusion.     

Evidence for Neotethys rooted within the Vardar suture zone from the Voras Massif, northernmost Greece

Three conflicting models are currently proposed for the location and tectonic setting of the Eurasian continental margin and adjacent Tethys ocean in the Balkan region during Mesozoic–Early Tertiary time. Model 1 places the Eurasian margin within the Rhodope zone relatively close to the Moesian platform. A Tethyan oceanic basin was located to the south bordering a large “Serbo-Pelagonian” microcontinent. Model 2 correlates an integral “Serbo-Pelagonian” continental unit with the Eurasian margin and locates the Tethys further southwest. Model 3 envisages the Pelagonian zone and the Serbo-Macedonian zone as conjugate continental units separated by a Tethyan ocean that was sutured in Early Tertiary time to create the Vardar zone of northern Greece and former Yugoslavia. These published alternatives are tested in this paper based on a study of the tectono-stratigraphy of a completely exposed transect located in the Voras Mountains of northernmost Greece. The outcrop extends across the Vardar zone, from the Pelagonian zone in the west to the Serbo-Macedonian zone in the east.Within the Voras Massif, six east-dipping imbricate thrust sheets are recognised. Of these, Units 1–4 correlate with the regional Pelagonian zone in the west (and related Almopias sub-zone). By contrast, Units 5–6 show a contrasting tectono-stratigraphy and correlate with the Paikon Massif and the Serbo-Macedonian zone to the east. These units form a stack of thrust sheets, with Unit 1 at the base and Unit 6 at the top. Unstacking these thrust sheets places ophiolitic units between the Pelagonian zone and the Serbo-Macedonian zone, as in Model 3. Additional implications are, first, that the Paikon Massif cannot be seen as a window of Pelagonian basement, as in Model 1, and, secondly, Jurassic andesitic volcanics of the Paikon Massif locally preserve a gneissose continental basement, ruling out a recently suggested origin as an intra-oceanic arc.We envisage that the Almopias (Vardar) ocean rifted in Triassic time, followed by seafloor spreading. The Almopias ocean was consumed beneath the Serbo-Macedonian margin in Jurassic time, generating subduction-related arc volcanism in the Paikon Massif and related units. Ophiolites were emplaced onto the Pelagonian margin in the west and covered by Late Jurassic (pre-Kimmeridgian) conglomerates. Other ophiolitic rocks formed within the Vardar zone (Ano Garefi ophiolite, Unit 4) in latest Jurassic–Early Cretaceous time and were not deformed until Early Tertiary time. The Vardar zone finally sutured in the Early Tertiary creating the present imbricate thrust structure of the Voras Mountains.     

Tectonic evolution of the Intra-Pontide suture zone in the Armutlu Peninsula, NW Turkey

The Armutlu Peninsula and adjacent areas in NW Turkey play a critical role in tectonic reconstructions of the southern margin of Eurasia in NW Turkey. This region includes an inferred Intra-Pontide oceanic basin that rifted from Eurasia in Early Mesozoic time and closed by Late Cretaceous time. The Armutlu Peninsula is divisible into two metamorphic units. The first, the Armutlu Metamorphics, comprises a ?Precambrian high-grade metamorphic basement, unconformably overlain by a ?Palaeozoic low-grade, mixed siliciclastic/carbonate/volcanogenic succession, including bimodal volcanics of inferred extensional origin, with a possibly inherited subduction signature. The second unit, the low-grade znik Metamorphics, is interpreted as a Triassic rift infilled with terrigenous, calcareous and volcanogenic lithologies, including basalts of within-plate type. The Triassic rift was unconformably overlain by a subsiding Jurassic–Late Cretaceous (Cenomanian) passive margin including siliciclastic/carbonate turbidites, radiolarian cherts and manganese deposits. The margin later collapsed to form a flexural foredeep associated with the emplacement of ophiolitic rocks in Turonian time. Geochemical evidence from meta-basalt blocks within ophiolite-derived melange suggests a supra-subduction zone origin for the ophiolite. The above major tectonic units of the Armutlu Peninsula were sealed by a Maastrichtian unconformity. Comparative evidence comes from the separate Almacık Flake further east.Considering alternatives, it is concluded that a Mesozoic Intra-Pontide oceanic basin separated Eurasia from a Sakarya microcontinent, with a wider Northern Neotethys to the south. Lateral displacement of exotic terranes along the south-Eurasian continental margin probably also played a role, e.g. during Late Cretaceous suturing, in addition to overthrusting.     

Neotectonic deformation in the transition zone between the Dead Sea Transform and the East Anatolian Fault Zone, Southern Turkey: a palaeomagnetic study of the Karasu Rift Volcanism

In southern Turkey ongoing differential impingement of Arabia into the weak Anatolian collisional collage resulting from subduction of the Neotethyan Ocean has produced one of the most complex crustal interactions along the Alpine–Himalayan Orogen. Several major transforms with disputed motions, including the northward extension of the Dead Sea Fault Zone (DSFZ), meet in this region. To evaluate neotectonic motion on the Amanos and East Hatay fault zones considered to be northward extensions of the DSFZ, the palaeomagnetism of volcanic fields in the Karasu Rift between these faults has been studied. Remanence carriers are low-Ti magnetites and all except 5 of 51 basalt lavas have normal polarity. Morphological, polarity and K–Ar evidence show that rift formation occurred largely during the Brunhes chron with volcanism concentrated at 0.66–0.35 Ma and a subsidiary episode at 0.25–0.05. Forty-four units of normal polarity yield a mean of D/I=8.8°/54.7° with inclination identical to the present-day field and declination rotated clockwise by 8.8±4.0°. Within the 15-km-wide Hassa sector of the Karasu Rift, the volcanic activity is concentrated between the Amanos and East Hatay faults, both with left lateral motions, which have rotated blocks bounded by NW–SE cross faults in a clockwise sense as the Arabian Block has moved northwestwards. An average lava age of 0.5 Ma yields a minimum cumulative slip rate on the system bounding faults of 0.46 cm/year according with the rate deduced from the Africa–Arabia Euler vector and reduced rates of slip on the southern extension of the DSFZ during Plio-Quaternary times. Estimates deduced from offsets of dated lavas flows and morphological features on the Amanos Fault Zone [Tectonophysics 344 (2002) 207] are lower (0.09–0.18 cm/year) probably because they are limited to surface fault breaks and do not embrace the seismogenic crust.Results of this study suggest that most strike slip on the DSFZ is taken up by the Amanos–East Hatay–Afrin fault array in southern Turkey. Comparable estimates of Quaternary slip rate are identified on other faults meeting at an unstable FFF junction (DSFZ, East Anatolian Fault Zone, Karatas Fault Zone). A deceleration in slip rate across the DSFZ and its northward continuation during Plio-Quaternary times correlates with reorganization of the tectonic regime during the last 1–3 Ma including tectonic escape within Anatolia, establishment of the North and East Anatolian Fault Zones bounding the Anatolian collage in mid–late Pliocene times, a contemporaneous transition from transpression to transtension and concentration of all basaltic magmatism in this region within the last 1 Ma.     

The palaeoenvironmental and palaeohydrological evolution of Padul Peat Bog (Granada, Spain) over one million years, from elemental, isotopic and molecular organic geochemical proxies

The elemental (concentration of organic carbon, atomic H/C and C/N ratios), isotopic (δ¹³C values of organic matter) and molecular (predominant n-alkane chain length and carbon preference index (CPI)) organic components were measured for 600 samples taken from a 107-m long core from the Padul Basin (Andalusia, Spain). The record runs from the Lower Pleistocene (ca. 1 Ma B.P.) to the mid-Holocene (ca. 4.5 ka B.P.) with, in general, little diagenesis (removal of components). Two markedly different hydrogeological scenarios were interpreted: (1) From ca. 1 Ma to ca. 400 ka B.P. run-off recharge was significant and water depths were greater (lacustrine scenario). From ca. 400 to 4.5 ka B.P., the Padul Basin became a peat bog s.s. with the major water input coming from groundwater inflow. From ca. 400 to ca. 180 ka B.P. alternating episodes with either predominant grasses, trees or aquatic macrophytes which were linked to wet/dry phases, took place. An important deglaciation episode has been interpreted to occur between ca. 180 and 170 ka B.P. The global climatic changes occurring from ca. 170 to 25 ka B.P. were not recorded in the proxies, though they do show important variations linked to the Last Glacial Maximum and the beginning of the Holocene (ca. 25–10 ka B.P.): (2) Cold phases coexisting with dry periods produced the recession of forests and the development of grasses. After these periods, as both temperature and precipitation increased, forests expanded and the water level, linked to thaw, rose, especially at ca. 20 ka B.P. Few changes occurred during the Holocene, although there were short alternations between wet and dry episodes. Overall, the techniques applied proved to be excellent palaeoenvironmental proxies for studying the basin’s palaeoclimatological and palaeohydrological evolution.     

Modes of occurrence of mercury and other trace elements in coals from the warrior field, Black Warrior Basin, Northwestern Alabama

The mineralogic residence and abundance of trace metals is an important environmental issue. Data from the USGS coal quality database show that potentially toxic elements, including Hg, As, Mo, Se, Cu, and Tl are enriched in a subset of coal samples in the Black Warrior Basin of Alabama, USA. Although the coal as-mined typically is low in these elements, localized enrichments occur in high-pyrite coals and near faults. Microscopic analyses demonstrate that the residence of these elements is dominantly in a late-stage pyrite associated with structurally disrupted coal. Further, our data suggest addition of Hg to the coal matrix as well. The source of these trace elements was hydrothermal fluids driven into the Black Warrior Basin by Alleghanian age tectonism.