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811.
W. Shotyk M.E. Goodsite F. Roos-Barraclough R. Frei G. Asmund T.S. Hansen 《Geochimica et cosmochimica acta》2003,67(21):3991-4011
Mercury concentrations are clearly elevated in the surface and sub-surface layers of peat cores collected from a minerotrophic (“groundwater-fed”) fen in southern Greenland (GL) and an ombrotrophic (“rainwater-fed”) bog in Denmark (DK). Using 14C to precisely date samples since ca. AD 1950 using the “atmospheric bomb pulse,” the chronology of Hg accumulation in GL is remarkably similar to the bog in DK where Hg was supplied only by atmospheric deposition: this suggests not only that Hg has been supplied to the surface layers of the minerotrophic core (GL) primarily by atmospheric inputs, but also that the peat cores have preserved a consistent record of the changing rates of atmospheric Hg accumulation. The lowest Hg fluxes in the GL core (0.3 to 0.5 μg/m2/yr) were found in peats dating from AD 550 to AD 975, compared to the maximum of 164 μg/m2/yr in AD 1953. Atmospheric Hg accumulation rates have since declined, with the value for 1995 (14 μg/m2/yr) comparable to the value for 1995 obtained by published studies of atmospheric transport modelling (12 μg/m2/yr).The greatest rates of atmospheric Hg accumulation in the DK core are also found in the sample dating from AD 1953 and are comparable in magnitude (184 μg/m2/yr) to the GL core; again, the fluxes have since gone into strong decline. The accumulation rates recorded by the peat core for AD 1994 (14 μg/m2/yr) are also comparable to the value for 1995 obtained by atmospheric transport modelling (18 μg/m2/yr). Comparing the Pb/Ti and As/Ti ratios of the DK samples with the corresponding crustal ratios (or “natural background values” for preanthropogenic peat) shows that the samples dating from 1953 also contain the maximum concentration of “excess” Pb and As. The synchroneity of the enrichments of all three elements (Hg, Pb, and As) suggests a common source, with coal-burning the most likely candidate. Independent support for this interpretation was obtained from the Pb isotope data (206Pb/207Pb = 1.1481 ± 0.0002 in the leached fraction and 1.1505 ± 0.0002 in the residual fraction) which is too radiogenic to be explained in terms of gasoline lead alone, but compares well with values for U.K. coals. In contrast, the lowest values for 206Pb/207Pb in the DK profile (1.1370 ± 0.0003 in the leached fraction and 1.1408 ± 0.0003 in the residual fraction) are found in the sample dating from AD 1979: this shows that the maximum contribution of leaded gasoline occurred approximately 25 yr after the zenith in total anthropogenic Pb deposition. 相似文献
812.
I. Expsito J. F. Simancas F. Gonzlez Lodeiro F. Bea P. Montero K. Salman 《Journal of Structural Geology》2003,25(12):2077-2087
The high-temperature metamorphism recorded in the Valuengo and Monesterio areas constitutes a rare occurrence in the Ossa-Morena Zone of Southwest Iberia, where low-grade metamorphism dominates. The metamorphism of the Valuengo area has been previously considered either Cadomian or Variscan in age, whereas that of Monesterio has been interpreted as a Cadomian imprint. However, these areas share important metamorphic and structural features that point towards a common tectonometamorphic evolution. The metamorphism of the Valuengo and Monesterio areas affects Late Proterozoic and Early Cambrian rocks, and is syn-kinematic with a top-to-the-north mylonitic foliation, which was subsequently deformed by early Variscan folds and thrusts. The U–Pb zircon age (480±7 Ma) we have obtained for an undeformed granite of the Valuengo area is consistent with our geological observations constraining the age of the metamorphism. We propose that this high-temperature metamorphic imprint along a NW–SE ductile extensional shear zone is related to the crustal extension that occurred in the Ossa-Morena Zone during the Cambro-Ordovician rifting. In the same way, the tectonothermal effect of the preorogenic rifting stage may have been wrongly attributed to orogenic processes in other regions as well as in this one. 相似文献
813.
Validation of Landslide Susceptibility Maps; Examples and Applications from a Case Study in Northern Spain 总被引:9,自引:3,他引:9
Remondo Juan González Alberto De Terán José Ramón Díaz Cendrero Antonio Fabbri Andrea Chung Chang-Jo F. 《Natural Hazards》2003,30(3):437-449
A procedure for validating landslide susceptibility maps wasapplied in a study area in northern Spain and the results obtained compared. Validationwas used to carry out sensitivity analysis for individual variables and combinationsof variables. The validity of different map-making methods was tested, as well as theutility of different types of Favourability Functions. The results obtained show thatvalidation is essential to determine the predictive value of susceptibility maps. Italso helps to better select the most suitable function and significant variables, thus improving the efficiency of the mapping process. Validation based on a temporal strategy makes it possible to derive hazard maps from susceptibility maps. 相似文献
814.
Gregory K. Druschel Robert J. Hamers George W. Luther III Jillian F. Banfield 《Aquatic Geochemistry》2003,9(2):145-164
The oxidation kinetics of trithionate (S3O62-
) and tetrathionate (S4O
6
2-
) with hydroxyl radicals (OH*) have been investigated in systems analogous to acid mine drainage (AMD) environments. The discovery of hydroxyl radical
(OH*) formation on pyrite surfaces (Borda et al., 2003) suggests hydroxyl radicals may affect the oxidation kinetics of intermediate
sulfur species such as tetrathionate. Cyclic voltammetry experiments in acidic solutions indicate that the reaction of S4O
6
2-
with OH* goes through an unknown intermediate, tentatively assigned as S3O
4
n-
. An outer-sphere electron transfer mechanism for the reaction of S4O
6
2-
with OH* to form S3O
4
n-
is proposed based on experimental results. Oxidation rates for trithionate and tetrathionate in the presence of Fenton's
reagent (which forms hydroxyl radicals) are too fast to be directly measured using UV-Vis spectrophotometry, electrochemical,
or stop-flow spectrophotometry methods. Competitive reaction kinetics within the context of the Haber—Weiss mechanism suggests
that the rate constant for the oxidation of trithionate and tetrathionate with OH* is in excess of 108 M-1 sec-1. 相似文献
815.
Offsets from isotopic equilibrium in biogenic carbonates have complicated paleoclimate reconstructions for decades. A new archive of climate, deep-sea corals, is used to evaluate the calcification processes, independent of photosynthesis, that contribute to these offsets. Carbon and oxygen stable isotope data from six modern deep-sea corals show strong linear trends between δ13C and δ18O. Slopes of these trends between samples are similar and range between 1.9 to 2.6 for Δδ13C/Δδ18O. Linear trends intersect isotopic equilibrium for δ18O and are slightly depleted for δ13C. Variations in the isotopic ratios are strongly correlated with the density banding structure. Isotopically depleted aragonite is associated with light, quickly precipitating bands, whereas isotopically enriched points correspond to slowly accumulating, less dense aragonite. The densest white band at the trabecular center is furthest from isotopic equilibrium for both carbon and oxygen. Data from this region fall off the linear trend between δ18O and δ13C. This deviation, where δ13C remains constant while the δ18O continues to decrease, does not support “vital effect” mechanisms that call upon kinetic fractionation to explain offsets from isotopic equilibrium. We propose a new mechanism for vital effects in these deep-sea corals that is based on a thermodynamic response to a biologically induced pH gradient in the calcifying region. 相似文献
816.
Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone 总被引:1,自引:0,他引:1
Moritz F. Lehmann Peter Reichert Alberto Barbieri 《Geochimica et cosmochimica acta》2003,67(14):2529-2542
The stable isotope composition (δ15N and δ18O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ15N and δ18O values for residual nitrate. Maximum δ15N and δ18O values amounted to 27.2 and 15.7‰, respectively.15N and 18O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ18O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ15N. 相似文献
817.
818.
819.
The impact of accelerometry on CHAMP orbit determination 总被引:6,自引:0,他引:6
The contribution of the STAR accelerometer to the CHAMP orbit precision is evaluated and quantified by means of the following
results: orbital fit to the satellite laser ranging (SLR) observations, GPS reduced-dynamic vs SLR dynamic orbit comparisons,
and comparison of the measured to the modeled non-gravitational accelerations (atmospheric drag in particular). In each of
the four test periods in 2001, five CHAMP arcs of 2 days' length were analyzed. The mean RMS-of-fit of the SLR observations
of the orbits computed with STAR data or the non-gravitational force model were 11 and 24 cm, respectively. If the accelerometer
calibration parameters are not known at least at the few percent level, the SLR orbit fit deteriorates. This was tested by
applying a 10% error to the along-track scale factor of the accelerometer, which increased the SLR RMS-of-fit on average to
17 cm. Reference orbits were computed employing the reduced-dynamic technique with GPS tracking data. This technique yields
the most accurate orbit positions thanks to the estimation of a large number of empirical accelerations, which compensate
for dynamic modeling errors. Comparison of the SLR orbits, computed with STAR data or the non-gravitational force model, to
the GPS-based orbits showed that the SLR orbits employing accelerometer observations are twice as accurate. Finally, comparison
of measured to modeled accelerations showed that the level of geomagnetic activity is highly correlated with the atmospheric
drag model error, and that the largest errors occur around the geomagnetic poles.
Received: 7 May 2002 / Accepted: 18 November 2002
Correspondence to: S. Bruinsma
Acknowledgments. The TIGCM results were obtained from the CEDAR database. This study was supported by the Centre National d'Etudes Spatiales
(CNES). The referees are thanked for their helpful remarks and suggestions. 相似文献
820.
Summary ?Above orographically structured terrain considerable differences of the regional wind field may be identified during large-scale
extreme wind events. So far, these regional differences could not be resolved by climate models. To determine the relationships
between large-scale atmospheric conditions, the influence of orography, and the regional wind field, data measured in the
upper Rhine valley within the framework of the REKLIP Regional Climate Project were analyzed and calculations were made using
the KAMM mesoscale model. In the area of the upper Rhine valley, ratios of the wind velocity in the Rhine valley at 10 m above
ground level, νval, and the large-scale flow velocity, νlar, are between νval/νlar ≈ 0.1 and νval/νlar ≈ 1. The νval/νlar ratio exhibits a strong dependence on thermal stratification, δ, and decreases from νval/νlar ≈ 1 at δ = 0 K m−1 to νval/νlar ≈ 0.2 at δ = 0.0075 K m−1. In areas, where the lateral mountainous border of the Rhine valley is interrupted, the νval/νlar ratio increases again with increasing stability or decreasing Froude number. This is obviously due to flow around the Black
Forest under stable stratification. It is demonstrated by model calculations that a complex wind field develops in the Rhine
valley at small Froude numbers (Fr < 1) irrespective of the direction of large-scale flow. The νval/νlar ratio is characterized by small values in the direct lee side (νval/νlar ≈ 0.2) and high values on the windward side of the lateral mountainous border of the Rhine valley (νval/νlar ≈ 0.8).
Received October 22, 2001; revised June 18, 2002; accepted June 23, 2002 相似文献