Carbohydrate sources in a coastal marine environment

Individual neutral sugars in sediments, sediment trap materials and major biological sources of a coastal marine environment (Dabob Bay, Washington State) were analyzed by capillary gas chromatography of equilibrated isomeric mixtures. Plankton, bacteria, and vascular plant tissues of different types yielded reproducible and biochemically consistent compositional patterns. These patterns, when expressed in simple parameters, allowed distinctions between marine and terrestrial carbohydrate sources as well as among the major different types of vascular plant tissues. Plankton and bacteria, due to their compositional diversity, were not further distinguishable by carbohydrate compositions alone. Carbohydrate compositions of Dabob Bay sediments and sediment trap materials, interpreted using source-indicator parameters, indicate a predominantly marine origin with increased relative input of terrestrially-derived carbohydrates in winter periods of low phytoplankton productivity. Both plankton and grasses are indicated as major carbohydrate sources during spring. Glucose yield enhancement factors, determined by comparative acid pretreatments, confirm the general predominance of α-cellulose-poor marine polysaccharides and increased levels of α-cellulose-rich vascular plant remains in winter sediment trap samples.     

Phosphorus Sorption Dynamics of Hawaii’s Coastal Wetlands

While phosphorus (P) sorption has been studied in Hawaii’s terrestrial soils, P sorption dynamics have yet to be investigated in coastal wetlands. In other coastal zones, wetlands have been shown to sorb P and act as P sinks at the land–sea interface. Thus, the objectives of this study were to examine variance in the P sorption index (PSI) within wetlands along hydrologic gradients and among wetlands of different types and to identify soil properties that best explain variability in the PSI. Forty wetlands on five islands were sampled and P sorption and related properties were measured. Phosphorus sorption index values ranged from −16.4–1,732.5. Hydrologic zone (within sites) and surface water salinity (among sites) accounted for significant proportions of the variance in the PSI. While texture, pH, and carbon content were found to be important predictors of PSI, the highest correlations were found for oxalate-extractable iron.     

Hydrologic artifact dispersals at Pingasagruk,North Coast,Alaska

Situated on a coastal sand bar, Pingasagruk is a habitation site with prehistoric and historic components. Data from systematic surface sampling led to analyses that show different artifact distribution patterns on and off this site and suggest the dispersals are due to storms and erosion, in addition to human activity. To explain the disparate distributions of cultural materials, this study uses a model of hydrologic artifact dispersal and, possibly, differential sorting. Differences in distribution patterns at Pingasagruk highlight the importance of considering how cultural and noncultural transformation processes affect the occurrence of sites and their artifacts. © 1993 John Wiley & Sons, Inc.     

Kampelite,Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O,a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula,Russia)

Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,...     

Hierarchically nested river landform sequences. Part 2: Bankfull channel morphodynamics governed by valley nesting structure

River corridors exhibit landforms nested within landforms repeatedly down spatial scales. In Pasternack et al. ( 2018 ), a new, scale‐independent, hierarchical river classification was developed that uses five landform types to map the domains of a single fluvial process – flow convergence routing – at each of three–five spatial scales. Given those methods, this study investigated the details of how flow convergence routing organizes nested landform sequences. The method involved analyzing landform abundance, sequencing, and hierarchical nesting along the 35 km gravel/cobble lower Yuba River in California. Independent testing of flow convergence routing found that hydraulic patterns at every flow matched the essential predictions from classification, substantiating the process–morphology link. River width and bed elevation sequences exhibit large, nonrandom, and linked oscillations structured to preferentially yield wide bars and constricted pools at base flow and bankfull flow. At a flow of 8.44 times bankfull, there is still an abundance of wide bar and constricted pool landforms, but larger topographic drivers also yield an abundance of nozzle and oversized landforms. The nested structure of flow convergence routing landforms reveals that base flow and bankfull landforms are nested together within specific floodprone valley landform types, and these landform types control channel morphodynamics during moderate to large floods. As a result, this study calls into question the prevailing theory that the bankfull channel of a gravel/cobble river is controlled by in‐channel, bankfull, and/or small flood flows. Such flows may initiate sediment transport, but they are too small to control landform organization in a gravel/cobble river with topographic complexity. Copyright © 2018 John Wiley & Sons, Ltd.     

Distribution and abundance of macroinvertebrates on certain connecticut tidal marshes,with emphasis on dominant molluscs

The distribution of macroinvertebrates on Connecticut tidal marshes corresponds well with that reported for other marshes along the Atlantic and Gulf coasts of the United States. The greatest densities and biomass of the ribbed mussel,Geukensia demissa, were found on marshes in the central and western part of the state where both the annual production ofSpartina alterniflora and tidal range are large. *** DIRECT SUPPORT *** A01BY019 00011     

Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.